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Magnesium alloy with high yield strength and corrosion resistance and preparation method thereof

A high corrosion resistance, magnesium alloy technology, applied in the preparation of corrosion resistant magnesium alloy, high yield strength, corrosion resistant magnesium alloy field, can solve the problems of high yield strength, corrosion resistance, high price, and increase the production cost of magnesium alloy , to achieve high yield strength and tensile strength, improve toughness and yield strength, and reduce micro-segregation

Pending Publication Date: 2019-09-17
CHINA WEAPON SCI ACADEMY NINGBO BRANCH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] For example, the Chinese invention patent "A High Yield Ratio Deformed Magnesium Alloy Containing Rare Earth Cerium and Yttrium" with the patent No. CN201410210886.2 (authorized announcement No. CN103952613A), in which rare earth elements are added, the addition of rare earth elements can effectively The yield strength of the magnesium alloy is greatly improved, and the purity of the alloy itself will also be significantly improved, but the price of the rare earth is relatively high, and a large amount of addition will greatly increase the production cost of the magnesium alloy
In addition, it is difficult for the existing magnesium alloys to ensure that the magnesium alloys have high yield strength and good corrosion resistance while ensuring low production costs.

Method used

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  • Magnesium alloy with high yield strength and corrosion resistance and preparation method thereof
  • Magnesium alloy with high yield strength and corrosion resistance and preparation method thereof
  • Magnesium alloy with high yield strength and corrosion resistance and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The high-yield strength and corrosion-resistant magnesium alloy of this embodiment includes the following components and their weight percentages: Zn 6%, Al 1.5%, Mn 0.3%, Ca 0.4%, Y 0.01%, Gd 0.2% and the rest Mg; the composition and weight percentage of impurities in the magnesium alloy are Fe≤0.01, Cu≤0.01, Ni≤0.00.5, Zn / Al mass ratio is I, 4<I≤6.5.

[0033] The preparation method of the above-mentioned high yield strength and corrosion-resistant magnesium alloy comprises the following steps:

[0034] (1) Alloy melting and casting

[0035] Under the protection of SF6+CO2 gas or under the special solvent for magnesium alloy, heat the industrial magnesium ingot in a resistance crucible furnace, heat it up to 750°C after melting, remove the slag, and then add zinc ingot, and quickly dissolve the zinc ingot when adding Press it below the surface of the molten magnesium, stir for 2-5 minutes after the zinc ingot is melted, make it evenly mixed, and let it stand for 15 mi...

Embodiment 2

[0045]The high yield strength and corrosion-resistant magnesium alloy of this embodiment includes the following components and their weight percentages: Zn 6.5%, Al 1.5%, Mn 0.4%, Ca 0.5%, Y 0.2%, Gd0.01% and the balance of Mg ; The composition and weight percentage of impurities in the magnesium alloy are Fe≤0.01, Cu≤0.01, Ni≤0.005, Zn / Al mass ratio is I, 4<I≤6.5.

[0046] The preparation method of the above-mentioned high yield strength and corrosion-resistant magnesium alloy comprises the following steps:

[0047] (1) Alloy melting and casting

[0048] Under the protection of SF6+CO2 gas, heat the industrial magnesium ingot in a resistance crucible furnace, heat it up to 750°C after melting, remove the slag, then add zinc ingot, and press the zinc ingot into the magnesium melt quickly when adding Below the surface, after the zinc ingot is melted, stir for 2-5 minutes to make it mix evenly, and let it stand for 15 minutes; then add aluminum ingot, aluminum-manganese master ...

Embodiment 3

[0057] The high yield strength and corrosion-resistant magnesium alloy of this embodiment includes the following components and their weight percentages: 5.5% Zn, 1.0% Al, 0.2% Mn, 0.6% Ca, 0.2% Y, 0.2% Gd and the rest of Mg ; The composition and weight percentage of impurities in the magnesium alloy are Fe≤0.01, Cu≤0.01, Ni≤0.005, Zn / Al mass ratio is I, 4<I≤6.5.

[0058] The preparation method of the above-mentioned high yield strength and corrosion-resistant magnesium alloy comprises the following steps:

[0059] (1) Alloy melting and casting

[0060] Under the protection of SF6+CO2 gas, heat the industrial magnesium ingot in a resistance crucible furnace, heat it up to 800°C after melting, remove the slag, then add zinc ingot, and press the zinc ingot into the magnesium melt quickly when adding Below the surface, after the zinc ingot is melted, stir for 2-5 minutes to make it mix evenly, and let it stand for 15 minutes; then add aluminum ingot, aluminum-manganese master al...

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Abstract

The invention relates to a magnesium alloy with high yield strength and corrosion resistance. The magnesium alloy is characterized by comprising the following components in percentage by weight: 5-6.5% of Zn, 1.0-1.5% of Al, 0.2-0.4% of Mn, 0.3-0.6% of Ca, 0.01-0.2% of Y, 0.01-0.2% of Gd and the balance Mg and inevitable impurities, wherein the sum of the weight percentages of Y and Gd in the magnesium alloy is that Y plus Gd is greater than or equal to 0.2% and less than or equal to 0.4%. The invention also relates to a preparation method. Zinc, aluminum, calcium and trace rare earth elements namely yttrium and gadolinium are added to the magnesium alloy, and the addition of calcium can refine magnesium alloy crystal grains and precipitated tissues, and the improvement of subsequent yield strength and tensile strength is facilitated; the trace rare earth elements namely yttrium and gadolinium form a intermetallic compound with aluminum to provide a dispersion nucleation condition for the crystal grains, so that the refinement of a crystal grain structure and improvement of toughness and yield strength of the magnesium alloy are facilitated; and by controlling the percentage content of trace rare earth elements namely yttrium and gadolinium, the corrosion resistance is good while the cost is reduced and higher tensile strength and yield strength are obtained.

Description

technical field [0001] The invention relates to the technical field of magnesium alloy materials, in particular to a high-yield strength and corrosion-resistant magnesium alloy, and also relates to a preparation method of the high-yield strength and corrosion-resistant magnesium alloy. Background technique [0002] Magnesium was discovered for the first time in 1774. It has high specific strength, specific stiffness, excellent damping performance, and many advantages such as antimagnetic, shielding, heat dissipation, easy cutting, easy recycling, etc. It is currently widely used in automobiles and motorcycles Such as transportation, computer, communication, instrumentation, home appliances, metallurgy, aerospace, national defense and military industry and other departments. However, the low absolute strength of magnesium alloys limits its further application in the field of structural materials. [0003] Yield strength is an important parameter to measure the performance of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C23/04C22C1/03C22F1/06
CPCC22C1/03C22C23/04C22F1/06
Inventor 王荣乐启炽朱秀荣王恩刚任政王志峰王军宋运坤庞松郭红燕徐国辉
Owner CHINA WEAPON SCI ACADEMY NINGBO BRANCH
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