Composite metal photocatalysis system and preparation method and application thereof
A composite metal and photocatalysis technology, applied in the chemical industry, can solve the problems of difficult separation of catalysts, many post-processing steps, and complicated post-processing steps, and achieves the promotion of photo-generated electrons and holes separation, low overpotential and charge transfer resistance, The effect of promoting free radical cycloaddition reaction
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Embodiment 1
[0036] 70.4g Ni(π-C 3 h 5 ) 2 , 73.4g triphenylphosphine mixed in 500g distilled water, heated to 40°C and stirred for 6h; 115.6g AgNO 3 , Mix 58.7g of diphenyl disulfide in 1000g of distilled water, raise the temperature to 50°C and stir for 7 hours, then mix the two aqueous solutions, add 58.7g of carbon nanorods in the state of stirring the mixed salt solution and mix to obtain a suspension A ;
[0037]Dissolve sodium carbonate in water to form a 20wt% sodium carbonate solution, which is the alkaline precipitant B, heat the suspension A and alkaline precipitant B to 40°C, and slowly add the alkaline solution B to the slurry A During the precipitation process, the reaction temperature was controlled at 40°C and the pH of the system was 8; after the precipitation reaction was completed, the slurry was obtained after aging at 70°C for 3 hours;
[0038] The slurry was filtered, washed with deionized water, and the filter cake was dried at 115° C. for 10 h, and calcined at 3...
Embodiment 2
[0042] 137.5g Ni(COD) 2 , 63.7g tributylphosphine mixed in 1000g distilled water, heated to 45°C and stirred for 6h; 128.8g Cd(NO 3 ) 2 1. Mix 36.8g of dicumyl peroxide in 1000g of distilled water, raise the temperature to 55°C and stir for 8h, then mix the two aqueous solutions, add 53.9g of 5A molecular sieve to mix under the state of stirring the mixed salt solution to obtain suspension A;
[0043] Dissolve sodium bicarbonate in water to form a 30wt% sodium bicarbonate solution, which is the alkaline precipitant B. Heat the suspension A and the alkaline precipitant B to 30°C, and slowly add the lye B dropwise to In the slurry A, control the reaction temperature of the precipitation process to 30°C and the pH of the system to 9; after the precipitation reaction is completed, age at 80°C for 4 hours to obtain the slurry;
[0044] The slurry was filtered, washed with deionized water, and the filter cake was dried at 120° C. for 11 h, and calcined at 350° C. for 10 h to obtai...
Embodiment 3
[0048] Mix 110.5g Ni(CDT) and 48.9g tri-tert-butylphosphine in 500g distilled water, raise the temperature to 50°C and stir for 5h; mix 107.4g SnCl 4 , Mix 29.4g of dicumyl peroxide in 1000g of distilled water, raise the temperature to 60°C and stir for 8 hours, then mix the two aqueous solutions, add 39.2g of ordered mesoporous carbon in the state of stirring the mixed salt solution and mix to obtain a suspension Liquid A;
[0049] Dissolve ammonium carbonate in water to form a 20wt% ammonium carbonate solution, which is the alkaline precipitant B, heat the suspension A and alkaline precipitant B to 35°C, and slowly add the alkaline solution B to the slurry A During the precipitation process, the reaction temperature was controlled at 35°C and the pH of the system was 9; after the precipitation reaction was completed, the slurry was obtained after aging at 80°C for 5 hours;
[0050] The slurry was filtered, washed with deionized water, and the filter cake was dried at 130° C...
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