Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

High-elasticity resin modified silicone oil and preparation method thereof

A modified silicon, high-elasticity technology, applied in the direction of improved hand-feeling fibers, fiber types, textiles and papermaking, etc., can solve the problems of quality improvement and inability to achieve, achieve simple process, excellent film-forming properties, and easy reaction process. control effect

Active Publication Date: 2020-05-19
NINGBO RUNHE HIGH TECH MATERIAL CO LTD
View PDF2 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, block silicone oils of various concepts have emerged one after another, such as five-membered and six-membered multi-component copolymerization, polyurethane polyether block silicone oil, hyperbranched silicone oil with T-shaped structure, etc., but its essential structure has not changed. Polyether, amino, organic The ternary components of the silicon core have basically not changed, so if these silicone oils are used to treat textiles, the bulkiness, smoothness and softness of the textiles will not be able to achieve a qualitative improvement

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • High-elasticity resin modified silicone oil and preparation method thereof
  • High-elasticity resin modified silicone oil and preparation method thereof
  • High-elasticity resin modified silicone oil and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] (1) Add 30 parts of polyethylene glycol (the number average molecular weight is 150) into a reaction kettle equipped with a thermometer, a stirrer and condensing reflux, raise the temperature to 50 ° C, and feed nitrogen, and 100 parts of diphenylmethane Diisocyanate is slowly added dropwise into the reaction kettle through a constant pressure dropping funnel, and after 3 hours of heat preservation, the temperature is lowered to below 40°C, and nitrogen gas is stopped to obtain a polyurethane prepolymer.

[0042] (2) 200 parts of polyurethane prepolymers obtained and 63 parts of N,N-dimethyl-1,3-propylenediamine are added to the reaction kettle equipped with thermometer, agitator and condensing reflux, and the temperature is raised to 40 ℃, and feed nitrogen, after 4 hours of heat preservation, add 2080 parts of epoxy-terminated polyether silicone oil (number average molecular weight is 9000) and 1300 parts of isopropanol, raise the temperature to 75 ℃, keep the temperat...

Embodiment 2

[0048] (1) Add 45 parts of polyethylene glycol (the number average molecular weight is 200) into a reaction kettle equipped with a thermometer, a stirrer and condensing reflux, raise the temperature to 60 ° C, and feed nitrogen, and 113 parts of diphenylmethane Diisocyanate is slowly added dropwise into the reaction kettle through a constant pressure dropping funnel, and after 2.5 hours of heat preservation, the temperature is lowered to below 40°C, and nitrogen gas is stopped to obtain a polyurethane prepolymer.

[0049] (2) 200 parts of polyurethane prepolymers obtained and 46 parts of N,N-dimethyl-1,3-propylenediamine are added to the reaction kettle equipped with thermometer, agitator and condensing reflux, and the temperature is raised to 45 ℃, and feed nitrogen, after 3 hours of heat preservation, add 2000 parts of epoxy-terminated polyether silicone oil (number average molecular weight: 12000) and 1200 parts of isopropanol, raise the temperature to 80 ℃, keep the tempera...

Embodiment 3

[0051] (1) Add 60 parts of polyethylene glycol (the number average molecular weight is 200) into a reaction kettle equipped with a thermometer, a stirrer and condensing reflux, raise the temperature to 70 ° C, and feed nitrogen, and 150 parts of diphenylmethane Diisocyanate is slowly added dropwise into the reaction kettle through a constant pressure dropping funnel, and after being kept warm for 2 hours, the temperature is lowered to below 40°C, and nitrogen gas is stopped to obtain a polyurethane prepolymer.

[0052](2) Add 200 parts of polyurethane prepolymer and 46 parts of N,N-dimethyl-1,3-propanediamine to the reaction kettle, raise the temperature to 50°C, and feed nitrogen gas for 2 After 1 hour, add 1600 parts of epoxy-terminated polyether silicone oil (the number-average molecular weight is 11000) and 1000 parts of isopropanol, heat up to 80° C., after 10 hours of heat preservation reaction, cool down to below 40° C., stop feeding nitrogen, and obtain High elastic re...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses high-elasticity resin modified silicone oil. The invention relates to the field of fine chemical synthesis, in particular to a high-molecular polymer, which has the main structural general formula shown as the specification, wherein A is CH2CH2O, B is a group represented as the specification, R1 is CH2CH2CH2, R is m, n, p, z, x is an integer, 3 < = x < = 5, 2 < = m < = 4, 5< = n < = 7, 105 < = p < = 145, and 2 < = z < = 4. According to the invention, a polyurethane material has a soft and hard chain segment block structure, so that the high-elasticity resin modified silicone oil is developed on the basis of the principle that the silicone oil has high elasticity and can endow a material with high elasticity, high-activity polyurea elastic resin with a soft and hardblock structure is connected on the basis of an organic silicon soft chain segment; the high-elasticity resin modified silicone oil structurally has a soft-hard chain segment, so that the high-elasticity resin modified silicone oil has a better treatment effect on fabric treatment compared with other silicone oil.

Description

technical field [0001] The invention relates to the field of fine chemical synthesis, in particular to a highly elastic resin-modified silicone oil and a preparation method thereof. Background technique [0002] In the past 10 years, the development of polyetheramine-based silicone oil has reached a highly mature stage. When it comes to the price hand-to-hand combat stage in the stock market, it is difficult to carry out alternative incremental growth through performance improvement, and it can only squeeze out the market share of competitors through price wars. ; Due to the high transparency and homogeneity of the synthesis process, core raw materials, and cost-effectiveness of block silicone oil, companies are forced to innovate the structure of silicone oil to improve performance and effect, so as to effectively replace block silicone oil and amino silicone oil for market competition. readjust. In recent years, block silicone oils of various concepts have emerged one aft...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/48C08G18/61C08G18/32C08G18/10D06M15/568D06M101/32
CPCC08G18/66C08G18/4833C08G18/61C08G18/3228C08G18/10D06M15/568D06M2200/50D06M2101/32C08G18/6529
Inventor 皮碧荣徐炜朱建华章东升
Owner NINGBO RUNHE HIGH TECH MATERIAL CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com