A high-voltage positive electrode sheet and its preparation method

A high-voltage, positive electrode technology, applied in the direction of electrode manufacturing, battery electrodes, electrode collector coating, etc., can solve the problems of ignoring the design of positive electrodes, achieve high-current charging and discharging, high conductivity efficiency, and improve charging and discharging efficiency effect

Active Publication Date: 2020-07-24
广东永邦新能源股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The key to improving the high specific energy index of lithium-ion batteries lies in the development of high specific energy positive electrode activity and the design of positive electrodes, and most researchers have devoted their main energy to the development of high specific energy positive electrode active materials, while ignoring the positive electrode. Design, especially the design of conductive agents

Method used

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  • A high-voltage positive electrode sheet and its preparation method
  • A high-voltage positive electrode sheet and its preparation method
  • A high-voltage positive electrode sheet and its preparation method

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Effect test

Embodiment 1

[0029] A high-voltage positive electrode sheet, comprising a positive electrode current collector and a positive electrode slurry layer coated on the surface of the positive electrode current collector, the positive electrode slurry layer is composed of 92.5wt% positive active material, 5.5wt% composite conductive agent and 2wt% The binder is prepared by carbonization treatment, and the composite conductive agent is composed of 68wt% cellulose, 30wt% graphene and 2wt% aluminum powder.

[0030] Wherein, the length of the cellulose is 30 μm, the diameter is 200 nm, the average particle size of the graphene is 55 nm, the BET surface area is 600 m2 / g, and the particle size of the aluminum powder is 40 nm.

[0031] Wherein, the binder is polyvinylidene fluoride.

[0032] Wherein, the positive electrode active material is LiNi x co y mn z o 2 , where x=0.3, y=0.5, z=0.2.

[0033] Wherein, the particle size distribution D50 of the positive electrode active material is 13 μm.

...

Embodiment 2

[0045] A high-voltage positive electrode sheet, comprising a positive electrode current collector and a positive electrode slurry layer coated on the surface of the positive electrode current collector, the positive electrode slurry layer is composed of 87wt% positive active material, 10wt% composite conductive agent and 3wt% viscose The composite conductive agent is prepared by carbonizing the binder, and the composite conductive agent is composed of 57wt% cellulose, 40wt% graphene and 3wt% aluminum powder.

[0046] Wherein, the length of the cellulose is 10 μm, the diameter is 100 nm, the average particle size of the graphene is 10 nm, the BET surface area is 800 m2 / g, and the particle size of the aluminum powder is 30 nm.

[0047] Wherein, the binder is polyvinylidene fluoride.

[0048] Wherein, the positive electrode active material is LiNi x co y mn z o 2 , where x=0.26, y=0.44, z=0.3.

[0049] Wherein, the particle size distribution D50 of the positive electrode act...

Embodiment 3

[0062] A high-voltage positive electrode sheet, including a positive electrode current collector and a positive electrode slurry layer coated on the surface of the positive electrode current collector, the positive electrode slurry layer is composed of 98wt% positive electrode active material, 1wt% composite conductive agent and 1wt% viscose The composite conductive agent is prepared by carbonizing the binder, and the composite conductive agent is composed of 79wt% cellulose, 20wt% graphene and 1wt% aluminum powder.

[0063] Wherein, the length of the cellulose is 50 μm, the diameter is 300 nm, the average particle size of the graphene is 100 nm, the BET surface area is 400 m2 / g, and the particle size of the aluminum powder is 49 nm.

[0064] Wherein, the binder is polyvinylidene fluoride.

[0065] Wherein, the positive electrode active material is LiNi x co y mn z o 2 , where x=0.33, y=0.61, z=0.6.

[0066] Wherein, the particle size distribution D50 of the positive elec...

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Abstract

The invention relates to the technical field of lithium batteries, in particular to a high-voltage positive plate and a preparation method thereof. The high-voltage positive plate comprises a positivecurrent collector and a positive pulp layer coated on the surface of the positive current collector, the positive pulp layer is obtained by carbonating a positive active material, a composite conductive agent and binder, and the composite conductive agent is composed of 57-79wt% of cellulose, 20-40wt% of graphene and 1-3wt% of aluminite powder. The high-voltage positive plate and the preparationmethod thereof have the advantages that the cellulose is added into the composite conductive agent, the high-voltage positive plate has a better network structure after the cellulose is carbonized, the migration rate of lithium ions in an electrode material can be effectively improved, the charging and discharging efficiency is improved, the use amount of the graphene is reduced, and the cost is reduced; a small amount of aluminum powder is added into the conductive agent, the practice shows that the electrical conductivity of the positive pulp layer can be effectively improved, and the effectof improving the charging and discharging of large current is achieved.

Description

technical field [0001] The invention relates to the technical field of lithium batteries, in particular to a high-voltage positive electrode sheet and a preparation method thereof. Background technique [0002] With the rapid development of electronic equipment and the increasingly prominent energy and environmental issues, people have put forward higher requirements for chemical power sources. Lithium-ion batteries have rapidly emerged in the market due to their high voltage, large specific energy, long cycle life, and no pollution, and have become a new type of clean, high-energy energy. Especially in the 21st century, with the rapid development and wide application of various portable electronic devices, wireless mobile communication devices, and electric vehicles, the demand for lithium-ion batteries with higher specific capacity, long cycle life, and low cost appears to be even greater. urgent. [0003] The key to improving the high specific energy index of lithium-io...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/131H01M4/62H01M4/1391H01M4/04
CPCH01M4/0404H01M4/131H01M4/1391H01M4/625H01M4/626Y02E60/10
Inventor 姚学永易辉华
Owner 广东永邦新能源股份有限公司
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