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Ionic liquid catalyst treating system

A technology of ionic liquid and treatment process, which is applied in the field of ionic liquid catalyst treatment system, and can solve the problems of high level of ionic liquid and toxic microorganisms

Pending Publication Date: 2018-08-03
UOP LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0013] However, it has been found that in some embodiments these ionic liquid levels are still too high
For example, it has been found that ionic liquid levels of 10 to 40 ppm may still be toxic to microorganisms in wastewater treatment facilities

Method used

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  • Ionic liquid catalyst treating system

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Effect test

Embodiment 1

[0038] Add 10.1 g of 1-butyl-3-methylimidazole hexafluorophosphate to 720 g of deionized (DI) water Ionic liquid (BMIM), a pH of 3 was obtained. The solution was then neutralized with 4.9 g of NaOH, forming a solid precipitate of mainly aluminum hydroxide and bringing the pH of the solution to 6. After removing the precipitate by filtration, the solution (containing 0.014 mg ionic liquid / mg solution) was tested for toxicity. The solution's half-maximal effect concentration (EC-50) was then determined for luminescence of Aliivibrio fischeribacteria to assess the toxicity of the solution. The assay EC-50 was achieved at a dilution of 5.7 mg solution / liter water. Therefore, the EC-50 of this ionic liquid is 80 ppB, which is much lower than the level achievable only by combining gravity settling with a coalescer.

Embodiment 2

[0040] To 770 g of deionized (DI) water was added 10.1 g of tributylpentyl Ionic liquid (TBPP) to obtain a pH value of 3. The solution was then neutralized with 4.3 g of NaOH, forming a solid precipitate of mainly aluminum hydroxide and bringing the pH of the solution to 6. After removing the precipitate by filtration, the toxicity of the solution (containing 0.013 mg ionic liquid / mg solution) was determined. The EC-50 of this solution was then determined for the luminescence of Vibrio fischeri bacteria to assess the toxicity of the solution. The assay EC-50 is achieved at a dilution of 1.2 mg solution / liter water. Therefore, the EC-50 of this ionic liquid is 16 ppB, which is much lower than the level achievable only by combining gravity settling with a coalescer.

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Abstract

A process removing ionic liquid from a process stream is described. The process stream is introduced into a coalescer to form an ionic liquid stream and a first treated process stream which has less ionic liquid than the process stream. The first treated process stream is introduced into a separator to form a second treated process stream. The second treated process stream has less ionic liquid than the first treated process stream. The separator is selected from a filtration zone comprising sand or carbon, an adsorption zone, a scrubbing zone, an electrostatic separation zone, or combinationsthereof.

Description

[0001] priority statement [0002] This application claims priority to US Application No. 62 / 268,865, filed December 17, 2015, the contents of which are incorporated herein by reference in their entirety. Background technique [0003] Various hydrocarbon conversion processes can use ionic liquid catalysts. Alkylation is commonly used to combine light olefins (such as mixtures of olefins such as propylene and butenes) with isobutane to produce relatively high-octane branched-chain paraffinic fuels, including isoheptane and isooctane. Similarly, alkylation reactions can be carried out using aromatic compounds such as benzene instead of isobutane. When benzene is used, the product obtained from the alkylation reaction is an alkylbenzene (eg, ethylbenzene, cumene, dodecylbenzene, etc.). [0004] Used in the oligomerization of light olefins (such as ethylene, propylene and butene) to produce higher carbon number olefin products (such as C 6+ alkenes) are well known. Oligomeriza...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C7/10C07C7/12B01J31/40B01J31/22B01D15/00B01D15/04B01D17/025B01D17/032B01D17/06B01D24/02
CPCB01D15/00B01D15/361B01D17/06C07C7/10C07C7/12B01J31/0284B01J31/40B01J31/0298C10G25/02C10G25/05C10G31/00C10G53/08C10G2300/4081C10G2300/706C10G57/005C10G57/02C10G67/14C10G53/02B01D11/04B01D24/02B01J31/22B01D17/0202B01D17/0208B01D17/045B01J31/0282B01J31/0288B01J38/64C07C7/005C07C7/13
Inventor M·利普曼D·S·拉弗亚迪斯D·A·纳菲斯K·德特里克
Owner UOP LLC
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