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Photosensitive ink material and preparation method thereof

A technology of ink and photosensitive resin, applied in the field of ink materials, can solve problems such as lack of mature technology

Active Publication Date: 2018-08-24
SHENZHEN GLITER PRINTING MATERIALS & EQUIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] So far, there is no mature technology independently developed in this field in China.

Method used

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  • Photosensitive ink material and preparation method thereof
  • Photosensitive ink material and preparation method thereof
  • Photosensitive ink material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0086] The preparation method of basic embodiment 1 hyperbranched photosensitive resin

[0087] The hyperbranched photosensitive resin is a photosensitive resin obtained through an esterification reaction between a hyperbranched matrix containing a terminal hydroxyl group and a monomer containing a carboxyl group, and the specific reaction equation is (B);

[0088]

[0089] In the above-mentioned reaction equation, HBP is the abbreviation form of hyperbranched resin, and concrete molecular formula is following formula (I);

[0090] HBP:

[0091]

Embodiment 2

[0092] The preparation method of the acetoacetate compound of basic embodiment 2β-dicarboxyl structure

[0093] The self-crosslinking curable photosensitive resin is an acetoacetate compound based on a β-dicarboxyl structure;

[0094] The polyhydroxy macromolecular compound is mixed with a monoacetoacetate compound or a diacetoacetate compound, and then a catalyst is added as a reaction material, which is synthesized by microwave irradiation; the monoacetoacetate compound is The compound containing the basic structure of formula (II), the described diacetoacetate compound is a compound containing the basic structure of formula (III),

[0095]

[0096] Wherein, R1 is a tertiary alcohol or pinacol.

[0097] The polyhydroxy macromolecular compound can be selected from chitosan, dextran or hyaluronic acid.

Embodiment 3

[0098] The preparation method of the polymer microsphere of basic embodiment 3 cutting stabilizer

[0099] The preparation process of the polymer microspheres of the excised stabilizer is as follows:

[0100] Using Z-type macromolecular RAFT reagent as a stable dispersant, ethanol / water mixture as a dispersion medium, and 10% of 4-acryloylmorpholine (ACMO), 6% of methacrylic acid (MAA) and 6% of A mixture of glycidyl methacrylate (GMA) and 6% methacrylic acid (MAA) is used as a monomer for light dispersion polymerization to synthesize a stable white milky dispersion; then dilute with water and add excess thermal initiator diisopropyl Benzene peroxide is heated in a nitrogen oil bath for 20-28h, and the clean polymer functional microspheres whose surface does not contain a stable dispersant are obtained after removing the dispersion medium; the structural formula (II') of the Z-type macromolecule RAFT reagent is as follows:

[0101]

[0102] The preparation method of basic ...

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Abstract

The invention discloses a photosensitive ink material and a technological process for applying the prepared photosensitive ink material to printing. The photosensitive ink material is prepared from components in percentage by weight as follows: 30%-60% of photosensitive resin, 30%-50% of pigments, 4%-8% of a photoinitiator, 5%-10% of a diluent and 1%-5% of an aid. The photosensitive ink material is applicable to color spraying or inkjet systems of 3D curved glass frames, and on the basis of no increase of construction difficulty, the negative effect of a curved surface on the exposure imagingeffect is reduced as far as possible. On the basis of the special requirements of photosensitive ink for printing of 3D curved glass cover plates, various key raw materials are designed and synthesized and are used for a formula of the photosensitive ink, on one hand, the key raw materials are used for matching a production process, on the other hand, the key raw materials are used for matching acuring process, and more importantly, the ink pattern effect, the environmental tolerance of cured patterns and other properties are improved.

Description

technical field [0001] The invention relates to an ink material, in particular to an ink material used for pattern printing on curved glass. Background technique [0002] The difficulty of graphic printing on 3D curved cover glass lies in changing from flat printing to curved surface printing. The higher the radius of curvature of the glass, the more challenging the pattern printing will be. At present, the graphics and text printing process similar to the front 3D curved cover glass of Samsung edge series mobile phones in South Korea inherits the thermal transfer technology that Samsung mobile phones have always liked to use on high-end models. The graphics and text printing process with the most rate loss has increased the difficulty of processing. At the same time, many of the core process parameters are jointly developed by Samsung and its suppliers, which are unique to Samsung and difficult to replicate in the industry. [0003] Recently, Corning Corporation of the Un...

Claims

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Application Information

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IPC IPC(8): C09D11/30G03F7/004
CPCC09D11/30G03F7/004
Inventor 邢槐泽邢孔球邢孔繁张国慧
Owner SHENZHEN GLITER PRINTING MATERIALS & EQUIP
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