A physical modification method to improve the mechanical properties of electrospun micro-nanofibrous membranes
A micro-nano fiber, physical modification technology, applied in fiber treatment, textile and papermaking, fabric surface trimming, etc. The effect of surface wettability, good integrity, and improved mechanical properties
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Embodiment 1
[0025] In the first step, the PLA micro-nano fiber membrane prepared by electrospinning technology is transferred to the anti-adhesion base material PTFE membrane, and a layer of the base material is covered on it;
[0026] In the second step, the electrospun PLA micro-nanofiber membrane held by the double-layer PTFE membrane in the first step is placed between two splints with heating and pressurization functions, wherein the glass transition temperature of PLA (T g ) is 60℃, melting temperature (T m ) is 120-170°C, set the temperature of the two splints to T g -20°C, that is, 40°C, the pressure between the two splints is adjusted to 50MPa, the PLA fiber membrane is treated in the temperature and pressure synergistic field for 1s, then cooled to room temperature, and the treated fiber membrane is taken out, thus obtaining a physical-based PLA fiber membrane material modified to improve mechanical properties. Compared with the pristine fiber membrane, the breaking strength i...
Embodiment 2
[0028] In the first step, the PLA micro-nano fiber membrane prepared by electrospinning technology is transferred to the anti-adhesion base material PTFE membrane, and a layer of the base material is covered on it;
[0029] In the second step, the electrospun PLA micro-nanofiber membrane held by the double-layer PTFE membrane in the first step is placed between two splints with heating and pressurization functions. The temperature of the two splints is set at 60°C. The pressure between them was adjusted to 2MPa, and the PLA fiber membrane was treated in the temperature and pressure synergistic field for 5min, then cooled to room temperature, and the treated fiber membrane was taken out, thereby obtaining a PLA fiber membrane with improved mechanical properties based on physical modification. Material. Compared with the pristine fiber membrane, the breaking strength is increased by about 510%, and the modulus is increased by about 900%.
Embodiment 3
[0031] In the first step, the PLA micro-nano fiber membrane prepared by electrospinning technology is transferred to the anti-adhesion base material PTFE membrane, and then covered with a layer of the base material;
[0032] In the second step, the electrospun PLA micro-nanofiber membrane held by the double-layer PTFE membrane in the first step is placed between two splints with heating and pressurization functions. The temperature of the two splints is set at 60°C. The pressure between them was adjusted to 14MPa, and the PLA fiber membrane was treated in the temperature and pressure synergistic field for 100s, then cooled to room temperature, and the treated fiber membrane was taken out, thereby obtaining a PLA fiber membrane with improved mechanical properties based on physical modification. Material. Compared with the pristine fiber membrane, the breaking strength is increased by about 648%, and the modulus is increased by about 1315%.
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