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A method for improving the hardness of spherical calcium chloride produced by acid calcium method

A technology of calcium chloride and calcium acid, applied in the direction of calcium/strontium/barium chloride, calcium/strontium/barium halide, etc., can solve the problems of prolonged production cycle, rising production cost and equipment repair cost, etc. The effect of forming rate, reducing product cost and improving hardness

Active Publication Date: 2022-02-08
青岛海湾集团有限公司 +1
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Problems solved by technology

In the production process of the existing conventional spherical calcium chloride, the hardness of the final product is usually improved by increasing sodium chloride in the dust removal process, but the calcium chloride content in the calcium chloride solution generated by the calcium acid reaction is generally about 37%. The same ion effect of chloride ion, sodium chloride solid is difficult to dissolve in this calcium chloride solution, in order to improve the content of sodium chloride in the final product, increase the sodium chloride content in the calcium chloride solution, just need to chlorine Warming the calcium chloride solution and adding a large volume of dissolving equipment, by prolonging the dissolution time for 4-8 hours to fully dissolve the added sodium chloride solid in the calcium chloride solution, resulting in a longer production cycle, production costs and equipment repair costs rise

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  • A method for improving the hardness of spherical calcium chloride produced by acid calcium method
  • A method for improving the hardness of spherical calcium chloride produced by acid calcium method
  • A method for improving the hardness of spherical calcium chloride produced by acid calcium method

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Embodiment Construction

[0013] The technical process of the present invention will be further described in detail in conjunction with specific applications below.

[0014] In the process of producing spherical calcium chloride in the existing conventional technology, it includes hydrochloric acid and limestone reacting to generate calcium chloride solution, namely calcium acid reaction process of calcium water, two-effect evaporation process, dust removal process, evaporation calcium production process and feeding into fluidized bed In the granulation process of forming spherical calcium chloride, the hardness and density of calcium chloride particles with higher purity are not high, and they are easy to pulverize, resulting in a low granulation rate of spherical calcium chloride in the final product. The first test and the actual verification of on-site production show that when more than 1.9% sodium chloride is added to the spherical calcium chloride, the hardness of the spherical calcium chloride p...

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Abstract

The invention provides a method for improving the hardness of spherical calcium chloride produced by the acid calcium method. The process for producing spherical calcium chloride by the acid calcium method includes a calcium acid reaction process and a double-effect evaporation process in which hydrochloric acid reacts with limestone to form a calcium chloride solution. , dust removal process, evaporation calcium production process and granulation process, before the acid calcium reaction process, there is also a mixing process, in the mixing process, limestone and sodium chloride solid particles are mixed and then sent to the acid calcium reaction process, adding hydrochloric acid, Generate a calcium chloride solution containing sodium chloride, and then enter other processes in sequence to finally generate spherical calcium chloride particles.

Description

technical field [0001] The invention relates to the production technical field of calcium chloride, in particular to a production method of spherical calcium chloride. Background technique [0002] In the prior art, the calcium chloride produced by the calcium acid method has low hardness and low density. It is necessary to add sodium chloride during the production process to make the hardness and bulk density of the spherical calcium chloride bidirectional. Therefore, controlling the content of calcium chloride in spherical calcium chloride is an important indicator to control the hardness of the product and reduce the amount of powder in the product. In the production process of the existing conventional spherical calcium chloride, the hardness of the final product is usually improved by increasing sodium chloride in the dust removal process, but the calcium chloride content in the calcium chloride solution generated by the calcium acid reaction is generally about 37%. Th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01F11/28
CPCC01F11/28C01P2004/32
Inventor 孙新德代善乐姜杰林鹏鹏石信平任兴源逄健仇广义
Owner 青岛海湾集团有限公司
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