Porous catalytic honeycomb pottery material, multifunctional porous catalytic honeycomb pottery material and preparation method of porous catalytic honeycomb pottery material and multifunctional porous catalytic honeycomb pottery material
A multifunctional, honeycomb technology, used in chemical instruments and methods, ceramic products, separation methods, etc., to achieve high catalytic efficiency, improved purification efficiency, and high specific surface area.
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[0059] The present invention also provides a method for preparing the porous catalytic honeycomb ceramic material as described in any one of the above technical solutions, comprising the following steps:
[0060] Weigh nano low-temperature frit glaze, attapulgite, modified diatomite and modified tourmaline powder in parts by weight, add appropriate amount of lubricant and water, mix by ball milling for 3-10 hours, extrude and form at 100-120°C After drying for 2-10 hours under high temperature, it is sintered at 750-850° C. to obtain a porous catalytic honeycomb ceramic material.
[0061] In this step, after preparing the raw materials, add an appropriate amount of lubricant and water to the raw materials, use a ball mill with the ball as stone for ball milling and mixing, use a general extrusion molding method for molding, and perform low-temperature sintering after drying, which can effectively meet the requirements of diatomite. Amorphization, not greatly sacrificing the am...
Embodiment 1
[0069] Weigh 27 parts of nano low-temperature frit glaze, 40 parts of attapulgite, 25 parts of modified diatomite and 5 parts of modified tourmaline powder by weight, add an appropriate amount of lubricant, and use a ball mill with a ball as a stone to mill the above raw materials After mixing for 3 hours, extrusion molding, drying at 100° C. for 8 hours, calcining at 750° C., and keeping at this temperature for 1 hour to obtain a porous catalytic honeycomb ceramic material.
[0070] The calcined porous pottery particles are immersed in 3 parts by weight of tetrabutyl titanate, taken out after saturation, dried and then calcined and decomposed at 400°C. The pores or surfaces of the pottery particles are covered with a nano-titanium oxide layer to obtain multifunctional porous ceramic particles. Catalytic honeycomb ceramic material with a pore size of about 0.5-10mm.
[0071] Performance Testing:
[0072] The obtained multifunctional porous catalytic honeycomb pottery material...
Embodiment 2
[0076]Weigh 25 parts of nano low-temperature frit glaze, 25 parts of attapulgite, 30 parts of modified diatomite and 20 parts of modified tourmaline powder by weight, add an appropriate amount of lubricant, and use a ball mill with a ball as a stone to mill the above raw materials After mixing for 5 hours, extrusion molding, drying at 110° C. for 5 hours, calcining at 800° C., and maintaining at this temperature for 2 hours, a porous catalytic honeycomb ceramic material was obtained.
[0077] Immerse the calcined porous pottery plate into 2 parts by weight of a true solution of saturated concentration prepared by ammonium metatungstate and praseodymium nitrate composite material, take it out after saturation, dry it, and then calcine and decompose it at 500°C. The pores or the surface are covered with a nano-tungsten oxide / nano-praseodymium oxide layer to obtain a multifunctional porous catalytic ceramic plate with a pore diameter of about 300nm and a size of 20×20×2.5cm.
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