Improved slow-release long-acting superhydrophobic anti-pollution-flashover paint
An anti-fouling flashover coating and super-hydrophobic technology, applied in the coating and other directions, can solve the problems of low elongation, breaking strength and tear strength, easy detachment of the coating, cracking, etc., and achieve long-term hydrophobic migration , Improve hydrophobic migration, enhance the effect of hydrophobic performance
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[0048] The preparation method of the improved slow-release long-acting super-hydrophobic antifouling flashover coating of the present invention comprises the following steps:
[0049] ① Stir trifluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane and dodecamethylcyclohexasiloxane evenly, add sodium sulfate, stir evenly, heat up to 60~70°C, and then add Concentrated hydrochloric acid with a concentration of 37% is added dropwise, reacted for 1~2 hours after the dropwise addition, cooled to 20~30°C, added ammonia water, adjusted pH to 6~7, and obtained hydrogen-terminated fluorine-containing polysiloxane; The mass ratio of fluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane, dodecamethylcyclohexasiloxane, sodium sulfate and concentrated hydrochloric acid is 4~6:1:10~15:0.5~ 1: 0.2~0.5;
[0050] ② Stir the hydrogen-terminated fluorine-containing polysiloxane and methallyl alcohol obtained in step ① evenly, then add metal nickel, heat up to 80-90°C, and react for 1-2 h...
Embodiment 1
[0057] An improved slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 35kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 20kg of hydrogen-terminated polysiloxane, 55kg of 107 silicone rubber, and hydrophobic gas-phase White carbon black 20kg, nano zinc oxide 3kg, oleyl amino oleate 2kg, nano calcium carbonate 4kg, ketoxime crosslinking agent 1kg, talcum powder 5kg, silane coupling agent 1kg, decabromodiphenyl ether 1kg and organic solvent 165kg ;
[0058] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:
[0059] ①Stir 100kg of trifluoropropylmethylcyclotrisiloxane, 25kg of tetramethyldisiloxane and 250kg of dodecamethylcyclohexasiloxane evenly, add 12.5kg of sodium sulfate, stir well and heat up to 60°C , then drop 5kg of concentrated hydrochloric acid with a concentration of 37% therein, react for 1 hour after the dropwise addi...
Embodiment 2
[0064] An improved slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 45 kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 30 kg of hydrogen-terminated polysiloxane, 65 kg of 107 silicone rubber, and hydrophobic gas-phase 30kg of white carbon black, 5kg of nano-zinc oxide, 4kg of oleyl amino oleate, 6kg of nano-calcium carbonate, 3kg of ketoxime type crosslinking agent, 10kg of talcum powder, 2kg of silane coupling agent, 2kg of decabromodiphenyl ether and 175kg of organic solvent ;
[0065] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:
[0066] ①Stir 60kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 150kg of dodecamethylcyclohexasiloxane evenly, add 10kg of sodium sulfate, stir evenly and heat up to 70°C, Then, 5 kg of concentrated hydrochloric acid with a concentration of 37% was added dropwise...
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