Smelting method of electronic scraps

A technology of electronic waste and smelting methods, which is applied in the direction of improving process efficiency, etc., can solve problems such as high operation and maintenance and smelting costs, short service life of smelting equipment, and increased copper content in slag, so as to reduce heat input and reduce Energy consumption and the effect of prolonging the service life

Inactive Publication Date: 2019-08-30
SHUI KOU SHAN NONFERROUS METALS LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method uses an oxidizing agent to oxidize the aluminum in the waste and separate it from the valuable metal copper, but it does not give the specific concentration and dosage of the oxidizing agent, and the concentration and dosage of the oxidizing agent will affect the recovery rate of copper during the smelting process. High concentration and dosage will increase the oxidation amount of metal copper, thereby increasing the copper content in the slag and reducing the recovery rate of copper; and the temperature of this smelting method is too high (over 1300°C), which is not conducive to energy saving and consumption reduction, making the smelting equipment Short service life, high operation and maintenance and smelting costs

Method used

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  • Smelting method of electronic scraps
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Examples

Experimental program
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Effect test

Embodiment 1

[0034] A method for smelting electronic waste, comprising the following steps:

[0035] Electronic scrap (Cu 8.80%, Sn 4%, Fe 8%, Au 10g / t, Ag 191g / t, Pd0.11g / t, Al 0.28%, Al 2 o 3 1.28%; SiO 2 28.88%), slagging agent and coal are mixed to obtain a mixed material, in which the slagging agent is made of copper smelting slag (Cu0.35wt%, TFe26.37wt%, SiO 2 33.60%, CaO 15.91%) and dolomite (CaO 56%). In the mixed material, the mass proportion of electronic waste is 44%, the mass proportion of slagging agent is 44%, and the mass proportion of coal is 12%.

[0036]The above-mentioned mixed materials are added from the feed port 3 of the smelting zone of the blowing furnace on the oxygen-enriched side. Introduce high-concentration oxygen and low-concentration oxygen, wherein the concentration of high-concentration oxygen in smelting zone 1 is 65%, and the ratio of the oxygen supply volume to the mass of the mixed material is 855-1700m 3 氧气 / t 物料 , specifically 1000 m 3 氧气 / t...

Embodiment 2

[0040] A method for smelting electronic waste, comprising the following steps:

[0041] Electronic waste (Cu 55%, Sn 8%, Fe 12%, Au 5g / t, Ag 415g / t, Pt500g / t, Al 15%, SiO 2 8wt%), slagging agent and fuel (granulated coal and coke) are mixed to obtain a mixed material. Among them, the slagging agent is composed of limestone (CaO 90%) and silica (SiO 2 98%); in the mixed material, the mass proportion of electronic waste is 30%, and the mass proportion of fuel is 8%.

[0042] The above-mentioned mixed materials are added from the feeding port of the smelting zone of the oxygen-enriched side blowing furnace. During smelting, high-concentration oxygen and Low-concentration oxygen, in which the concentration of high-concentration oxygen in the smelting zone is 40%, and the ratio of the oxygen supply volume to the mass of the mixed material is 250-1100 m 3 氧气 / t 物料 , specifically 800 m 3 氧气 / t 物料 , the concentration of low-concentration oxygen in the fuming zone is 35%, the...

Embodiment 3

[0045] A method for smelting electronic waste, comprising the following steps:

[0046] Electronic waste (Cu 35%, Sn6%, Fe 8%, Au 5g / t, Ag 415g / t, Pt 500g / t, Al 15%, SiO 2 8wt%), slagging agent and coal are mixed to obtain a mixed material. Among them, the slagging agent is made of copper smelting slag (Cu 0.69wt%, TFe 42wt%, SiO 2 30%, CaO5%) and limestone; in the mixed material, the mass proportion of electronic waste is 55%, the mass proportion of slagging agent is 40%, and the mass proportion of fuel is 5%.

[0047] The above-mentioned mixed materials are added from the feeding port of the smelting zone of the oxygen-enriched side blowing furnace. During smelting, high-concentration oxygen and Low-concentration oxygen, in which the concentration of high-concentration oxygen in the smelting zone is 70%, and the ratio of the oxygen supply volume to the mass of the mixed material is 600-2100 m 3 氧气 / t 物料 , specifically 1500m 3 氧气 / t 物料 , the concentration of low-conc...

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Abstract

The invention discloses a smelting method of electronic scraps. The smelting method of electronic scraps comprises the following steps of 1) mixing the electronic scraps with a slag former and a fuelto obtain a mixed material; and 2) feeding the mixed material in an oxygen-enriched side converting furnace, separately introducing high concentration oxygen and low concentration oxygen in a smeltingarea and a fuming area in the oxygen-enriched side converting furnace, controlling the flue gas outlet temperatures of the smelting area and the fuming area to be 700-1250 DEG C, and performing smelting to produce Cu alloy and furnace slag, wherein the mass ratio of CaO to SiO2 in the furnace slag is larger than or equal to 0.30, the mass ratio of Fe to SiO2 is 0.05-1.0, and the content of Al2O3is smaller than or equal to 17%. The electronic scraps are smelted by adopting the oxygen-enriched side converting furnace of which the smelting area communicates with the fuming area, the high concentration oxygen and the low concentration oxygen are separately introduced in the smelting area and the fuming area, the condition that impurities enter the furnace slag after being sufficiently oxidized is ensured, loss of valuable metals (Cu, Sn and the like), caused after the valuable metals enter the furnace slag after being oxidized, is avoided, the separation efficiency of the impurities andthe alloy and the recovery rate of the valuable metal alloy are effectively improved, the separation difficulty of other impurities and the valuable metal alloy is reduced, and the smelting efficiencyis improved.

Description

technical field [0001] The invention relates to the technical fields of nonferrous metal smelting, hazardous waste treatment and resource recycling, in particular to a method for smelting electronic waste. Background technique [0002] With the continuous development of the electronics and information industry, the total amount of electronic waste is increasing. This type of electronic waste not only contains a large amount of valuable metals (such as copper, tin, iron, aluminum, lead, precious metals, etc.), but also contains a large amount of Plastics, resins, ceramics and other materials have high resource recovery value. [0003] At present, the smelting technology of electronic waste is mainly divided into fire method and wet method. Pyrochemical treatment technology is to use a high-temperature metallurgical furnace to heat the molten material, and through a series of high-temperature chemical reactions, the valuable metal enters the alloy / matte phase in the form of m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B7/00C22B15/00C22B25/02C22B25/06
CPCC22B7/004C22B15/0056C22B25/02C22B25/06Y02P10/20
Inventor 何从行肖松文张晓林任国兴白成庆潘炳付绸琳夏星付高明陈国兰
Owner SHUI KOU SHAN NONFERROUS METALS LTD
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