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A pc/abs material with high binding force and easy electroplating and its preparation method

A technology of ABS material and binding force, which is applied in the field of PC/ABS material and its preparation, can solve the problems of reduced electroplatability, coating binding force, failure to meet the performance requirements of electroplated products, poor heat resistance, and weather resistance, etc., to improve The overall physical properties, broaden the field of use, good effect of dimensional stability

Active Publication Date: 2018-11-09
广东道生科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, PC resin has high melt viscosity, difficult processing and molding, especially large-scale products are prone to stress cracking, poor chemical resistance, and high price. These deficiencies limit the application of PC to a certain extent; the performance of ABS resin is between engineering Between plastics and general-purpose plastics, it has good impact resistance and processing performance, and the price is relatively cheap, so it has been widely used.
However, its heat resistance and weather resistance are poor, and its mechanical properties are not ideal.
The PC / ABS alloy with PC and ABS as the main raw materials is an important engineering plastic alloy, which has the characteristics of good processing formability, corrosion resistance and toughness, but its heat resistance and weather resistance are poor, and its mechanical properties are not ideal.
Moreover, PC is the main component of PC / ABS alloy materials, which results in a significant reduction in the number of electroplating points of PC / ABS materials, reduces its electroplatability, coating bonding strength and other properties, and cannot meet the increasingly higher performance requirements of electroplating products.

Method used

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  • A pc/abs material with high binding force and easy electroplating and its preparation method
  • A pc/abs material with high binding force and easy electroplating and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Modified carbon fiber of the present invention has following method to prepare:

[0028] The modified carbon fiber is made by putting 97% by weight of PAN-based carbon fiber and 3% by weight of anti-sedimentation aluminate ASA into a high-speed mixer, and mixing uniformly at 100°C with a rotating speed of 750RPM.

Embodiment 2

[0030] Weigh 15% by weight of the modified carbon fiber of Example 1 for pre-drying, and dry at 130°C for 4 hours; then 61% by weight of PC, 20% by weight of ABS, 3.3% by weight of toughening compatibilizer, The dispersant of 0.2% by weight, the lubricant of 0.2% by weight and the antioxidant of 0.3% by weight are added in the high-speed mixer, at 55-65 ℃, mix well; The extrusion granulation is carried out in the extruder, and the extruder is divided into 10 zones: zone 1 (230°C), zone 2 (240°C), zone 3 (240°C), zone 4 (245°C), zone 5 (250°C) , Zone 6 (250°C), Zone 7 (245°C), Zone 8 (250°C), Zone 9 (245°C), Zone 10 (260°C); the particles after extrusion granulation are re-dried before injection molding , to prepare the standard splines required for testing performance. The test standards and test results are shown in Table 2.

Embodiment 3

[0032] Weigh 27% by weight of the modified carbon fiber of Example 1 for pre-drying, and dry at 130°C for 4 hours; then 41% by weight of PC, 28% by weight of ABS, 3.3% by weight of toughening compatibilizer, The dispersant of 0.2% by weight, the lubricant of 0.2% by weight and the antioxidant of 0.3% by weight are added in the high-speed mixer, at 55-65 ℃, mix well; The extrusion granulation is carried out in the extruder, and the extruder is divided into 10 zones: zone 1 (230°C), zone 2 (240°C), zone 3 (240°C), zone 4 (245°C), zone 5 (250°C) , Zone 6 (250°C), Zone 7 (245°C), Zone 8 (250°C), Zone 9 (245°C), Zone 10 (260°C); the particles after extrusion granulation are re-dried before injection molding , to prepare the standard splines required for testing performance. The test standards and test results are shown in Table 2.

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Abstract

The invention relates to a PC / ABS material with high binding force and easy to electroplate and a preparation method thereof. The PC / ABS material is prepared from the following components by a weight ratio: 33.4 to 61.3 percent of PC, 20 to 30 percent of ABS, 15 to 30 percent of modified carbon fiber, 3 to 5 percent of compatilizer, 0.2 to 0.5 percent of dispersant, 0.3 to 1 percent of antioxidant and 0.2 to 0.5 percent of lubricant. The preparation method of the PC / ABS material comprises the following steps of mixing all the components into a mixing agitator according to a proportion to carry out mixing; blending and granulating an obtained mixture through a twin screw extruder. The method provided by the invention is simple, easy and feasible; the dispersion, in a PC / ABS matrix, of the carbon fiber is promoted through the introduction of the compatilizer, so that the excellent electric conduction performance can be given to a PC / ABS alloy composition through a minute quantity of the carbon fiber; the linear expansion coefficient of the composition is decreased; an electroplating procedure can be directly carried out; coarsening, activating and chemical plating procedures are omitted; the electroplating procedure is simplified; a product composition provided by the invention has high mechanical strength; further, the dimensional stability is good.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a PC / ABS material with high binding force and easy electroplating and a preparation method thereof. Background technique [0002] At present, the casing materials of office supplies are mostly PC resin, ABS resin or PC / ABS composite resin. However, PC resin has high melt viscosity, difficult processing and molding, especially large-scale products are prone to stress cracking, poor chemical resistance, and high price. These deficiencies limit the application of PC to a certain extent; the performance of ABS resin is between engineering Between plastics and general-purpose plastics, it has good impact resistance and processing performance, and the price is relatively cheap, so it has been widely used. However, its heat resistance and weather resistance are poor, and its mechanical properties are not ideal. The PC / ABS alloy with PC and ABS as the main raw materials is an...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L69/00C08L55/02C08L35/06C08K13/06C08K9/04C08K7/06C08K5/134C08K5/526
CPCC08K2201/001C08L69/00C08L2205/035C08L2205/08C08L55/02C08L35/06C08K13/06C08K9/04C08K7/06C08K5/1345C08K5/526
Inventor 李本立郑少辉徐建辉徐正国
Owner 广东道生科技股份有限公司
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