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Preparation process of neptunium oxide target pellets

A preparation process, neptunium oxide technology, applied in the field of neptunium oxide target pellet preparation process, can solve the problems of complex process, high production cost, low loading capacity, etc., and achieve the goal of simple process flow, low cost and high neptunium utilization rate Effect

Active Publication Date: 2018-07-06
CHINA INSTITUTE OF ATOMIC ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to solve the problems of low overall neptunium loading, high production cost and complicated process in the existing neptunium oxide target preparation process, the present invention provides a neptunium oxide target pellet preparation process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) Neptunium oxide powder and magnesium oxide powder are taken as target pellet raw materials as required, wherein the quality of magnesium oxide powder accounts for 1% of the total mass of the two;

[0020] (2) In the neptunium oxide powder, take out the neptunium oxide powder equal to the mass of the magnesium oxide powder, mix the taken out neptunium oxide powder with the magnesium oxide powder in a three-dimensional motion mixer for 6 hours, and obtain the primary mixed powder ;

[0021] (3) Add the remaining neptunium oxide powder and stearic acid into the three-dimensional motion mixer, make it continue to mix with the aforementioned primary mixing powder for 3 hours, and obtain the mixed powder; wherein, the addition of stearic acid accounts for all neptunium oxide powder and oxidation 0.2% of the total mass of magnesium powder;

[0022] (4) In the glove box, a hydraulic press is used to cold-press the mixed powder with a pressure of 350 MPa, and the holding ti...

Embodiment 2

[0025] (1) Neptunium oxide powder and magnesium oxide powder are taken as target pellet raw materials as required, wherein the quality of magnesium oxide powder accounts for 5% of the total mass of the two;

[0026] (2) In the neptunium oxide powder, take out the neptunium oxide powder accounting for 0.5 times the mass of the magnesium oxide powder, mix the taken out neptunium oxide powder with the magnesium oxide powder in a three-dimensional motion mixer for 4 hours, and obtain the initial mixing powder;

[0027] (3) Add the remaining neptunium oxide powder and stearic acid into the three-dimensional motion mixer, make it continue to mix with the aforementioned primary mixing powder for 2 hours, and obtain the mixed powder; wherein, the addition of stearic acid accounts for all neptunium oxide powder and oxidation 0.4 of the total mass of magnesium powder;

[0028] (4) In the glove box, a hydraulic press is used to cold press the mixed powder with a pressure of 400 MPa, and...

Embodiment 3

[0031] (1) taking neptunium oxide powder and magnesium oxide powder as target piece raw material as required, wherein the quality of magnesium oxide powder accounts for 10% of the total mass of the two;

[0032] (2) In the neptunium oxide powder, take out the neptunium oxide powder accounting for 4 times the mass of the magnesium oxide powder, and mix the taken out neptunium oxide powder and the magnesium oxide powder in a three-dimensional motion mixer for 8 hours to obtain an initial mix powder;

[0033] (3) Add the remaining neptunium oxide powder and stearic acid into the three-dimensional motion mixer, make it continue to mix with the aforementioned primary mixing powder for 5 hours, and obtain the mixed powder; wherein, the addition of stearic acid accounts for all neptunium oxide powder and oxidation 0.6 of the total mass of magnesium powder;

[0034] (4) In the glove box, a hydraulic press is used to cold-press the mixed powder with a pressure of 600 MPa, and the hold...

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Abstract

The invention belongs to the field of nuclear material preparation and provides a preparation technology of a neptunium oxide target pellet for solving the problems that an existing preparation technology of a neptunium oxide target is relatively low in overall neptunium loading capacity, relatively high in production cost and relatively complicated in process. The technology comprises the following steps: (1) taking neptunium oxide powder and magnesium oxide powder as a target pellet material; (2) taking out part of neptunium oxide powder and mixing with the magnesium oxide powder to obtain preliminarily mixed powder; (3) adding the remaining neptunium oxide powder and further mixing with stearic acid to obtain mixed powder; (4) carrying out cold press molding to prepare a target pellet body; and (5) carrying out pressureless sintering to prepare the neptunium oxide target pellet. The preparation technology has the advantages of being simple in technological process and low in cost; the prepared neptunium oxide target pellet is high in overall neptunium loading capacity and high in neutron utilization rate, has relatively high thermal conductivity and good in-pile irradiation performance, and is convenient to chemically dissolve and extract and suitable for massive production of 238Pu fuel.

Description

technical field [0001] The invention belongs to the field of nuclear material preparation, and in particular relates to a process for preparing neptunium oxide target pellets. Background technique [0002] 238 Pu is an important nuclear material in the field of space nuclear energy, and it is an ideal fuel for radioisotope power and heat sources required for space activities. Taking the United States as an example, in the past 60 years of space exploration missions, the 42 radioisotope power systems carried on the spacecraft launched by the United States have chosen 238 Pu as fuel. [0003] Currently, 238 The production of Pu is mainly by irradiation in the reactor 237 Np way to achieve, the principle is: 237 Np undergoes (n,γ) reaction under neutron irradiation to produce 238 Np nuclides, produced 238 Np undergoes beta decay to generate 238 Pu. [0004] Based on the above principles, the Savannah River Laboratory in the United States developed NpO 2 - Al diffusion...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G21C21/02G21C3/62C04B35/51C04B35/622
CPCC04B35/51C04B35/622C04B2235/3206C04B2235/9607G21C3/623G21C21/02Y02E30/30
Inventor 尹邦跃屈哲昊郑新海
Owner CHINA INSTITUTE OF ATOMIC ENERGY
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