A compound of metal-organic framework encapsulating corrosion inhibitor and its preparation method and application
A metal-organic framework and corrosion-inhibitor technology, which is applied in the field of metal-organic framework-encapsulated corrosion-inhibitor composites and the field of preparation thereof, can solve the problems of lack of water stability and acid-sensitive dissociation, and achieve high yield and high Anti-corrosion efficiency and the effect of less dosage
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Embodiment 1
[0047] Preparation of ZIF-67 Encapsulated Copper Ion Modified Thiazole Corrosion Inhibitor Complex
[0048] The first step: preparation of copper ion-modified 2-mercapto-1,3,4-thiadiazole precursor:
[0049] Firstly, 3.95g of Tris base was dissolved in 13mL of deionized water, then the volume was adjusted to 25mL with deionized water, and then the pH was adjusted to 8.8 with ammonium chloride to obtain a buffer solution. At room temperature, 69 mg (0.41 mmol) of 2-mercapto-1,3,4-thiadiazole and 50 mg (0.21 mmol) of copper nitrate trihydrate (2-mercapto-1,3,4-thiadiazole and copper nitrate The molar ratio of trihydrate (about 2:1) was added to the buffer solution together, and stirred at room temperature for 30 minutes to obtain a copper ion-modified thiazole-containing corrosion inhibitor precursor with a yield of 83%.
[0050] The above 2-mercapto-1,3,4-thiadiazole and copper nitrate trihydrate are in the molar ratio of 2 to 4:1, copper ion and 2-mercapto-1,3,4-thiadiazole a...
Embodiment 2
[0057] Preparation of ZIF-67 Encapsulated Copper Ion Modified Thiazole Corrosion Inhibitor Complex
[0058] The first step: preparation of copper ion-modified 2-mercapto-1,3,4-thiadiazole precursor:
[0059] Firstly, 3.95g of Tris base was dissolved in 13mL of deionized water, then the volume was adjusted to 25mL with deionized water, and then the pH was adjusted to 8.8 with ammonium chloride to obtain a buffer solution. Mix 104 mg (0.62 mmol) 2-mercapto-1,3,4-thiadiazole with 50 mg (0.21 mmol) copper nitrate trihydrate (2-mercapto-1,3,4-thiadiazole and copper nitrate The molar ratio of trihydrate is about 3:1) was added to the above buffer solution, and stirred at room temperature for 30 minutes to obtain the copper ion-modified thiazole-containing corrosion inhibitor precursor with a yield of 88%.
[0060] The above 2-mercapto-1,3,4-thiadiazole and copper nitrate trihydrate are in the molar ratio of 2 to 4:1, copper ion and 2-mercapto-1,3,4-thiadiazole active group Both of...
Embodiment 3
[0067] Preparation of ZIF-67 Encapsulated Copper Ion Modified Thiazole Corrosion Inhibitor Complex
[0068] The first step: preparation of copper ion-modified 2-mercapto-1,3,4-thiadiazole precursor:
[0069]Firstly, 3.95g of Tris base was dissolved in 13mL of deionized water, then the volume was adjusted to 25mL with deionized water, and then the pH was adjusted to 8.8 with ammonium chloride to obtain a buffer solution. Mix 138mg (0.83mol) 2-mercapto-1,3,4-thiadiazole with 50mg (0.21mol) copper nitrate trihydrate (2-mercapto-1,3,4-thiadiazole and copper nitrate The trihydrate molar ratio is about 4:1) was added to the above buffer solution together, and stirred at room temperature for 30 minutes to obtain a copper ion-modified thiazole-containing corrosion inhibitor precursor with a yield of 85%.
[0070] The above 2-mercapto-1,3,4-thiadiazole and copper nitrate trihydrate are in the molar ratio of 2 to 4:1, copper ion and 2-mercapto-1,3,4-thiadiazole active group Both of th...
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