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Compound fire extinction material used for coal mine, and preparation method thereof

A technology for fire extinguishing materials and coal mines, which is applied in fire protection equipment, mining equipment, earth-moving drilling, etc. It can solve the problems of small combustion and cooling effect, uneconomical, and high price of fire extinguishing agents, and achieves the goal of accelerating the consolidation speed and increasing the bonding effect. Effect

Active Publication Date: 2018-09-07
CHINA COAL TECH & ENG GRP CHONGQING RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Gas fire extinguishing agents such as haloalkane, carbon dioxide, and inert gas are expensive, and it is difficult to exert their fire extinguishing efficiency in open spaces; dry powder fire extinguishing agents have high fire extinguishing efficiency and fast fire extinguishing speed. However, dry powder fire extinguishing has little cooling effect on combustion. It has the function of covering and preventing combustion and evaporation. The surface of the coal pile is easy to cause re-ignition, and the interior of the coal pile basically does not play a role. The foam fire extinguishing agent has high fire extinguishing efficiency and fast fire extinguishing speed when applied to combustible liquid fires. However, it is low in efficiency when used to extinguish coal spontaneous combustion fires , large amount, uneconomical

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The composite fire extinguishing material for coal mine provided in this embodiment, the fire extinguishing material comprises the following components by weight percentage: 12% of sandy soil, 7% of vermiculite, 3.2% of pyrophyllite, 3.5% of bentonite, 1.7% of nano silicon dioxide, carboxymethyl Cellulose sodium 1.5%, hydroxyethyl cellulose 0.5%, silicate mixture 1.3%, melamine cyanurate 0.6%, phosphoric acid 0.6%, sodium alginate 0.1%, Tween-80 0.3%, polyvinyl alcohol Butyraldehyde 0.1%, chitosan 0.2% and water 67.4%;

[0022] in:

[0023] The silicate mixture is composed of sodium silicate and lithium silicate in a mass ratio of 0.6:2.0;

[0024] The particle diameters of the sand, vermiculite, pyrophyllite and bentonite are all less than 120 μm.

[0025] In this embodiment, the method for preparing a composite fire extinguishing material for coal mines includes the following steps: first, sodium carboxymethyl cellulose, hydroxyethyl cellulose, silicate mixture, mel...

Embodiment 2

[0029] The composite fire extinguishing material for coal mines provided in this embodiment includes the following components by weight percentage: 15% sand, 7% vermiculite, 3.5% pyrophyllite, 3.5% bentonite, 2.0% nano-silica, carboxymethyl Cellulose sodium 1.5%, hydroxyethyl cellulose 0.6%, silicate mixture 1.3%, melamine cyanurate 0.7%, phosphoric acid 0.6%, sodium alginate 0.3%, Tween-80 0.3%, polyvinyl alcohol condensation Butyraldehyde 0.3%, chitosan 0.2% and water 63.2%;

[0030] in:

[0031] The silicate mixture is composed of sodium silicate and lithium silicate in a mass ratio of 0.6:2.0;

[0032] The particle sizes of the sand, vermiculite, pyrophyllite and bentonite are all less than 120 μm.

[0033] In this embodiment, the method for preparing a composite fire extinguishing material for coal mines includes the following steps: Butyral, chitosan and 3 / 4 volume of water were stirred and mixed for 15 minutes, then sand, vermiculite, pyrophyllite and bentonite were ...

Embodiment 3

[0037] The composite fire extinguishing material for coal mines provided in this embodiment includes the following components by weight percentage: 13% sand, 6% vermiculite, 3.3% pyrophyllite, 3.2% bentonite, 1.8% nano-silica, carboxymethyl Cellulose sodium 1.3%, hydroxyethyl cellulose 0.5%, silicate mixture 1.2%, melamine cyanurate 0.6%, phosphoric acid 0.4%, sodium alginate 0.2%, Tween-80 0.2%, polyvinyl alcohol condensation Butyraldehyde 0.2%, chitosan 0.1% and water 68.0%.

[0038] in:

[0039] The silicate mixture is composed of sodium silicate and lithium silicate in a mass ratio of 0.5:2.0;

[0040] The particle sizes of the sand, vermiculite, pyrophyllite and bentonite are all less than 120 μm.

[0041] In this embodiment, the method for preparing a composite fire extinguishing material for coal mines includes the following steps: Butyral, chitosan and 3 / 4 volume of water were stirred and mixed for 12min, then sand, vermiculite, pyrophyllite and bentonite were added...

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Abstract

The invention provides a compound fire extinction material used for a coal mine. The fire extinction material is prepared from the following ingredients in parts by weight: 12-15% of sandy soil, 5-7%of vermiculite, 3.2-3.5% of pyrophyllite, 2.7-3.5% of bentonite, 1.7-2.0% of nano-silica, 1.2-1.5% of sodium carboxymethylcellulose, 0.5-0.6% of hydroxyethyl cellulose, 1.1-1.3% of silicate mixture, 0.6-0.7% of melamine cyanurate, 0.3-0.6% of phosphoric acid, 0.1-0.3% of sodium alginate, 0.1-0.3% of Tween-80, 0.1-0.3% of polyvinyl butyral, 0.1-0.2% of chitosan and the balance of water, wherein thetotal amount of above raw materials is 100%. According to the compound fire extinction material prepared with the preparation method, a multilayer structure can be formed on the surface of coal, in addition, the coal can be cooled in a targeted way so as to perform the efficacies on thermal insulation, oxygen insulation, smoke inhibition and the like, effects on efficiently resisting flame and quickly carrying out fire extinction are achieved, and the flame resistance of the material is greatly improved.

Description

technical field [0001] The invention relates to the technical field of fire extinguishing materials, in particular to a composite fire extinguishing material for coal mines and a preparation method thereof. Background technique [0002] Coal mines mined underground are generally subject to mining technology limitations, and there will be a lot of coal left in the goaf. Under the condition of suitable oxygen supply and heat storage environment, coal spontaneous combustion will occur after a period of time. Spontaneous combustion of coal underground in coal mines is one of the five major disasters in coal mines. my country is a large coal-producing country. At present, 50% of the coal mines are threatened by coal spontaneous combustion, and with the development of new lignite coal fields in the central and western regions of my country and the deep mining of old mines, the threat of coal spontaneous combustion becomes more serious. The basic principle of coal spontaneous comb...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A62D1/00E21F11/00
CPCA62D1/00E21F11/00
Inventor 徐俊郝建国陈明河李尚国叶正亮王正辉刘国忠郝宇杜云峰闫凯刘华锋陈辉
Owner CHINA COAL TECH & ENG GRP CHONGQING RES INST CO LTD
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