High-rigidity optical diffusion PC material, and preparation method and application thereof

A light-diffusion, high-rigidity technology, applied in the field of materials, can solve the problems of reducing fluidity and interface bonding force, affecting light-diffusion PC light transmittance, and difficult to control size and curvature, so as to improve tensile strength and bending resistance Rigidity, flexible application, short material mixing time effect

Active Publication Date: 2017-12-01
蓝小平
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] The patent (CN104725816A) proposes a preparation method of glass fiber-reinforced flame-retardant light-diffusing PC composite material, but the patent does not propose how to solve the problem of surface roughness and brittleness caused by the addition of glass fiber
And because the glass fiber is easy to cause anisotropy due to dispersion problems in the process of sending out the tube, it will cause problems such as cracking of the lamp tube under light and high temperature.
[0003] The patent (CN105542426A) proposes a low-expansion flame-retardant light-diffusing PC composite material for LED lamp tubes and its preparation method. This patent first proposes that enhanced light-diffusing PC can be used for ultra-thin lamp tubes, but there are several problems in this patent: 1 , using flat glass fibers with a width and thickness of 16 microns. This glass fiber is different from cylindrical glass fibers with an aspect ratio. Not only does it not provide reinforcement, but it is also easy to greatly reduce the The fluidity and interfacial bonding force of PC are compromised, and the bonding part with PC is easy to produce pores, which makes it easy to become brittle, rough surface, etc.; The reason of its own purity will affect the light transmittance; 3. Wollastonite is a needle-like structure, which can increase the strength, but wollastonite is a non-transparent material, which will affect the light transmittance of light-diffusing PC; Low expansion can be achieved, but there are problems such as surface problems, brittleness and light transmission
At present, the cost of ordinary PC light diffusion materials is relatively high, the linear expansion coefficient is relatively large during extrusion molding, and the cooling molding is slow when making thinner products, and the size and curvature are difficult to control. Therefore, high rigidity, low expansion, and low cost have been developed. Light-diffusing PC material is an urgently needed technology in the market

Method used

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  • High-rigidity optical diffusion PC material, and preparation method and application thereof
  • High-rigidity optical diffusion PC material, and preparation method and application thereof
  • High-rigidity optical diffusion PC material, and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] The composition of present embodiment is as follows:

[0056] PC resin Mitsubishi 7025: 100kg

[0057] Strengthening agent calcium sulfate whisker, glass microsphere 7: 3 composite: 5.3kg

[0058] Light diffusing agent: 1.5 micron, 2 micron silicone compounded at a weight ratio of 1:1, with a total weight of 1.6kg

[0059] Antioxidant: 1010: 0.2kg

[0060] Anti-UV agent: UV622: 0.5kg

[0061] Dispersant: pentaerythritol tetrastearate: 0.5kg

[0062] Dispersant: white mineral oil: 0.1kg

[0063] Flame retardant: Potassium perfluorobutane sulfonate: 0.08kg

[0064] Toner: 2,2,-(2,5-thiophene)bis[5-(1,1-dimethylethyl)]-benzotriazole: 0.05kg

[0065] The preparation process is as follows:

[0066] Dry PC resin at 120°C for 8 hours, mix with white mineral oil at low speed for 3 minutes, add toner, flame retardant, dispersant and mix for 5 minutes, add antioxidant, anti-UV agent and light diffusing agent for high-speed mixing for 10 minutes, and finally Add the reinfo...

