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Low-dielectric-constant halogen-free resin composition and low-flowability prepreg with same

A resin composition and low-dielectric technology, applied in the field of halogen-free low-dielectric resin composition and low-flow prepreg, can solve the problems of increased overall viscosity of resin glue, poor wettability of reinforcing materials, etc. The effect of good bonding, excellent flame retardant performance and good processability

Active Publication Date: 2018-08-17
ZHEJIANG WAZAM NEW MATERIAL CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the use of a large amount of bisphenol A phenolic resin increases the overall viscosity of the resin glue, resulting in poor wettability of the resin composition to the reinforcing material.

Method used

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  • Low-dielectric-constant halogen-free resin composition and low-flowability prepreg with same
  • Low-dielectric-constant halogen-free resin composition and low-flowability prepreg with same
  • Low-dielectric-constant halogen-free resin composition and low-flowability prepreg with same

Examples

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Embodiment Construction

[0028] The following specific examples are further descriptions of the methods and technical solutions provided by the present invention, but should not be construed as limiting the present invention. The instruments, equipment and methods used in the present invention are commonly used instruments, equipment and methods in the art unless otherwise specified.

[0029] The types and sources of the raw materials used to prepare the halogen-free low-dielectric resin composition in the examples of the present invention are as follows:

[0030] Bisphenol A epoxy resin, manufacturer: Nanya Epoxy, NPEL-128

[0031] Phosphorus-containing phenolic resin, manufacturer: Dow, XZ92741

[0032] DCPD epoxy, manufacturer: Changchun, Taiwan, DNE260

[0033] Biphenyl type epoxy, manufacturer: SHIN-A, SE-70H

[0034] Curing agent EF-30, manufacturer: Cray Valley, styrene-maleic anhydride copolymer (St:MA=3:1)

[0035] Curing agent EF-40, manufacturer: Cray Valley, styrene-maleic anhydride co...

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PUM

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Abstract

The invention discloses a low-dielectric-constant halogen-free resin composition and a low-flowability prepreg with the same. The low-dielectric-constant halogen-free resin composition comprises, by weight, 10-80 parts of epoxy resin, 5-30 parts of phenoxy resin, 10-50 parts of flame retardants, 5-50 parts of curing agents, 0-5 parts of curing accelerators, 10-80 parts of fillers, 5-30 parts of toughening agents and 0-80 parts of additives. The low-dielectric-constant halogen-free resin composition and the low-flowability prepreg have the advantages that the low-dielectric-constant halogen-free resin composition is good in wettability and sufficiently low in dielectric constant and dielectric loss tangent, and the low-flowability prepreg prepared from the low-dielectric-constant halogen-free resin composition is good in heat resistance after being cured, is low in dielectric constant and dielectric loss factor, excellent in flame retardance and good in water resistance, water absorption and cohesiveness.

Description

technical field [0001] The invention belongs to the field of resin materials for printed circuit boards, in particular to a halogen-free low-dielectric resin composition and a low-flow prepreg prepared by using the resin composition. Background technique [0002] In recent years, the rapid development of flexible copper clad laminates has promoted the development of electronic products in the direction of "light, thin, short, and small". In the past, the pure film used in rigid-flex boards was difficult to meet the high heat resistance requirements of rigid-flex boards due to the poor dimensional stability of the material itself and the heat resistance. Therefore, PCB manufacturers are looking for other alternative materials for the connection between rigid boards and flexible boards. Currently, the better alternative material is No-Flow prepreg. [0003] The current existing non-flow glue semi-cured products mostly adopt the resin system with rubber-modified epoxy resin as...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08L61/06C08K3/36C08K5/54B32B17/04B32B17/06B32B27/04B32B27/38B32B15/20B32B15/04
CPCB32B5/02B32B5/26B32B15/14B32B15/20B32B2260/021B32B2260/046B32B2262/101B32B2307/3065B32B2307/726B32B2457/08C08L63/00C08L2201/02C08L2201/08C08L2203/20C08L2205/025C08L2205/03C08L2205/035C08L61/06C08K3/36C08K5/54
Inventor 竺孟晓潘锦平彭康陈忠红梁希亭盛佳炯
Owner ZHEJIANG WAZAM NEW MATERIAL CO LTD
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