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Preparation method of efficient condensation hydrophilic and hydrophobic thin-film coating with multi-scale structure

A hydrophilic-hydrophobic, multi-scale technology, applied in the direction of coating, etc., can solve the problem that the condensation performance of the super-hydrophobic wall surface is difficult to further improve, and achieve the effects of improving condensation efficiency, low reaction temperature, and low energy consumption

Active Publication Date: 2019-10-25
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, the advantages of superhydrophobic walls in controlling droplet fusion and shedding and enhancing droplet condensation have attracted the attention of researchers. However, the extremely low surface energy of superhydrophobic walls forms a high energy barrier for droplet nucleation. Make it difficult to further improve the condensation performance of the super-hydrophobic wall surface

Method used

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  • Preparation method of efficient condensation hydrophilic and hydrophobic thin-film coating with multi-scale structure
  • Preparation method of efficient condensation hydrophilic and hydrophobic thin-film coating with multi-scale structure
  • Preparation method of efficient condensation hydrophilic and hydrophobic thin-film coating with multi-scale structure

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preparation example Construction

[0043] The invention provides a preparation method of a high-efficiency condensation hydrophilic and hydrophobic film coating with multi-scale structure, such as figure 1 shown, including:

[0044] Step 101, preparing a titanium dioxide film with a micron and nanometer secondary composite structure on a glass substrate;

[0045] Step 102, modifying the titanium dioxide film;

[0046] In step 103, a combined hydrophilic and hydrophobic surface is prepared by using an ultraviolet mask photolithography method.

Embodiment

[0049] Step 1: Preparation of TiO2 Thin Films with Micro- and Nano-Secondary Composite Structures

[0050] First, the surface of the glass substrate is treated by a plasma cleaner, and the cleaned glass sheet is placed in a solution of concentrated sulfuric acid: hydrogen peroxide solution = 7:3 (volume ratio), kept in a vacuum drying box at 80 °C for 2 hours, and high-purity water is used. Rinse, place it in an ultrasonic cleaner for 15 minutes, rinse with high-purity water, and finally dry it with high-purity nitrogen for use.

[0051] Put 1 mol / L titanium trichloride solution and add an appropriate amount of sodium chloride and pre-treated glass sheets together into a reaction kettle containing a polytetrafluoroethylene lining (a custom-made bracket is set in the lining, and glass sheets are added. stability in the reactor), uniformly heated from 90°C to 160°C, heating rate of about 1.2°C / min, kept at 160°C for 2 hours, cooled to room temperature, taken out, rinsed slowly w...

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Abstract

The invention discloses a preparation method of an efficient condensation hydrophilic and hydrophobic thin-film coating with a multi-scale structure, and belongs to the field of thin-film coating preparation methods. The preparation method comprises the steps: a titanium dioxide thin film with a micrometer and nanometer secondary composite structure is prepared on a glass substrate; the titanium dioxide thin film is modified; and a hydrophilic and hydrophobic combined surface is prepared through ultraviolet mask photolithography. The titanium dioxide microspheric thin film prepared through in-situ growth of a hydrothermal method is good in structure, good in uniformity and compactness, high in purity, low in cost, easy in technological operation, low in reaction temperature and less in energy consumption, hydrophilic and hydrophobic areas prepared by combining with vapor deposition and the ultraviolet mask photolithography are regularly arrayed, wall surfaces have micrometer, nanometerand millimeter scale multi-stage feature structures and have very high photoresponse regulable and controllable characteristics, and by regulating and controlling the width and number of the hydrophilic and hydrophobic areas with the millimeter-scale surfaces, the hydrophilic and hydrophobic heterogeneous combined surface with high condensation efficiency is prepared.

Description

Technical field: [0001] The invention belongs to the field of thin-film coating preparation methods, and in particular relates to a preparation method of a high-efficiency condensation hydrophilic and hydrophobic thin-film coating with a multi-scale structure regulated by light response. Background technique: [0002] When steam condenses, it will release a lot of latent heat, so its heat transfer performance has great application potential in refrigeration, thermal power generation, petrochemical, aerospace, micro-phase change thermal control devices and other fields. In recent years, the advantages of superhydrophobic walls in controlling droplet fusion and shedding and enhancing droplet condensation have attracted the attention of researchers. However, the extremely low surface energy of superhydrophobic walls forms a high energy barrier to droplet nucleation. This makes it difficult to further improve the condensation performance of superhydrophobic walls. Inspired by t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/25C03C17/42
CPCC03C17/256C03C17/42C03C2217/212C03C2218/111C03C2218/15C03C2218/33
Inventor 刘灯辉黄志冯妍卉张欣欣
Owner UNIV OF SCI & TECH BEIJING
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