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Hydration heat regulation composition, as well as preparation method and application thereof

A composition and heat of hydration technology, applied in the field of concrete admixtures, can solve the problems of reduced concrete strength, reduced concrete durability, poor effect, etc., and achieve the effects of reducing corrosion, reducing heating and cooling rates, and improving safety

Active Publication Date: 2018-07-31
GUANGDONG NO 2 HYDROPOWER ENGINEERING COMPANY LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, the reduction of the central temperature of concrete with heat of hydration inhibitors is proportional to the reduction of strength. Although the current heat of hydration inhibitors play a role in cooling, they also reduce the strength of concrete.
Moreover, most of the hydration heat control materials are made of starch or dextrin materials through hydrolysis or high-temperature gelatinization modification, and their hydration temperature rise control performance in actual concrete structures can only control the induction period of hydration heat release. It has poor effect on the late hydration exothermic reaction period, which greatly reduces the durability of concrete

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Embodiment 1, the preparation of cationic acrylic resin

[0042] A mix 9 parts of methyl methacrylate, 7 parts of hydroxyethyl acrylate, 7 parts of isooctyl acrylate and 2 parts of butyl acetate hair agent to obtain a mixture;

[0043] B Add 1 / 2 of the mixture obtained in step A into 11 parts of n-butanol and stir until dissolved, then raise the temperature to 118°C, after heating for 22 minutes, add the remaining mixture obtained in step A dropwise at a rate of 0.4g / min, drop After the addition, the temperature was raised to 120°C for 2 hours of heat preservation reaction to obtain a polymer, and n-butanol was recovered under reduced pressure;

[0044] C Add 26 parts of diisocyanate to the polymer obtained in step B, raise the temperature to 75°C, keep the temperature for 2 hours, then cool down to 48°C, add 26 parts of pentaerythritol, then add 0.03 parts of stannous octoate, heat up to 80°C, and keep the temperature for reaction 2h, the extended chain prepolymer was...

Embodiment 2

[0047] Embodiment 2, the preparation of modified diatomite

[0048] a. Dry diatomaceous earth, pass through a 100-mesh sieve to obtain fine powder, then add hydrochloric acid with a volume concentration of 8%, the solid-to-liquid ratio of the fine powder to hydrochloric acid is 1g:2mL, heat to 110°C for 3h, Cool, wash with water until neutral, and dry to obtain acidic diatomite powder;

[0049] b. dissolving xylitol in water and stirring until completely dissolved, then adding the acidic diatomite powder obtained in step a and stirring, the weight ratio of xylitol and acidic diatomite powder is 6:1, forming a uniform colloid shape, dried, ground, that is.

Embodiment 3

[0050] Embodiment 3, a kind of hydration heat regulating composition

[0051] The hydration heat regulating composition consists of the following components and parts by weight thereof:

[0052] 48 parts of cationic acrylic resins, 14 parts of amino resins, 5 parts of epoxy phosphoric acid esters, 8 parts of tartaric acid and 18 parts of modified diatomaceous earths; The modified diatomite described above is the modified diatomite prepared in Example 2.

[0053] Preparation:

[0054] S1 First take cationic acrylic resin, amino resin and epoxy phosphate and stir evenly to obtain a mixture;

[0055] S2 Stir tartaric acid and modified diatomaceous earth evenly, then add to the mixture obtained in step S1, mix evenly, granulate, pass through 10-60 meshes, and obtain.

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PUM

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Abstract

The invention belongs to the technical field of concrete admixtures, and particularly relates to a hydration heat regulation composition, as well as a preparation method and application thereof. The hydration heat regulation composition provided by the invention is mainly prepared from a cationic-type acrylic resin, an amino resin, epoxy phosphate, tartaric acid and modified diatomite. According to the prepared hydration heat regulation composition, the release of hydration heat can be effectively inhibited, and hydration speeds in different stages during a cement hydration process can be regulated and controlled at different degrees, so that an effect of reducing the total heat release at an early stage is achieved; meanwhile, the production of hydration heat can be continuously reduced,the phenomenon of concrete cracking can be effectively reduced, and the durability and the safety of concrete components are improved.

Description

technical field [0001] The invention belongs to the technical field of concrete admixtures, and in particular relates to a hydration heat regulating composition and a preparation method and application thereof. Background technique [0002] Concrete, as the most widely used building material, has been widely used in industrial and civil buildings as well as in major projects. The biggest disadvantage of concrete is that it is prone to cracks, which affects its durability. Although the factors that cause concrete cracking include plastic shrinkage, dry shrinkage, temperature influence and other aspects, in recent decades, it has been found that the temperature deformation caused by the heat release of cement hydration has become the leading cause of concrete cracking. Cement hydration will release a lot of heat. When the heat released by cement hydration in concrete is too late to dissipate, the internal temperature of concrete will rise, and when the hydration stops later, ...

Claims

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Application Information

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IPC IPC(8): C04B24/28
CPCC04B40/0039C04B24/2641C04B24/282C04B24/281C04B24/06C04B14/08
Inventor 谢祥明李意余青山
Owner GUANGDONG NO 2 HYDROPOWER ENGINEERING COMPANY LTD
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