Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Modified monomer, modified polymer comprising same, and method for producing the modified monomer and the modified polymer

一种聚合物、改性的技术，应用在含羟基化合物脱水制备醚、醚制备、运输和包装等方向，能够解决效果不足等问题，达到优异加工性、容易改性、耐磨性和抗湿滑性优异的效果

Inactive Publication Date: 2018-05-11
LG CHEM LTD
View PDF6 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Therefore, studies have been conducted to introduce functional groups having affinity or reactivity with silica into the terminals of rubber molecules, but the effect is insufficient

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Modified monomer, modified polymer comprising same, and method for producing the modified monomer and the modified polymer
  • Modified monomer, modified polymer comprising same, and method for producing the modified monomer and the modified polymer
  • Modified monomer, modified polymer comprising same, and method for producing the modified monomer and the modified polymer

Examples

Experimental program
Comparison scheme
Effect test

preparation Embodiment 1

[0039] Preparation Example 1: Preparation of 1-(2-methoxyethoxy)-4-vinylbenzene

[0040] 1) Preparation of hydroxystyrene

[0041] The sodium hydroxide of 0.275 mole is put into the round bottom flask of 500ml, the dehydrated alcohol of 60ml is added wherein to dissolve sodium hydroxide, then the acetoxystyrene of 0.065 mole is added in the flask, under nitrogen atmosphere will obtain The solution was stirred at room temperature for 4 hours. Next, 50 ml of distilled water and 30 ml of ethyl acetate were sequentially added to the resulting mixture to extract an organic layer, and the extraction process of the organic layer was repeated three times. The extracted organic layer was dried over anhydrous magnesium sulfate and filtered to remove any remaining moisture. Thereafter, the solvent was removed under reduced pressure to obtain 7.54 g (yield: 96%) of hydroxystyrene as a yellow solid. Purified hydroxystyrene 1 H nuclear magnetic resonance (NMR) spectral data are as follo...

preparation Embodiment 2

[0047] Preparation Example 2: Preparation of 1-(2-(2-methoxyethoxy)ethoxy)-4-vinylbenzene

[0048] 1) Preparation of hydroxystyrene

[0049] The sodium hydroxide of 0.275 moles is put into the round bottom flask of 500ml, the dehydrated alcohol of 60ml is added wherein to dissolve sodium hydroxide, then the acetoxystyrene of 0.065 moles is added in the flask, under nitrogen atmosphere, make The solution was stirred at room temperature for 4 hours. Next, 50 ml of distilled water and 30 ml of ethyl acetate were sequentially added to the resulting mixture to extract an organic layer, and the organic layer extraction process was repeated three times. The extracted organic layer was dried using anhydrous magnesium sulfate and filtered to remove residual moisture. Thereafter, the solvent was removed under reduced pressure to obtain 7.54 g (yield: 96%) of hydroxystyrene as a yellow solid. Purified hydroxystyrene 1 H NMR spectral data are as follows:

[0050] 1 H-NMR (500MHz, CD...

Embodiment 1

[0055] Embodiment 1: the preparation of modified styrene polymer

[0056] 28.8 millimoles of styrene and 1.4 millimoles of the styrene compound prepared according to Preparation Example 2 were put into a 100 ml Schlenk flask, 30 ml of anhydrous n-hexane was added thereto, and then the temperature inside the flask was raised to 40°C. When the temperature inside the reactor reached 40° C., 0.25 ml (0.63 mmol in hexane) of a 2.5 M n-butyllithium hexane solution was added to the reactor to cause an adiabatic heating reaction. After about 20 minutes, methanol was used to terminate the polymerization reaction to complete the preparation of the modified styrene polymer.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
molecular weightaaaaaaaaaa
Login to View More

Abstract

The present invention relates to a substituted styrene compound which is effective in modifying a polymer expressed by the chemical formula 1 (see description and scope of claims), a method for producing the compound, a modified polymer comprising a functional group derived from the substituted styrene compound, a method for producing the modified polymer, a rubber composition comprising the modified polymer, and molded goods produced from the rubber composition.

Description

technical field [0001] [Cross Reference to Related Application] [0002] This application claims the priority and benefit of Korean Patent Application No. 10-2015-0181690 filed on December 18, 2015 and Korean Patent Application No. 10-2016-0143544 filed on October 31, 2016, their disclosures This specification is incorporated by reference in its entirety. [technical field] [0003] The present invention relates to a styrenic compound used for polymer modification, a preparation method of the compound, a modified polymer comprising a functional group derived from the styrenic compound, a preparation method of the modified polymer, a method comprising the A rubber composition of a modified polymer, and a molded article produced from the rubber composition. Background technique [0004] According to recent demands for fuel-efficient automobiles, polymers having low rolling resistance, high abrasion resistance, excellent tensile properties, and handling stability typified by...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08F216/14C08F212/08C08F257/02C08K3/36C08K3/04C08L15/00C08C19/26
CPCC08F212/08C08F236/10C08F236/06C07C43/215C08L9/00C08L9/06C08F2/06C08F4/48C08F212/22C08F216/14C08C19/25B60C1/00C07C41/09
Inventor 金珉秀崔源文赵大濬
Owner LG CHEM LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com