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Organic-inorganic hybrid semi-conductive dicyclohexyl-imine bismuth bromide compound and crystal and preparation method and use thereof

A technology of dicyclohexylimide bismuth bromide and cycloheximide salt is applied in the directions of organic chemistry methods, organic chemistry, photometry using electric radiation detectors, etc. The effects of stable physical and chemical properties, low preparation cost, and easy cutting

Active Publication Date: 2017-04-05
FUJIAN INST OF RES ON THE STRUCTURE OF MATTER CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Currently, people are interested in CH 3 NH 3 PB 3 The photoelectric performance research of lead-based composite materials has made great progress, but the existence of the toxic metal lead element contained in the material restricts its wide application, especially this kind of material is very easy to dissolve in water and release Pb to the environment causing pollution in

Method used

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  • Organic-inorganic hybrid semi-conductive dicyclohexyl-imine bismuth bromide compound and crystal and preparation method and use thereof
  • Organic-inorganic hybrid semi-conductive dicyclohexyl-imine bismuth bromide compound and crystal and preparation method and use thereof
  • Organic-inorganic hybrid semi-conductive dicyclohexyl-imine bismuth bromide compound and crystal and preparation method and use thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0047] About (C 6 h 12 NH 2 ) 2 BiBr 5 The synthesis of raw material adopts water / ethanol (both volume ratio is 1:1) as mixed solvent, with C 6 h 12 NH, Bi 2 o 3 Mix the three initial raw materials with HBr according to the molar ratio of 4:1:10, and the reaction equation is as follows:

[0048] 4C 6 h 12 NH+Bi 2 o 3 +10HBr=2(C 6 h 12 NH 2 ) 2 BiBr 5 +3H 2 o

[0049] Concrete implementation steps: 0.04mol C 6 h 12 NH and 0.01mol Bi 2 o 3 Add to 30ml of water / ethanol mixed solvent, slowly add 0.1mol HBr under the condition of vigorous stirring, and gradually dissolve the precipitate in the solution as the reaction proceeds; continue to add 0.05mol HBr to adjust the pH value of the solution, and then the obtained The solution is subjected to microporous filtration, and the solvent is evaporated to dryness to obtain the raw material.

Embodiment 2

[0051] Different from Example 1, the C 6 h 12 NH 2 Br, BiBr 3 The three initial raw materials of HBr and HBr are mixed and reacted according to the molar ratio of 2:1:5. Regulate the amount of added HBr to control the solution pH value in the reaction process, finally can obtain identical (C 6 h 12 NH 2 ) 2 BiBr 5 compound.

Embodiment 3

[0053] Different from Example 1, the C 6 h 12 NH 2 Cl, BiCl 3 The three initial raw materials of HBr and HBr are mixed and reacted according to the molar ratio of 2:1:6. Regulate the amount of added HBr to control the solution pH value in the reaction process, finally can obtain identical (C 6 h 12 NH 2 ) 2 BiBr 5 compound.

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Abstract

The invention relates to an organic-inorganic hybrid semi-conductive dicyclohexyl-imine bismuth bromide compound and crystal and a preparation method and use thereof. The chemical formula of the material is (C6H12NH2)2BiBr5, and belongs to a monoclinic system P21 / n space group. The absorption cut-off side length of the crystalline material approximates to 430nm; and the crystal exhibits good photoconductive property, can be used for manufacturing photoconductive detectors, and has potential application value in photoelectric detection, integrated photoelectric functional elements and the like. The synthesis and preparation method disclosed by the invention is high in practicability, simple in path and easy for operation; no complex production equipment is needed; manufacture cost is low; and the synthesis and preparation method is suitable for batch production.

Description

technical field [0001] The present invention relates to a kind of organic / inorganic hybrid semiconductor bismuth bromide dicyclohexylimide compound, crystal and its preparation method and application (molecular formula is C 12 h 28 N 2 BiBr 5 ), belonging to the field of artificial crystal materials in the technical field of optoelectronic functional materials. [0002] technical background [0003] Semiconductor materials are the material basis of modern information science and new energy technology. They play an irreplaceable role in information communication, high-speed computing, large-capacity data processing, renewable clean energy, and large-scale integrated circuits. A pillar industry for national security. Among them, bulk semiconductors are the most important form of existence and application of materials. Representative semiconductor materials such as silicon, germanium, and indium antimonide, which are widely used at present, exist in the form of single crysta...

Claims

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Application Information

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IPC IPC(8): C07D295/027C07D295/023G01J1/42
CPCC07B2200/13C07D295/023C07D295/027G01J1/42
Inventor 罗军华孙志华张静姬成敏张伟川李丽娜
Owner FUJIAN INST OF RES ON THE STRUCTURE OF MATTER CHINESE ACAD OF SCI
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