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Anti-blocking PVB (Polyvinyl Butyral) rubber sheet with long-term isolating membrane-free protection at temperature greater than 10 DEG C and preparation method thereof

An anti-blocking, non-isolation technology, applied in the direction of film/sheet adhesive, film/sheet without carrier, adhesive, etc., can solve the adverse effects of haze, light transmittance, and adhesion of laminated glass products , anti-adhesive agent can not reach the anti-adhesion effect of the isolation film, etc.

Active Publication Date: 2018-07-24
ZHANGJIAGANG ALIEN NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

People have also tried to add some anti-adhesive agents in the film formula, such as patent documents CN02825306, CN200480011069, CN200680008950, although also slightly effective, these anti-adhesive agents are all dissolved or dispersed evenly in the entire PVB film, resulting in PVB film The anti-adhesive agent on the surface layer is too small to achieve the anti-adhesive effect that can prevent it from being protected by the isolation film. However, when enough anti-adhesive agents are added to the formula, it will affect the haze, light transmittance, and Adverse effects such as adhesion

Method used

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  • Anti-blocking PVB (Polyvinyl Butyral) rubber sheet with long-term isolating membrane-free protection at temperature greater than 10 DEG C and preparation method thereof
  • Anti-blocking PVB (Polyvinyl Butyral) rubber sheet with long-term isolating membrane-free protection at temperature greater than 10 DEG C and preparation method thereof
  • Anti-blocking PVB (Polyvinyl Butyral) rubber sheet with long-term isolating membrane-free protection at temperature greater than 10 DEG C and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Add anti-blocking agent before PVB film molding, and add anti-blocking agent to the surface of PVB molten rubber to manufacture single-layer PVB film that does not need isolation film protection when the temperature is greater than 10°C. The specific process is as follows:

[0048] ⑴95 extruder and other equipment form a PVB production line;

[0049] (2) PVB resin powder is fed to 95 machines through weight loss weighing A, and its feed rate is 72 parts by weight / minute, and the feed port is the powder feed port of the extruder;

[0050] (3) the anti-blocking agent butyric acid of 0.01 weight part, the 3GO plasticizer of 26 weight parts, the 1010 antioxidant of 0.2 weight part, the 328 ultraviolet absorber of 0.2 weight part, the sodium acetate knock value regulator of 0.09 weight part , 0.5 parts by weight of water are uniformly mixed after weight loss weighing B also to this 95 machine feed, feed port is the first oil injection port of this extruder, and its feed rate...

Embodiment 2

[0058] Add anti-blocking agent before PVB film molding, and mix anti-blocking agent into a mixture of more than one raw material to manufacture anti-blocking three-layer PVB film without isolation film protection at temperatures above 10°C. The specific process is as follows:

[0059] (1) With the anti-blocking agent erucamide of 0.01 weight part, the PVB resin powder of 54 weight parts, the 3GO plasticizer of 45 weight parts, the ultraviolet absorber 328 of the antioxidant 1010 of 0.2 weight part, 0.2 weight part, 0.09 weight part The knocking value regulator potassium acetate of part and the water of 0.5 weight part, feed to a 52 type twin-screw extruder after mixing uniformly and be used for extruding the middle layer of three-layer structure PVB;

[0060] (2) the anti-blocking agent erucamide of 0.51 parts by weight, the anti-blocking agent silicon stearate of 0.5 parts by weight, the PVB resin powder of 72 parts by weight, the plasticizer 3GO of 26 parts by weight, the ant...

Embodiment 3

[0067] Add anti-blocking agent during the forming process of PVB film, spray anti-blocking agent when PVB film leaves the mold for thermal stretching and expansion, and manufacture anti-blocking single-layer PVB film that does not need isolation film protection when the temperature is greater than 10°C. The specific process is as follows:

[0068] ⑴With the anti-blocking agent oleyl palmitic acid amide of 0.01 weight part, the PVB resin powder of 72 weight parts, the 3GO plasticizer of 26 weight parts, the 1010 antioxidant of 0.2 weight part, the 328 ultraviolet absorber of 0.2 weight part, 0.09 parts by weight of potassium acetate knock value regulator and 0.5 parts by weight of water, after mixing, feed to a 95 type twin-screw extruder for producing this PVB film, and the feeding speed is 99 parts by weight / minute;

[0069] ⑵95 extruder and other equipment form a PVB production line;

[0070] (3) The temperature of the screw area of ​​the 95 extruder is set from low to high ...

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Abstract

The invention discloses an anti-blocking PVB (Polyvinyl Butyral) rubber sheet with long-term isolating membrane-free protection at an environmental temperature greater than 10 DEG C and a preparationmethod thereof. Some anti-blocking agents capable of modifying PVB hydroxyls into other groups or increasing steric hindrance among the PVB hydroxyls are screened out, and mainly distributed on the PVB surface by virtue of a novel manufacturing method before, during and after molding of the PVB rubber sheet, intermolecular hydrogen bonding on the surface of the PVB rubber sheet is weakened on a micro level, and mutual adhesion of the PVB rubber sheet is inhibited. Therefore, the anti-blocking PVB rubber sheet has anti-blocking property and can avoid isolating membrane protection at the environmental temperature greater than 10 DEG C. The PVB rubber sheet comprises the following overall components in parts by weight: 0.0001-10 parts of an anti-blocking agent, 0.0001-10 parts of other typesof assistants, 0.0001-2 parts of water, 3-50 parts of a plasticizer and 28-96.9997 parts of resin powder.

Description

technical field [0001] The invention relates to an anti-adhesion PVB film without isolation film protection for a long time when the temperature is higher than 10°C and a preparation method thereof, which belongs to the field of polymer materials. Background technique [0002] PVB is the abbreviation of polyvinyl butyral, which is a polymer resin material, and its Chinese name is polyvinyl butyral. [0003] PVB film is usually made of PVB resin powder and plasticizer as the main raw materials, and is thermoplastically extruded by an extruder. [0004] PVB film is a solid adhesive film widely used in automotive laminated glass, architectural laminated glass, photovoltaic double-glass laminated components and other fields. PVB films currently on the market are divided into single-layer PVB films, three-layer PVB films, multi-layer PVB films, PET film composite PVB films, PU film composite PVB films, etc. according to their structures; Thermal PVB film, PVB film for sound ins...

Claims

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Application Information

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IPC IPC(8): C09J7/10C09J129/14C09J11/04C09J11/06C09J11/08
CPCC08K5/09C08K5/20C08K5/42C09J7/00C09J11/04C09J11/06C09J11/08C09J129/14C09J2429/00C09J2301/122C09J2301/408
Inventor 张麒
Owner ZHANGJIAGANG ALIEN NEW MATERIAL TECH CO LTD
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