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Dispersion type waterborne epoxy zinc-alkene rusty, anti-rust and heavy anti-corrosion primer

A heavy-duty anti-corrosion primer and water-based epoxy technology, applied in the direction of anti-corrosion coatings, epoxy resin coatings, coatings, etc., can solve problems such as harsh construction conditions, difficult rust removal, zinc fever, etc., and achieve the effect of excellent electrical conductivity

Active Publication Date: 2018-09-14
湖北铁神新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] 1. Before the traditional anti-corrosion coating is applied again, it is necessary to use sandblasting, manual or electric tools and other derusting methods to treat the surface of the steel surface. However, some large-scale steel equipment is difficult to derust completely or even cannot derust, which affects the protection of the paint film. Function
[0003] 2. Zinc-rich heavy-duty anti-corrosion primer is one of the most important and widely used heavy-duty anti-corrosion coatings for ships, marine facilities, bridges, large-scale equipment and various large-scale building steel structures. Its anti-corrosion mechanism is based on metal zinc powder For the cathodic protection of steel, the content of zinc powder is closely related to its anti-corrosion effect, but the high content of zinc powder (60% ~ 85%) also brings many disadvantages to the zinc-rich primer: 1) The use of a large amount of zinc powder, in Zinc oxide dust and zinc vapor generated during thermal processing such as welding and cutting will affect human health and easily lead to "zinc fever"; 2) High zinc powder content leads to poor compactness and low strength of the paint film The compatibility of paint is poor; 3) The density of epoxy zinc-rich primer is about 3.0 g / cm3, which is twice that of ordinary epoxy antirust primer, which does not meet the concept of weight reduction and consumption reduction of new marine coatings
[0004] 3. Although water-based inorganic zinc-rich products are environmentally friendly and have good anti-corrosion effects, they are highly brittle, consume a lot of resources, the construction conditions are relatively harsh, and the bonding strength is not high, so they are only suitable for the surface of metal materials
[0005] 4. Although the traditional epoxy zinc-rich primer has good anti-corrosion effect, it contains a large amount of organic solvents, which is not environmentally friendly
At the same time, there are many disadvantages brought about by the high zinc content.
[0006] 5. At present, the Chinese patent No. CN 103897556 A discloses a zinc olefin heavy-duty anti-corrosion coating and its preparation method. The coating belongs to a solvent-based heavy-duty anti-corrosion coating. Volatile solvent, not conducive to environmental protection

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] Dispersion type waterborne zinc epoxy (three-component) anti-rust heavy-duty anti-corrosion primer with rust:

[0056] Component A: water-based epoxy dispersion STW-703A: 60 parts (dispersion VOC is 0, solid content is 50%); water-dispersed graphene P-ML20: 0.5 parts; graphene special dispersant (Mechelin New material MQ-512): 0.5 parts; zinc oxide (national standard): 10 parts; water-based dispersant W-18 (Deqian): 0.3 parts; water-based W-074 (Deqian): 0.3 parts; water-based rheological additives 201T (Deqian): 0.9 parts; anti-flash rust additive (340A Longhai Chemical): 0.5 parts; rust-reducing agent (2611): 7 parts; tap water: 20 parts

[0057] Preparation Process:

[0058] First mix water, W-18, part (half) of W-074 (mixer speed 500 rpm) (temperature not exceeding 45°C) evenly, then add STW-703A and stir at low speed until uniform, then add part (half) Water-based rheological additives and zinc oxide are mixed and stirred evenly, and then ground to a fineness of ...

Embodiment 2

[0064] Dispersion type waterborne zinc epoxy (three-component) anti-rust heavy-duty anti-corrosion primer with rust:

[0065] Component A: water-based epoxy dispersion STW-703A: 65 parts (dispersion VOC is 0, solid content is 50%); water-dispersed graphene P-ML20: 3 parts; graphene-specific dispersant (Machelin New material MQ-512): 0.5 parts; zinc oxide (national standard): 5 parts; water-based dispersant W-18 (Deqian): 0.3 parts; water-based W-074 (Deqian): 0.3 parts; water-based rheological additives 201T (Deqian): 0.9 parts; anti-flash rust additive (340A Longhai Chemical): 0.5 parts; rust-reducing agent (2611): 7 parts; tap water: 17.5 parts

[0066] Preparation method is the same as embodiment 1

[0067] B component: Zinc powder

[0068] Component C: water-based epoxy curing agent 703B (80% solid content): 50 parts; water: 50 parts.

Embodiment 3

[0070] Dispersion type waterborne zinc epoxy (three-component) anti-rust heavy-duty anti-corrosion primer with rust:

[0071] Component A: water-based epoxy dispersion STW-703A: 45 parts (dispersion VOC is 0, solid content is 50%); water-dispersed graphene P-ML20: 5 parts; graphene-specific dispersant (Machelin New material MQ-512): 0.5 parts; zinc oxide (national standard): 10 parts; water-based dispersant W-18 (Deqian): 0.3 parts; water-based W-074 (Deqian): 0.3 parts; water-based rheological additives 201T (Deqian): 0.9 parts; anti-flash rust additive (340A Longhai Chemical): 0.5 parts; rust-reducing agent (2611): 7 parts; tap water: 30.5 parts

[0072] Preparation method is the same as embodiment 1

[0073] B component: Zinc powder

[0074] Component C: water-based epoxy curing agent 703B (80% solid content): 50 parts; water: 50 parts.

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Abstract

The invention discloses a dispersion type waterborne epoxy zinc-alkene rusty, anti-rust and heavy anti-corrosion primer. The dispersion type waterborne epoxy zinc-alkene rusty, anti-rust and heavy anti-corrosion primer is a waterborne heavy anti-corrosion primer composed of three components, wherein a component A is composed of waterborne epoxy dispersion, dispersant, defoamer, zinc oxide, rust converter, water dispersible graphene, graphene-specialized dispersant, flash rust inhibiting auxiliaries, waterborne rheological auxiliaries and water; a component B is zinc powder; a component C is composed of waterborne epoxy curing agent and water. The dispersion type waterborne epoxy zinc-alkene rusty, anti-rust and heavy anti-corrosion primer has no volatilization of organic solvent, and by taking water as dispersion medium, can convert rust on steel into stable substance, give play to anti-corrosion capability of the graphene, the zinc oxide and epoxy resin and provide continuous negativeelectrode protecting ability for the surface of base materials.

Description

technical field [0001] The invention relates to the field of water-based epoxy anti-corrosion coatings, in particular to a dispersion-type water-based epoxy zincene (three-component) anti-rust anti-rust heavy-duty anti-corrosion primer and its preparation method and application. Background technique [0002] 1. Before the traditional anti-corrosion coating is applied again, it is necessary to use sandblasting, manual or electric tools and other derusting methods to treat the surface of the steel surface. However, some large-scale steel equipment is difficult to derust completely or even cannot derust, which affects the protection of the paint film. Features. [0003] 2. Zinc-rich heavy-duty anti-corrosion primer is one of the most important and widely used heavy-duty anti-corrosion coatings for ships, marine facilities, bridges, large-scale equipment and various large-scale building steel structures. Its anti-corrosion mechanism is based on metal zinc powder For the cathodi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D7/61C09D5/10
CPCC08K3/042C08K2003/0893C08K2003/2296C09D5/106C09D7/61C09D163/00
Inventor 施铭德许盛景刘思平周春爱
Owner 湖北铁神新材料有限公司
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