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Functional gel as well as preparation method and application thereof

A gel and functional technology, applied in semiconductor/solid-state device manufacturing, electrical components, electrical solid-state devices, etc., can solve the problems of easy water loss, high-temperature resistance of gel substrate materials, deformation and shrinkage, etc., and achieve strong wettability , The preparation process is simple and fast, and the effect of mild reaction conditions

Pending Publication Date: 2020-03-27
INST OF FLEXIBLE ELECTRONICS TECH OF THU ZHEJIANG +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Traditional semiconductor methods are not suitable for patterning on the surface of gel substrates. Because gel substrate materials are not resistant to high temperatures, they are prone to dehydration and deformation and shrinkage when encountering high temperatures. Most semiconductor methods require high-temperature treatment, which will lead to gel substrates The surface structure and geometry of the substrate material change, therefore, how to effectively pattern the surface of the gel substrate material without affecting the gel substrate material is a technical problem that needs to be solved urgently

Method used

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  • Functional gel as well as preparation method and application thereof
  • Functional gel as well as preparation method and application thereof
  • Functional gel as well as preparation method and application thereof

Examples

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preparation example Construction

[0043] The preparation method of the functional gel specifically comprises the following steps:

[0044] S1: Mix functional filler 1 with liquid metal 2 to obtain mixture 3;

[0045] S2: Provide a gel substrate 4, and use the mixture 3 as a raw material to form a prefabricated pattern layer 5 on the surface of the gel substrate 4, wherein the prefabricated pattern layer 5 includes a sacrificial layer and is dispersed on the The functional filler 1 in the sacrificial layer, and the sacrificial layer includes the oxide of the liquid metal 2;

[0046] S3: provide an etching solution, and make the etching solution react with the sacrificial layer to remove the sacrificial layer, so that the functional filler 1 is deposited on the surface of the gel substrate 4 to form a pattern layer 6, and a functional gel is obtained. glue.

[0047] For traditional flexible and stretchable sensors, liquid metal 2 is used as the flexible electrode to realize conformal integration with the flexi...

Embodiment 1

[0097] (1) Put 100 parts by weight of liquid metal EGaIn (gallium indium eutectic) into a glove box, fill the glove box with inert gas Ar, and disperse 0.1 parts by weight of gold microparticles in the liquid metal EGaIn to form a mixture, And continue to stir for 1 hour in an inert gas atmosphere, so that the gold microparticles are monodispersed in the liquid metal EGaIn, and the diameter of the gold microparticles is approximately 20 μm;

[0098] (2) A methacrylic anhydride-based gelatin substrate is provided, and the above mixture is used as a 3D printing slurry, and the mixture is drawn on the top surface of the methacrylic anhydride-based gelatin substrate by a 3D printer nozzle;

[0099] (3) Oxidize the liquid metal EGaIn on the surface of the gel substrate, place it under natural conditions (in the air), and heat it at a temperature of 60°C for 20min, so that the surface of the gel substrate is in contact with the air The liquid metal EGaIn undergoes an oxidation react...

Embodiment 2

[0104] (1) Put 100 parts by weight of liquid metal GaInSn into a glove box, fill the glove box with inert gas Ar, disperse 0.5 parts by weight of graphene sheets in liquid metal GaInSn to form a mixture, and inert gas atmosphere Continue to stir for 2 hours, so that the graphene sheets are monodispersed in the liquid metal GaInSn;

[0105] (2) Place the above mixture under oxygen-enriched conditions and heat it at 60°C for 2 minutes to cause the liquid metal GaInSn to oxidize, and the mass ratio of the liquid metal GaInSn oxide to the liquid metal GaInSn is 2:100;

[0106] (3) polyacrylamide-based gel substrate is provided, and the mixture is used as a 3D printing slurry, and the mixture is drawn on the top surface of the polyacrylamide-based gel substrate by a 3D printer nozzle;

[0107] (4) Immerse the bottom surface of the gel substrate in the dilute sulfuric acid solution for 1 hour, so that the dilute sulfuric acid solution slowly consumes the liquid metal GaInSn and its ...

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Abstract

The invention provides a preparation method of functional gel, which comprises the following steps: mixing functional filler with liquid metal to obtain a mixture; providing a gel substrate, and forming a prefabricated pattern layer on the surface of the gel substrate by taking the mixture as a raw material, with the prefabricated pattern layer comprising a sacrificial layer and a functional filler dispersed in the sacrificial layer, and the sacrificial layer comprising an oxide of a liquid metal; providing an etching solution, enabling the etching solution to react with the sacrificial layerto remove the sacrificial layer, enabling the functional filler to be deposited on the surface of the gel substrate to form a pattern layer, and obtaining the functional gel. The invention further provides the functional gel and application, due to the fact that the viscosity of the oxide of the liquid metal is large, the liquid metal can be stably attached to the surface of the gel substrate, then the sacrificial layer is consumed, conformal deposition of the functional filler on the surface of the gel substrate is achieved, and the functional gel with the stable structure is obtained. The preparation method can overcome the difficulty that the gel substrate cannot be patterned through a common semiconductor means.

Description

technical field [0001] The invention relates to the technical field of flexible electronics, in particular to a functional gel, its preparation method and application. Background technique [0002] The gel substrate (Hydrogel) has a three-dimensional network structure, which can rapidly swell and not dissolve in the dispersion medium. Due to the existence of the cross-linked network, the gel substrate can swell and retain a large amount of dispersion medium, and the absorption of the dispersion medium is related to the concentration of the gel. The degree of cross-linking of the adhesive substrate is closely related. Generally, the higher the degree of cross-linking of the gel substrate, the lower the retention of the dispersion medium. The aggregation state of the gel substrate is neither completely solid nor completely liquid. The behavior of the solid state is that it can maintain a certain shape and volume under certain conditions and has a certain mechanical strength. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L25/16H01L23/31H01L21/56
CPCH01L21/56H01L23/3107H01L25/16
Inventor 冯雪张柏诚刘兰兰付浩然蒋晔陈颖
Owner INST OF FLEXIBLE ELECTRONICS TECH OF THU ZHEJIANG
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