Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Viscosity reduction type polycarboxylate concrete admixture and preparation method thereof

A viscous polycarboxylic acid, high-performance technology, applied in the field of viscosity-reducing polycarboxylic acid high-performance water reducing agent and its preparation, can solve the problem of molecular structure hydrophilicity and hydrophobicity and viscosity reduction effect. Economic problems, complex preparation methods, etc., to achieve the effects of excellent cement adaptability, significant viscosity reduction effect, and simple process

Active Publication Date: 2017-10-20
广东瑞安科技实业有限公司
View PDF8 Cites 16 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the unsaturated modified polyoxyethylene ether macromonomer used in the synthesis process of the water reducer is formed by random copolymerization of ethylene oxide and propylene oxide, and has a relatively large molecular weight, which is very important for adjusting the hydrophilicity and hydrophobicity of the molecular structure and reducing viscosity. It is difficult to make a large contribution to the effect
At the same time, the preparation method of the two-step process and compounding is relatively complicated, and the subsequent industrialization and economics are still problems.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Viscosity reduction type polycarboxylate concrete admixture and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A viscosity-reducing polycarboxylate high-performance water reducer, the synthetic raw materials are: low molecular weight block modified unsaturated polyoxyethylene ether comonomer A, unsaturated carboxylic acid comonomer B, alkylphenol polyoxyethylene Ether C, initiator, reducing agent, chain transfer agent, liquid alkali and water; the mass ratio of synthetic raw materials is, unsaturated polyoxyethylene ether comonomer A: unsaturated carboxylic acid comonomer B: alkylphenol polyoxygen Vinyl ether C: initiator: reducing agent: chain transfer agent: liquid caustic soda: water is (320~420): (24~36): (3~10): (1~5): (0.5~3): ( 0.5~4): (20~50): (400~500).

[0024] Among them, the low-molecular-weight block-modified unsaturated polyoxyethylene ether comonomer has a molecular structure composed of propylene oxide or butylene oxide segments embedded in the middle of ethylene oxide segments, and its chemical structural formula is as follows Show: CH 2 =C(CH 2 CH 3 )CH 2 ...

Embodiment 2

[0032] In a four-necked flask equipped with a stirrer and a thermometer, put 324.1 parts of low molecular weight block-modified unsaturated polyoxyethylene ether CH with a molecular weight of 500 2 =C(CH 2 CH 3 )CH 2 O-(CH 2 CH 2 O) 2 -(CH 2 CH 2 CH 2 O) 2 -(CH 2 CH 2 O) 5 OH () and 4.8 parts of nonylphenol polyoxyethylene ether NP-4, add 250.5 parts of water, start stirring and heat up to 35 ° C ~ 40 ° C, after the monomer in the flask is completely dissolved, add 1.2 parts of ammonium persulfate, and stir for 5 minutes After ~10min, add material I and material II dropwise at the same time, material I (a solution prepared by stirring 34.7 parts of acrylic acid and 40 parts of water) dropwise for 3h to 4h, material II (2.1 parts of sodium bisulfite, 1.8 parts Thioglycollic acid and 58.7 parts of water were stirred evenly to form a solution) added dropwise for 3.5h to 4.5h, and then continued to keep warm at 40°C to 45°C for 1h to 2h after the completion of the reac...

Embodiment 3

[0034] In a four-necked flask equipped with a stirrer and a thermometer, put 359.4 parts of low molecular weight block-modified unsaturated polyoxyethylene ether CH with a molecular weight of 800 2 =C(CH 2 CH 3 )CH 2 O-(CH 2 CH 2 O) 3 -(CH 2 CH 2 CH 2 CH 2 O) 4 -(CH 2 CH 2 O) 7 OH and 5.7 parts of nonylphenol polyoxyethylene ether NP-10, add 254.3 parts of water, start stirring and heat up to 35 ° C ~ 40 ° C, after the monomer in the flask is completely dissolved, add 1.9 parts of sodium persulfate, and stir for 5 min ~ 10 min Then add material I and material solution dropwise at the same time, material I (a solution prepared by stirring 25.4 parts of acrylic acid and 30 parts of water uniformly) is added dropwise for 3h to 4h, material II (made of 1.8 parts of L-ascorbic acid, 1.6 parts of mercaptoethanol and 72.4 parts of water (mixed evenly to make a solution) dropwise for 3.5h~4.5h, continue to keep warm at 40°C~50°C for 1h~2h after dropping, after the reactio...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a viscosity reduction type polycarboxylate concrete admixture and a preparation method thereof. The polycarboxylate concrete admixture contains the following synthetic raw materials: low molecular weight segmented modified unsaturated polyoxyethylene ether comonomer A, an unsaturated carboxylic acid comonomer B, alkylphenol ethoxylate C, an initiator, a reducing agent, a chain transfer agent, caustic soda liquid and water, wherein the mass ratio of the synthetic raw materials is as follows: a ratio of the low molecular weight segmented modified unsaturated polyoxyethylene ether comonomer A to the unsaturated carboxylic acid comonomer B to the alkylphenol ethoxylate C to the initiator to the reducing agent to the chain transfer agent to the caustic soda liquid to the water is (320-420):(24-36):(3-10):(1-5):(0.5-3):(0.5-4):(20-50):(400-500). The viscosity reduction type polycarboxylate concrete admixture disclosed by the invention has the characteristics of excellent dispersion property, obvious viscosity reduction effect, and excellent cement adaptability, and the product is simple in process, safe, reliable and stable in performance, does not contain any chloride ion, does not have any Corrosion damage on reinforcement and is environment-friendly.

Description

technical field [0001] The invention belongs to the technical field of concrete admixtures, in particular to a viscosity-reducing polycarboxylate high-performance water reducer and a preparation method thereof. Background technique [0002] With the rapid development of my country's construction industry, high-grade concrete is being more and more used in engineering construction due to its high overall strength and light weight. However, the application environment of high-grade concrete often has complex building structures and dense reinforcement, which puts forward higher requirements for the workability, fluidity, self-compacting and strength growth of high-grade concrete. [0003] At present, the strength of concrete is mainly improved by reducing the water-cement ratio and increasing the amount of cementitious materials, but these methods will increase the viscosity of the concrete and reduce the fluidity, thereby reducing the pumping performance of the concrete and a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C04B24/32C04B103/30
CPCC04B40/0039C04B2103/302C04B24/32C04B24/04C04B2103/0096C04B2103/0068C04B22/06C04B22/002C04B22/14C04B24/16
Inventor 仲以林陆智明黄凯波符惠玲巫晓鑫
Owner 广东瑞安科技实业有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products