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An improved slow-release long-lasting super-hydrophobic antifouling flashover coating

An anti-pollution flashover coating and super-hydrophobic technology, applied in the direction of the coating, can solve the problems of low elongation, breaking strength and tear strength, easy detachment of the coating, poor corrosion resistance, etc., to improve the hydrophobicity. Mobility, long-term hydrophobicity and migration, uniform and tidy surface

Active Publication Date: 2019-05-07
STATE GRID CORP OF CHINA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, although the introduction of RTV coatings has alleviated the increasingly serious pollution flashover problem in power systems, the performance of current RTV coatings is still low. First, the coatings have weak adhesion, poor wear resistance, and poor corrosion resistance. Due to poor adhesion, In the process of maintenance, the coating is easy to detach due to the action of external force; secondly, due to the problem of its own structure and composition, its own mechanical properties, such as elongation, breaking strength and tear strength are all low, and it is easy to be damaged during actual use. Peeling, cracking, and falling off occur; thirdly, the surface of the current RTV paint is easy to absorb and accumulate dust. When the loose dirt reaches a certain thickness, the inside of the dirt is easy to form water flow channels and large-area stagnation areas, and finally forms flashover channel, leading to the occurrence of pollution flashover events; in addition, because RTV coatings not only have to withstand the effects of electric field and wind force, but also bear the erosion of temperature changes, rain, snow, frost and sunlight, the performance of RTV coatings gradually decreases with time. Small, easy to age and short service life, requires regular maintenance or even re-spraying, which brings great limitations to its use

Method used

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  • An improved slow-release long-lasting super-hydrophobic antifouling flashover coating

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preparation example Construction

[0048] The preparation method of the improved slow-release long-acting super-hydrophobic antifouling flashover coating of the present invention comprises the following steps:

[0049] ① Stir trifluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane and dodecamethylcyclohexasiloxane evenly, add sodium sulfate, stir evenly, heat up to 60~70°C, and then add Concentrated hydrochloric acid with a concentration of 37% is added dropwise, reacted for 1~2 hours after the dropwise addition, cooled to 20~30°C, added ammonia water, adjusted pH to 6~7, and obtained hydrogen-terminated fluorine-containing polysiloxane; The mass ratio of fluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane, dodecamethylcyclohexasiloxane, sodium sulfate and concentrated hydrochloric acid is 4~6:1:10~15:0.5~ 1: 0.2~0.5;

[0050] ② Stir the hydrogen-terminated fluorine-containing polysiloxane and methallyl alcohol obtained in step ① evenly, then add metal nickel, heat up to 80-90°C, and react for 1-2 h...

Embodiment 1

[0057] An improved slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 35kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 20kg of hydrogen-terminated polysiloxane, 55kg of 107 silicone rubber, and hydrophobic gas-phase White carbon black 20kg, nano zinc oxide 3kg, oleyl amino oleate 2kg, nano calcium carbonate 4kg, ketoxime crosslinking agent 1kg, talcum powder 5kg, silane coupling agent 1kg, decabromodiphenyl ether 1kg and organic solvent 165kg ;

[0058] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:

[0059] ①Stir 100kg of trifluoropropylmethylcyclotrisiloxane, 25kg of tetramethyldisiloxane and 250kg of dodecamethylcyclohexasiloxane evenly, add 12.5kg of sodium sulfate, stir well and heat up to 60°C , then drop 5kg of concentrated hydrochloric acid with a concentration of 37% therein, react for 1 hour after the dropwise addi...

Embodiment 2

[0064] An improved slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 45 kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 30 kg of hydrogen-terminated polysiloxane, 65 kg of 107 silicone rubber, and hydrophobic gas-phase 30kg of white carbon black, 5kg of nano-zinc oxide, 4kg of oleyl amino oleate, 6kg of nano-calcium carbonate, 3kg of ketoxime type crosslinking agent, 10kg of talcum powder, 2kg of silane coupling agent, 2kg of decabromodiphenyl ether and 175kg of organic solvent ;

[0065] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:

[0066] ①Stir 60kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 150kg of dodecamethylcyclohexasiloxane evenly, add 10kg of sodium sulfate, stir evenly and heat up to 70°C, Then, 5 kg of concentrated hydrochloric acid with a concentration of 37% was added dropwise...

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Abstract

The invention discloses an improved Type-1 slow-release long-acting superhydrophobic anti-pollution-flashover paint which is composed of the following raw materials in parts by weight: 35-45 parts of hydroxypropyl-terminated fluorine-containing polysiloxane, 20-30 parts of hydrogen-terminated polysiloxane, 55-65 parts of 107 silicone rubber, 20-30 parts of hydrophobic fumed silica, 3-5 parts of nano zinc oxide, 2-4 parts of amino oleate, 4-6 parts of nano calcium carbonate, 1-3 parts of ketoxime crosslinking agent, 5-10 parts of talcum powder, 1-2 parts of silane coupling agent, 1-2 parts of decabromodiphenyl oxide and 165-175 parts of organic solvent. The improved Type-1 slow-release long-acting superhydrophobic anti-pollution-flashover paint has the advantages of high mechanical properties, long service life (up to 15 years), favorable flame retardancy (Grade FV-0), favorable salt fog aging resistance and excellent pollution resistance, can still be effective in the smog pollution days, achieves the expected anti-pollution-flashover effect, and avoids the pollution flashover accident.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to an improved slow-release long-acting super-hydrophobic antifouling flashover coating. Background technique [0002] Pollution flashover accidents involve a wide range of areas, and the power outage lasts for a long time, which seriously threatens the operation safety of power transmission and transformation equipment. Especially in winter, there are thousands of pollution flashover trips in the national power grid, sometimes almost causing the provincial power grid to be disconnected. The anti-fouling flashover measures are nothing more than four main measures: taking measures to adjust creepage, cleaning insulators, using synthetic insulators, and coating RTV paint (room temperature vulcanized silicone rubber). Comprehensive investigation and comparison of the above anti-fouling flashover measures, it can be seen that coating RTV paint is the most economical and effective measu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/06C09D183/08C09D183/05C09D7/61C09D7/63C08G77/385C08G77/12
CPCC08G77/12C08G77/385C08K2201/011C09D7/61C09D7/62C09D7/63C09D7/65C09D183/06C08L83/08C08L83/04C08K13/06C08K9/04C08K3/36C08K5/06C08K2003/2296
Inventor 冯迎春马玮杰乔耀华王洪川韩正新杜远冯海清袁森陈培峰周洋卢志鹏
Owner STATE GRID CORP OF CHINA
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