Preparation method of solid-state lithium ion battery comprising solid electrolyte

A technology of lithium-ion batteries and solid-state electrolytes, which is applied in the manufacture of electrolyte batteries, non-aqueous electrolyte batteries, and solid electrolytes. Improvement and enhancement of room temperature conductivity and reduction of dry environment requirements

Active Publication Date: 2019-09-06
TIANJIN LISHEN BATTERY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Therefore, in view of the low conductivity and poor interface contact of the polymer solid electrolyte used in solid-state batteries, there is an urgent need for a solid-state electrolyte technology to improve the room-temperature conductivity of the solid-state electrolyte and realize the connection between the solid-state electrolyte and the electrode active material. , and the soft contact between the solid electrolyte and the electrode, to solve the problem of the solid-solid interface between the solid electrolyte and the electrode active material and between the solid electrolyte and the electrode
In addition, the harsh manufacturing environment of the solid-state battery manufacturing process needs to be improved urgently

Method used

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  • Preparation method of solid-state lithium ion battery comprising solid electrolyte
  • Preparation method of solid-state lithium ion battery comprising solid electrolyte
  • Preparation method of solid-state lithium ion battery comprising solid electrolyte

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preparation example Construction

[0036] see figure 1 , the present invention provides a preparation method of a solid-state lithium-ion battery containing a solid-state electrolyte, adopting the synergistic effect of double in-situ reaction, solidifying the liquid electrolyte monomer in-situ in the solid-state battery, and realizing the double-in-situ reaction technology in the solid state The application in the battery specifically includes the following steps:

[0037] The first step, the polymer monomer 1,3-dioxolane and the first lithium salt are dissolved in a volatile small molecule solvent to prepare the first mixed solution (that is, the polymer monomer and the first lithium salt mixed solution);

[0038] In the second step, the polymerization initiator and the second lithium salt are dissolved in a volatile small molecule solvent to prepare a polymerization initiation solution;

[0039] In the third step, tetraethyl orthosilicate and the third lithium salt are dissolved in formic acid to prepare th...

Embodiment 1

[0070] In Example 1, a method for preparing a solid-state lithium-ion battery comprising a solid-state electrolyte provided by the present invention specifically includes the following steps:

[0071] The first step, preparing polymer monomer 1,3-dioxolane and the first lithium salt mixed solution (i.e. the first mixed solution) 100g, wherein, containing 80g polymer monomer 1,3-dioxolane, And 20g lithium salt LiTFSI, stand-by.

[0072] Second step, get 10g tetraethyl orthosilicate and dissolve in 80g formic acid, and mix the 3rd lithium salt LiFSI of 10g, be mixed with the mixed solution of the 3rd lithium salt, tetraethyl orthosilicate and formic acid (being the second Mixed solution), the mass percent content is: tetraethyl orthosilicate is 10%, the third lithium salt is 10%, formic acid is 80%, stand-by.

[0073] The third step, according to the required composite solid electrolyte formula, mix the first mixed solution obtained in the first step and the second mixed soluti...

Embodiment 2

[0078] In Embodiment 2, a method for preparing a solid-state lithium-ion battery comprising a solid-state electrolyte provided by the present invention specifically includes the following steps:

[0079] The first step is to prepare 100 g of polymer monomer 1,3-dioxolane solution for use.

[0080] In the second step, the LiTFSI lithium salt and the polymerization initiator aluminum trifluoromethanesulfonate Al(OTf) 3 Dissolved in formic acid, prepared as a polymerization initiator solution, the mass content of LiTFSI is 0-30%, aluminum trifluoromethanesulfonate Al(OTf) 3 The concentration is 0.01M, ready to use.

[0081] The third step, take 1g of tetraethyl orthosilicate and dissolve it in 99g of formic acid to prepare a mixed solution (i.e. the second mixed solution) of tetraethyl orthosilicate and formic acid, mass percentage: tetraethyl orthosilicate Ethyl ester is 1%, formic acid is 99%, and it is ready for use.

[0082] The fourth step, according to the required compo...

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Abstract

The invention discloses a preparation method of a solid-state lithium ion battery comprising a solid electrolyte; the preparation method comprises the following steps of step 1, enabling a polymer monomer 1, 3-dioxolane and a first lithium salt to be dissolved in a small molecular solvent to prepare a first mixed solution; step 2, dissolving a polymerization reaction initiator and a second lithiumsalt to be dissolved in a in a small molecular solvent to prepare a polymerization reaction initiator liquid; step 3, dissolving tetraethyl orthosilicate and a third lithium salt into formic acid toprepare a second mixed solution; step 4, mixing the first mixed solution, the polymerization reaction initiator liquid and the second mixed solution to obtain a solid electrolyte solution; and step 5,injecting the solid electrolyte solution into a pre-prepared solid lithium ion battery which is not sealed and is not injected with an electrolyte, then drying, and sealing to obtain the assembled solid-state lithium ion battery. According to the preparation method, the room temperature electrical conductivity of the solid electrolyte can be improved, and the problem of poor interface contact ofthe solid electrolyte can be effectively solved.

Description

technical field [0001] The invention relates to the technical field of lithium ion batteries, in particular to a preparation method of a solid lithium ion battery containing a solid electrolyte. Background technique [0002] At present, lithium-ion batteries have the advantages of high voltage, high specific energy, many cycle times, and long storage time. They are widely used in consumer electronics, new energy vehicles, and energy storage. The electrical performance, service life and The study of safety performance is extremely important. [0003] For solid-state lithium-ion batteries, their high energy density and high safety have attracted much attention. In terms of the safety performance of the battery cell, traditional lithium-ion batteries have safety risks of leakage, fire, combustion, or even explosion, while solid-state lithium-ion batteries use solid-state or solid-state electrolytes, which reduce the risk of leakage, fire, combustion, and even explosion. secur...

Claims

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Application Information

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IPC IPC(8): H01M10/058H01M10/0565H01M10/0525
CPCH01M10/058H01M10/0565H01M10/0525H01M2300/0082Y02E60/10Y02P70/50
Inventor 孟繁慧郑涛刘婧谢富国周江伍绍中
Owner TIANJIN LISHEN BATTERY
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