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PETG blow molded bottle matte glass effect color masterbatch and preparation method thereof

A glass effect and color masterbatch technology is applied in the field of PETG bottle blowing matte glass effect color masterbatch and its preparation. The effect of smooth surface, increased production process and production cost

Inactive Publication Date: 2019-11-08
中山市正合色彩资源有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The above prior art adds mica powder and mica flakes to the PET base material, although it can achieve frosted or matte effects on the PET material, but it does not take into account the performance loss of the material after adding large particle size mica, and This kind of frosted or matte effect will appear rough and uneven on the surface of the product and increase the chance of product explosion in practical applications, so it cannot completely replace the existing frosted spraying technology

Method used

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  • PETG blow molded bottle matte glass effect color masterbatch and preparation method thereof
  • PETG blow molded bottle matte glass effect color masterbatch and preparation method thereof

Examples

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preparation example Construction

[0050] The preparation method of PETG bottle blowing matte glass effect color masterbatch of the present invention comprises the following steps:

[0051] (1) Dry all raw materials at 80°C for 2 hours for later use;

[0052] (2) Put PETG, white carbon black, and silicone light diffusing agent into a high-speed mixer and mix for 3-10 minutes at a speed of 1200-1500rpm / min, then add fluorphlogopite powder, antioxidant, and UV absorber according to the formula , PMMA and compatibilizer are mixed at a low speed of 400rpm / min for 1 to 3 minutes to obtain a mixed material;

[0053](3) Select a high-speed twin-screw extruder with a screw length-to-diameter ratio of 1:44, set the host speed of the high-speed twin-screw extruder to 450-600rpm / min, and the feeding speed to 350-410rpm / min, set The temperature of the high-speed twin-screw extruder is 190 °C in the first zone, 230 °C in the second area, 240 °C in the third area, 240 °C in the fourth area, 240 °C in the fifth area, 240 °C ...

Embodiment 1

[0068] No organic silicon light diffusing agent was added in Example 1, the amount of mica powder was larger than that of Example 3, and the light transmittance and haze were both smaller than that of Example 3.

Embodiment 2

[0069] No PMMA was added in Example 2, resulting in lower light transmittance and haze than Example 3.

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PUM

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Abstract

The invention discloses a PETG blow molded bottle matte glass effect color masterbatch and a preparation method thereof. The raw materials include: PETG, fluorophlogopite powder, an organosilicon light diffusing agent, white carbon black, pentaerythritol tetrastearate, an antioxidant, an ultraviolet absorbent, PMMA, a compatibilizer and a high temperature resistant solvent dye. The invention creatively introduces PMMA and the light diffusing agent into frosting masterbatch, utilizes the differences of PMMA and PETG base material density and refractive index to reach an excellent frosting effect with mica powder having a particle size of less than 10microm during processing, and can guarantee no loss of PETG base material's mechanical properties. At the same time, application of the light diffusing agent can reduce the dosage of mica, and can reach the effect of enhancing the haze while improving the light transmittance of the product. Adding of the color masterbatch provided by the invention can avoid spraying, and brings a similar matte glass effect without changing the mold procedure, thus avoiding the environmental protection problem caused by spraying.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a PETG bottle blowing matte glass effect color masterbatch and a preparation method thereof. Background technique [0002] If PETG bottle blowing is used in daily chemical packaging, if a matte glass effect is required (that is, the appearance of the bottle has a glass matte effect visually to improve product quality and gain consumers' favor and increase purchase desire), it is necessary to spray matte on the blown bottle Oil secondary processing, or the original mold needs to be sand blasted (after sand blasting, if the mold needs a smooth surface, it needs to be modified). [0003] Chinese patent CN102417696A discloses a method for making a frosted bottle body, comprising the following steps: mixing mica particles and PET plastics in proportion, adding an appropriate amount of about 5% additives (antioxidant, dispersant) to improve the mica powder Fluidity, the above-mentione...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08L33/12C08L83/04C08L25/06C08L51/06C08K13/02C08K3/34C08K3/36C08K5/134C08K5/526C08K3/30C08K5/132C08J3/22
CPCC08J3/226C08J2367/02C08J2425/06C08J2433/12C08J2451/06C08J2483/04C08K3/34C08K3/36C08K5/132C08K5/1345C08K5/526C08K13/02C08K2003/3045C08K2201/011
Inventor 陈旭升张宇刘刚
Owner 中山市正合色彩资源有限公司
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