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A physical modification method to improve the mechanical properties of electrospun micro-nanofibrous membranes

A micro-nano fiber, physical modification technology, applied in fiber treatment, textile and papermaking, fabric surface trimming, etc. The effect of surface wettability, good integrity, and improved mechanical properties

Active Publication Date: 2019-11-12
上海鹏冠生物医药科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to provide a physical modification method for improving the mechanical properties of electrospun micro-nano fiber membranes, so as to solve the problems of poor mechanical properties and poor wettability of surface body fluids in the application process of electrospun micro-nano fiber membranes in the prior art , and the strong foreign body sensation in the body, and the existing physical modification methods generally have defects such as long processing time and large shrinkage rate of the fiber membrane.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] In the first step, the PLA micro-nano fiber membrane prepared by electrospinning technology is transferred to the anti-adhesion base material PTFE membrane, and a layer of the base material is covered on it;

[0026] In the second step, the electrospun PLA micro-nanofiber membrane held by the double-layer PTFE membrane in the first step is placed between two splints with heating and pressurization functions, wherein the glass transition temperature of PLA (T g ) is 60℃, melting temperature (T m ) is 120-170°C, set the temperature of the two splints to T g -20°C, that is, 40°C, the pressure between the two splints is adjusted to 50MPa, the PLA fiber membrane is treated in the temperature and pressure synergistic field for 1s, then cooled to room temperature, and the treated fiber membrane is taken out, thus obtaining a physical-based PLA fiber membrane material modified to improve mechanical properties. Compared with the pristine fiber membrane, the breaking strength i...

Embodiment 2

[0028] In the first step, the PLA micro-nano fiber membrane prepared by electrospinning technology is transferred to the anti-adhesion base material PTFE membrane, and a layer of the base material is covered on it;

[0029] In the second step, the electrospun PLA micro-nanofiber membrane held by the double-layer PTFE membrane in the first step is placed between two splints with heating and pressurization functions. The temperature of the two splints is set at 60°C. The pressure between them was adjusted to 2MPa, and the PLA fiber membrane was treated in the temperature and pressure synergistic field for 5min, then cooled to room temperature, and the treated fiber membrane was taken out, thereby obtaining a PLA fiber membrane with improved mechanical properties based on physical modification. Material. Compared with the pristine fiber membrane, the breaking strength is increased by about 510%, and the modulus is increased by about 900%.

Embodiment 3

[0031] In the first step, the PLA micro-nano fiber membrane prepared by electrospinning technology is transferred to the anti-adhesion base material PTFE membrane, and then covered with a layer of the base material;

[0032] In the second step, the electrospun PLA micro-nanofiber membrane held by the double-layer PTFE membrane in the first step is placed between two splints with heating and pressurization functions. The temperature of the two splints is set at 60°C. The pressure between them was adjusted to 14MPa, and the PLA fiber membrane was treated in the temperature and pressure synergistic field for 100s, then cooled to room temperature, and the treated fiber membrane was taken out, thereby obtaining a PLA fiber membrane with improved mechanical properties based on physical modification. Material. Compared with the pristine fiber membrane, the breaking strength is increased by about 648%, and the modulus is increased by about 1315%.

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PUM

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Abstract

The invention provides a physical modification method for promoting a mechanical property of an electrostatic spinning micro-nano fiber membrane. The method comprises the following steps: 1) transferring the electrostatic spinning micro-nano fiber membrane to an anti-adhesion substrate material and coating a layer of anti-adhesion substrate material above the electrostatic spinning micro-nano fiber membrane; and 2) placing the electrostatic spinning micro-nano fiber membrane acquired in the step 1) between two splints, wherein the temperature T of the splints is a temperature value more than or equal to a result of a glass state temperature Tg of the electrostatic spinning micro-nano fiber membrane minus 20 DEG C but less than a melting temperature Tm of the electrostatic spinning micro-nano fiber membrane, namely, T is more than or equal to Tg-20 DEG C but less than Tm, and the pressure between the two splints is arranged at 1-50MPa, and then processing for a certain period of time, thereby acquiring the physically modified electrostatic spinning micro-nano fiber membrane. According to the invention, the mechanical property of the electrostatic spinning micro-nano fiber membrane is promoted, the foreign body sensation in the fibrous membrane is reduced, the liquid wettability on the fibrous membrane surface is improved, the processing time is greatly shortened and the processing efficiency is increased.

Description

technical field [0001] The invention belongs to the field of preparation and modification of nanometer materials, and more specifically relates to a physical modification method for improving the mechanical properties of electrospun micronano fiber membranes. Background technique [0002] In recent years, electrospinning technology, as a simple and effective method for preparing fibers with diameters ranging from hundreds of nanometers to several microns, has attracted more and more attention, and has attracted extensive attention from researchers from all over the world. So far, nearly a hundred kinds of polymers have been used to prepare electrospun nanofibrous membranes by solution or melt spinning. The electrospun fiber membrane material has the characteristics of large specific surface area, high porosity, small pore size distribution, and good continuity. In addition, the fiber membrane is also easy to be functionalized and modified, which can meet various application ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06C7/00D04H1/728D01D5/00D04H1/435D04H1/4282D04H1/4309D04H1/4318D04H1/43D04H1/4334
CPCD01D5/0015D04H1/4282D04H1/43D04H1/4309D04H1/4318D04H1/4334D04H1/435D04H1/728D06C7/00
Inventor 朱宏彬洪跟东
Owner 上海鹏冠生物医药科技有限公司
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