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A kind of hydrogenation catalyst composition and application

A hydrogenation catalyst and catalyst technology, applied in physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, chemical/physical processes, etc. The problem of high cost of hydrogenation catalysts can achieve the effect of easy recovery, promotion of hydrocracking and quality improvement

Active Publication Date: 2021-04-06
BEIJING HUASHI UNITED ENERGY TECH & DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Therefore, the technical problem to be solved by the present invention is to overcome the defects of high cost of cracking and hydrogenation catalysts in the prior art, inability to apply to all biomass and easy coking and deactivation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] This embodiment provides a hydrogenation catalyst composition, including catalyst A, catalyst B:

[0027] Catalyst A includes a first active component and a first carrier, the first active component is one or more of iron oxides and iron hydroxides, and the first carrier is dry distillation biomass charcoal;

[0028] Catalyst B includes a second active component and a second support, and the second active component is one or more of the oxides of Mo and W in Group VIB, or among the oxides of Fe, Co and Ni in Group VIII One or more, the second carrier is dry distillation biomass charcoal; catalyst B also includes a vulcanizing agent, and the vulcanizing agent is sulfur powder.

[0029] The first carrier is sulfonated dry distillation biochar, the second carrier is acidified or alkalized dry distillation biochar, and its dry distillation biochar is made of straw, reed, bark, algae and vegetable oil, One or more of animal oil, gutter oil, and animal manure are obtained by...

Embodiment 2

[0039] This embodiment provides a hydrogenation catalyst composition, including catalyst A and catalyst B:

[0040] As an embodiment of the present invention, in this embodiment, the first active component of catalyst A is ferric hydroxide, and the first carrier is obtained by sulfonation of chlorosulfonic acid after dry distillation of bark; the second active component of catalyst B is The component is molybdenum oxide, the second carrier is obtained by dry distillation of bark and alkalized with sodium hydroxide solution, and the vulcanizing agent contained in catalyst B is sulfur powder.

[0041] The first active component accounts for 10% of the mass of the first carrier, the particle size of the first carrier is 50 μm, and the specific surface area is 50 m 2 / g, the pore diameter is 1nm, and the pore volume is 0.01cm 3 / g; the second active component accounts for 1% of the mass of the second carrier, the particle size of the second carrier is 1 μm, and the specific surfa...

Embodiment 3

[0047] This embodiment provides a hydrogenation catalyst composition, including catalyst A and catalyst B:

[0048] As an embodiment of the present invention, in this embodiment, the first active component of catalyst A is ferric hydroxide, and the first carrier is prepared by algae dry distillation and sulfonated with chlorosulfonic acid; the second active component of catalyst B is Divided into molybdenum oxide and nickel oxide, the second carrier is made by dry distillation of straw and alkalized with sodium hydroxide solution, and the vulcanizing agent contained in catalyst B is sulfur powder.

[0049] The first active component accounts for 40% of the mass of the first carrier, the particle size of the first carrier is 35 μm, and the specific surface area is 200 m 2 / g, the pore diameter is 15nm, and the pore volume is 0.07cm 3 / g; the second active component accounts for 4% of the mass of the second carrier, the particle size of the second carrier is 30 μm, and the spec...

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Abstract

The invention relates to the technical field of bioenergy, in particular to a hydrogenation catalyst composition and its application. The invention provides a catalyst for combined use, including catalyst A and catalyst B, both catalyst A and catalyst B are supported by dry distillation biomass charcoal, and catalyst B is used in conjunction with a vulcanizing agent; the active component of catalyst A is iron oxide , one or more of iron hydroxides, the active component of catalyst B is one or more of the oxides of Mo, W, Fe, Co, Ni, and the metal active component can effectively activate hydrogen and Deoxidation, inhibit coking, improve product oil quality. The combined use of the catalyst provided by the invention is applied to the hydrogenation of the biomass slurry bed / suspension bed, which expands the application field of the biomass charcoal, and the catalyst is easy to recover and can be recycled.

Description

technical field [0001] The invention relates to the technical field of bioenergy, in particular to a biomass slurry bed / suspension bed hydrogenation catalyst composition and its application. Background technique [0002] The rapid development of the world economy has benefited from the wide application of fossil energy, such as oil, natural gas, and coal. With the continuous consumption of non-renewable fossil resources, and the CO produced by their combustion 2 , SO 2 , NO x Pollutants such as pollutants have caused increasingly serious environmental pollution, and the development of renewable new energy has become a top priority. Biomass is a kind of renewable energy. It is organic matter rich in carbon, hydrogen and oxygen that is directly or indirectly transformed through photosynthesis, including plants, animals, microorganisms and their excretion and metabolites. It is renewable, low-polluting, Widely distributed, it has great potential and advantages in meeting en...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/02B01J23/28B01J23/883B01J23/30C10G1/08
CPCC10G1/06C10G1/086B01J23/28B01J23/30B01J23/883B01J27/02C10G2300/1011B01J35/19
Inventor 林科李林郭立新崔永君江莉龙
Owner BEIJING HUASHI UNITED ENERGY TECH & DEV
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