Embodiment 2

[0068] The composition of present embodiment is as follows:

[0069] PC resin 1110R: 100kg

[0070] Reinforcing agent aluminum borate whisker and white carbon black compounded at a weight ratio of 8:2, a total of 7kg

[0071] Light diffusing agent: polysiloxane-based organic powder 1.6 microns: 0.9kg

[0072] Light diffuser: 3 micron methyl methacrylate beads: 0.8kg

[0073] Antioxidant: 300: 0.2kg

[0074] Anti-UV agent: UV5411: 0.3kg

[0075] Dispersant: stearic acid: 0.5kg

[0076] Dispersant: white mineral oil: 0.1kg

[0077] Flame retardant: Potassium perfluorobutane sulfonate: 0.08kg

[0078] Toner: 2,2,-(2,5-thiophene)bis[5-(1,1-dimethylethyl)]-benzotriazole: 0.06kg

[0079] The preparation process is as follows:

[0080] Dry PC resin at 120°C for 8 hours, mix with white mineral oil at low speed for 3 minutes, add toner, flame retardant, dispersant and mix for 5 minutes, add antioxidant, anti-UV agent and light diffusing agent for high-speed mixing for 10 minute...

Embodiment 3

[0082] The composition of present embodiment is as follows:

[0083] PC resin IR2200: 100kg

[0084] Strengthening agent: Zinc oxide and glass microspheres are mixed at a weight ratio of 5:5 to obtain a weight of 8kg

[0085] Light diffuser: 2 micron silicone 1.5kg

[0086] Antioxidant: 1010 / 168: 0.2 / 0.1kg

[0087] Anti-UV agent: UV531: 0.4kg

[0088] Dispersant: polyamide wax: 0.5kg

[0089] Dispersant: white mineral oil: 0.1kg

[0090] Flame retardant: Potassium benzenesulfonylbenzenesulfonate: 0.1kg

[0091] Toner: 2,2,-(2,5-thiophene)bis[5-(1,1-dimethylethyl)]-benzotriazole: 0.1 kg.

[0092] The production process is as follows:

[0093] Dry PC resin at 120°C for 8 hours, mix with white mineral oil at low speed for 3 minutes, add toner, flame retardant, dispersant and mix for 5 minutes, add antioxidant, anti-UV agent and light diffusing agent for high-speed mixing for 10 minutes, and finally Add the reinforcing agent and mix for 3 minutes; the screw temperature is ...

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Abstract

The invention provides a high-rigidity optical diffusion PC material, and a preparation method and an application thereof. The high-rigidity optical diffusion PC material comprises the following components in parts by weight: 75-100 parts of PC resin, 5-25 parts of enhancer, 1.5-5 parts of optical diffusant, 1-5 parts of processing aids and 0-3 parts of other aids. According to the high-rigidity optical diffusion PC material provided by the invention, rigidity is improved, so that a shrinking percentage and a linear expansion coefficient of the diffusion PC can be greatly reduced, and thickness of an optical diffusion PC illumination lamp product can be greatly reduced.

Description

technical field [0001] The invention belongs to the field of materials, and in particular relates to a high-rigidity light-diffusing PC material and a preparation method and application thereof. Background technique [0002] Patent (CN104725816A) proposes a preparation method of glass fiber reinforced flame-retardant light-diffusing PC composite material, but the patent does not propose how to solve the problem of rough surface and brittleness caused by the addition of glass fiber. And because the glass fiber is easy to cause anisotropy due to dispersion problems in the process of sending out the tube, it will cause problems such as cracking of the lamp tube under light and high temperature. [0003] The patent (CN105542426A) proposes a low-expansion flame-retardant light-diffusing PC composite material for LED lamp tubes and its preparation method. This patent first proposes that enhanced light-diffusing PC can be used for ultra-thin lamp tubes, but there are several proble...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L91/00C08L83/04C08L77/00C08K13/04C08K7/08C08K7/20C08K5/134C08K5/103C08K5/42C08K3/38C08K3/36C08K5/09C08K3/22C08K5/526C08K5/132B29B7/16B29C47/92B29C48/92
CPCC08L69/00B29B7/16B29C48/92B29C2948/92704B29C2948/9258C08K2003/387C08K2003/3045C08L2201/10C08L2203/18C08L2205/035C08L91/00C08K13/04C08K7/08C08K7/20C08K5/1345C08K5/103C08K5/42C08L83/04C08K3/38C08K3/36C08K5/09C08L77/00C08K3/22C08K5/526C08K5/132
Inventor 蓝小平黄春荣
Owner 蓝小平
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