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Silane cross-linking semi-conductive inner shielding material and production process thereof

A technology of silane crosslinking and production process, which is applied in the field of cable materials, can solve the problems of resin crosslinking, high temperature control of equipment, high reaction temperature, etc.

Inactive Publication Date: 2019-09-27
FAR EAST CABLE +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most silane cross-linking shielding materials are prepared by mixing graft A material and catalytic B material to prepare silane cross-linking semi-conductive shielding materials. The preparation of A material is the reaction of grafted silane triggered by peroxide, and the reaction temperature is relatively high. If it is higher than 200°C, high temperature control of the equipment is required. In addition, the introduction of peroxide will cause some resins to cross-link and produce coke, which requires regular shutdown to clean the coke in the equipment and other problems.

Method used

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  • Silane cross-linking semi-conductive inner shielding material and production process thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The production process of the silane cross-linked semi-conductive inner shielding material in this embodiment adopts high-conductivity A material and catalytic B material to be mixed and co-extruded and then cross-linked in warm water.

[0026] In parts by weight, 40 parts of ethylene-vinyl acetate copolymer, 60 parts of ethylene-vinyl silane copolymer, 60 parts of high-conductivity carbon black, 2 parts of EBS, 10 parts of white oil and 1 part of antioxidant 1010 are automatically metered The device automatically feeds the material into the single screw of the reciprocating machine to extrude and granulate to prepare high-conductivity A material. The temperature of the reciprocating machine shaft is 50°C, the first zone is 70°C, the second zone is 90°C, the third zone is 115°C, the temperature of the single screw mandrel is 40°C, the first zone is 90°C, the second zone is 120°C, and the head is 140°C.

[0027] In parts by weight, 100 parts of ethylene-vinyl acetate cop...

Embodiment 2

[0030] The silane cross-linked semiconductive inner shielding material of the present embodiment and its production process steps are as follows: in parts by weight, 50 parts of ethylene-vinyl acetate copolymer, 50 parts of ethylene-vinyl silane copolymer, and 55 parts of high-conductivity carbon black , 1 part of EBS, 8 parts of white oil and 0.8 part of antioxidant 1010 are passed through the automatic metering device, and the materials are automatically fed into the single screw of the reciprocating machine for extrusion and granulation to prepare high-conductivity A material. The temperature of the reciprocating machine shaft is 50°C, the first zone is 70°C, the second zone is 90°C, the third zone is 115°C, the temperature of the single screw mandrel is 40°C, the first zone is 90°C, the second zone is 120°C, and the head is 140°C.

[0031] In parts by weight, 100 parts of ethylene-vinyl acetate copolymer, 1 part of dibutyltin dilaurate, and 10101 parts of antioxidant are pa...

Embodiment 3

[0034] The production process steps of the silane cross-linked semiconductive inner shielding material of the present embodiment are as follows: in parts by weight, 50 parts of ethylene-vinyl acetate copolymer, 40 parts of ethylene-vinylsilane copolymer, and 70 parts of high-conductivity carbon black , 2 parts of EBS, 12 parts of white oil and 1.2 parts of antioxidant 1010 are passed through the automatic metering device, and the materials are automatically fed into the single screw of the reciprocating machine for extrusion and granulation to prepare high-conductivity A material. The temperature of the reciprocating machine shaft is 50°C, the first zone is 70°C, the second zone is 90°C, the third zone is 115°C, the temperature of the single screw mandrel is 40°C, the first zone is 90°C, the second zone is 120°C, and the head is 140°C.

[0035] In parts by weight, 100 parts of ethylene-vinyl acetate copolymer, 3 parts of dibutyltin dilaurate, and 10100.5 parts of antioxidant ar...

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Abstract

The invention discloses a silane cross-linking semi-conductive inner shielding material and a production process thereof. The production process comprises the following steps: preparing a high-conductivity material A; preparing a catalytic material B; mixing and extruding the high-conductivity material A and the catalytic material B into a mixture; performing warm water crosslinking on the mixture to obtain a finished product. In a manufacturing process of the high-conductivety material A, an ethylene- vinyl silane copolymer is subjected to warm water cross-linking, so silane grafting reaction in a traditional process is avoided, the reaction temperature is within 140 DEG C, no coke is produced, the production continuity is good, the stability is high, the energy consumption is low, continuous production can be realized without stopping, periodically shutting down equipment to clear the coke in the equipment is not needed, a prepared cable material is excellent in mechanical and insulating properties and semi-conductivity, which is conducive to improving the transmission capacity of a power grid, improving the wind resistance of a line, and improving and enhancing the safety and reliability of a distribution system.

Description

technical field [0001] The invention relates to a cable material, in particular to a silane cross-linked semi-conductive inner shielding material and a production process thereof. Background technique [0002] With the rapid development of the national economy, the development of the power grid is advancing by leaps and bounds, and higher requirements are put forward for the reliability of power supply. The use of overhead insulated cables is becoming more and more common, and the proportion of lines is increasing. The use of overhead insulated cables is conducive to improving the power transmission capacity of the power grid, improving the wind resistance of the line, improving and enhancing the safety and reliability of the power distribution system, and improving the power supply utilization rate of the line; it is conducive to urban construction and greening work, and reduces the pruning of trees along the line Reduce the amount of trees touching the wires, causing short...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08K3/04B29B9/06B29B9/12
CPCB29B9/06B29B9/12C08K2201/001C08L23/0853C08L23/0892C08L2203/202C08L2205/025C08L2205/03C08L2312/08C08K3/04C08L23/0869
Inventor 曾泽华徐静毛梦颖王射林
Owner FAR EAST CABLE
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