Modified polyurethane resin composite material for artificial grass and preparation method thereof
A technology of polyurethane resin and artificial turf, which is applied in the field of polyurethane materials, can solve problems such as slow curing speed, inability to apply to occasions with high mechanical performance requirements, hard and brittle materials, etc., and achieve the effect of improving elasticity
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Embodiment 1
[0031] A modified polyurethane resin composite material for artificial turf, prepared through the following steps:
[0032] (1) Preparation of modified polyurethane resin matrix
[0033] The isocyanate and polyether alcohol with a molar ratio of 6:1 were continuously stirred at 70°C for 4 hours in a nitrogen atmosphere to obtain component A; the 4,4'-diamino- Mix 3,3'-difluorodiphenylmethane and polyether alcohol evenly to obtain component B. When mixing, first melt 4,4'-diamino-3,3'-difluorodiphenylmethane at 120°C , and then mixed evenly with polyether alcohol; mix A component with a mass ratio of 0.6:1 and B component evenly, and add α-methacrylic acid accounting for 20% of the total mass of A component and B component, accounting for A Dibutyltin dilaurate with a total mass of 0.1% of component B and component B was reacted in an oven at 90°C for 4 hours to obtain a modified polyurethane resin matrix, wherein the polyether alcohol was polyether diol, and the isocyanate wa...
Embodiment 2
[0036] A modified polyurethane resin composite material for artificial turf, prepared through the following steps:
[0037] (1) Preparation of modified polyurethane resin matrix
[0038] The isocyanate and polyether alcohol with a molar ratio of 9:1 were continuously stirred at 80°C for 3 hours in a nitrogen atmosphere to obtain component A; the 4,4'-diamino- Mix 3,3'-difluorodiphenylmethane and polyether alcohol evenly to obtain component B. When mixing, first melt 4,4'-diamino-3,3'-difluorodiphenylmethane at 140°C , and then mixed with polyether alcohol; mix the A component and B component with a mass ratio of 0.9:1, and add α-methacrylic acid accounting for 30% of the total mass of A component and B component, accounting for A Dibutyltin dilaurate with 0.15% of the total mass of component B and component B was reacted in an oven at 150°C for 2 hours to obtain a modified polyurethane resin matrix. Wherein, the polyether alcohol is polyether diol, and the isocyanate is isop...
Embodiment 3
[0041] A modified polyurethane resin composite material for artificial turf, prepared through the following steps:
[0042] (1) Preparation of modified polyurethane resin matrix
[0043] The isocyanate and polyether alcohol with a molar ratio of 8:1 were continuously stirred at 75°C for 3 hours in a nitrogen atmosphere to obtain component A; the 4,4'-diamino- Mix 3,3'-difluorodiphenylmethane and polyether alcohol evenly to obtain component B. When mixing, first melt 4,4'-diamino-3,3'-difluorodiphenylmethane at 130°C , and then mixed with polyether alcohol evenly; mix A component and B component with a mass ratio of 0.8:1, and add α-methacrylic acid accounting for 25% of the total mass of A component and B component, accounting for A Dibutyltin dilaurate with 0.12% of the total mass of component B and component B was reacted in an oven at 100°C for 3 hours to obtain a modified polyurethane resin matrix. Wherein, the polyether alcohol is polyether diol, and the isocyanate is d...
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