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Regular carrier catalyst with desulfurization effect as well as preparation and application thereof

A technology for regular carrier and desulfurization, which is applied to a regular carrier catalyst with desulfurization and its preparation and application fields, can solve the problems of loss of octane number, decrease of desulfurization activity, decrease of octane number of gasoline products, etc.

Pending Publication Date: 2020-05-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hydrodesulfurization reacts sulfur-containing hydrocarbons such as gasoline with hydrogen in the presence of a hydrogenation catalyst. With the increasingly stringent fuel standards, this requires more severe hydrogenation reaction conditions such as higher reaction pressure or temperature to make sulfur Lower levels, but due to the large amount of olefins in gasoline, increasing the hydrogenation severity will result in higher octane loss
Adsorption desulfurization is usually carried out by contacting the adsorbent with sulfur-containing hydrocarbons under the condition of hydrogen. First, the sulfur-containing hydrocarbons in the oil are captured on the adsorbent, hydrogenated to generate hydrogen sulfide, and then combined with zinc oxide to form sulfur-zinc compounds. , will also lead to a decrease in the octane number of gasoline products; in addition, when the sulfur bound on the zinc oxide reaches saturation, it will lead to a decrease in desulfurization activity, and the sulfur must be removed through oxidation regeneration. In the frequent oxidation regeneration-reduction process, the adsorbent The deactivation rate is high, which affects the implementation effect of sulfur-containing hydrocarbon desulfurization

Method used

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  • Regular carrier catalyst with desulfurization effect as well as preparation and application thereof

Examples

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preparation example Construction

[0055] The method for preparing a structured carrier catalyst provided by the invention includes the step of preparing a suspension. The preparation method of the suspension includes: forming a mixture of metal powder, a hydroxyl-containing solvent and a surfactant, and treating it under ultrasonic waves to obtain a mixed liquid after ultrasonic treatment; wherein, during the ultrasonic treatment process, the fine particles are peeled off from the metal powder The metal particles are suspended in a hydroxyl-containing solvent (solvent for short); the larger particles are separated from the ultrasonically mixed solution to obtain a suspension, and the suspension contains fine particles containing modified metals. The metal powder (also known as metal powder) can be pure metal powder (when the metal film only contains modified metal and the modified metal is one kind), alloy powder containing modified metal and boron, containing Alloy powder of various modified metals. Among th...

Embodiment approach

[0069] According to the first embodiment described in the method for preparing a structured carrier catalyst of the present invention, preferably, the weight of the source of alumina calculated as alumina and the source of oxides of at least one metal in Group IIA and Group IIB calculated as oxides The ratio is 0-80:20-100, for example, 0-70:30-100 or 0-60:40-100 or 0-50:50-100 or 25-60:40-75 or 60-70:30-40.

[0070] According to the preparation method of the structured carrier catalyst of the present invention, the coating is such that in the product obtained by coating, the content of the active coating is 10 to 50% by weight, preferably 15 to 30% by weight, on a dry basis, More preferably 20-30% by weight. The coating is carried out one or more times. Preferably, drying and optional firing are carried out after each coating, and firing is carried out after the last coating, so that the content of the active coating in the obtained product meets the requirements.

[0071] A...

specific Embodiment approach

[0078] A specific embodiment of the preparation method of the structured carrier catalyst provided by the present invention includes the following steps: uniformly mixing the metal powder and the hydroxyl-containing solvent, and then using a specific ultrasonic power of 50-250W / (100g hydroxyl-containing solvent), preferably 100- Ultrasonic treatment at a power of 150W / (100g hydroxyl-containing solvent) for 4 to 10 hours, for example, 5 to 8 hours, and then centrifuge the ultrasonically mixed solution at 1200 to 3000 rpm, preferably 1500 to 2500 rpm, to obtain Suspension liquid; then mix matrix particles with the suspension liquid, disperse evenly, freeze-dry, and coat the regular carrier to prepare the regular carrier catalyst. The average particle size of the metal powder is less than 20 microns, preferably 1-15 microns or 3-18 microns; the metal powder: hydroxyl-containing solvent = 1:2-15 weight ratio, preferably 1:5-10; Said surfactant: solvent=0.001~100mg:1mL is for examp...

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Abstract

The invention discloses a regular carrier catalyst with a desulfurization effect as well as preparation and application thereof. The regular carrier catalyst comprises a regular carrier and an activecoating attached to the surface of the regular carrier, wherein the active coating comprises a matrix containing IIA and IIB group metal oxides and a modified metal film attached to the outer surfaceof the matrix, the modified metal film comprises a modified metal, and the modified metal comprises one or more of Cr, Mo and W. The preparation method comprises the following steps: forming a mixturefrom metal powder, a hydroxyl-containing solvent and a surfactant, then treating the mixture under ultrasonic waves to obtain a mixed solution after the ultrasonic treatment; after the ultrasonic treatment, separating the mixed solution to obtain suspension; contacting the suspension with matrix particles, carrying out freeze drying to obtain matrix particles containing a modified metal film, andcoating the regular carrier with the matrix particles containing the modified metal film to obtain the regular carrier catalyst. The catalyst is used for hydrocarbon hydro-desulfurization, has high desulfurization activity and good stability, and can reduce the octane number loss of gasoline.

Description

technical field [0001] The invention relates to a modified molecular sieve used for hydrogen desulfurization, a preparation method and an application method thereof. Background technique [0002] Sulfur in hydrocarbon fuels burns to produce sulfur oxides, which can inhibit the activity of noble metal catalysts in automobile exhaust converters and cause them to be irreversibly poisoned, and cannot achieve catalytic conversion of toxic gases in automobile exhaust, thus Exhausted vehicle exhaust contains unburned non-methane hydrocarbons, nitrogen oxides and carbon monoxide. These toxic gases are easily catalyzed by sunlight to form photochemical smog and cause acid rain. Sulfur oxide itself is also one of the main causes of acid rain. [0003] Reducing the sulfur content of fuels such as gasoline and diesel is considered one of the most important measures to improve air quality. As people pay more and more attention to environmental protection, environmental protection regula...

Claims

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Application Information

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IPC IPC(8): B01J23/26B01J23/28B01J23/30C10G45/04
CPCB01J23/28B01J23/26B01J23/30C10G45/04C10G2300/1037C10G2300/104C10G2300/1044C10G2300/70C10G2300/202C10G2400/02
Inventor 姜秋桥田辉平王鹏宋海涛孙言严加松林伟
Owner CHINA PETROLEUM & CHEM CORP
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