Perovskite photoelectric detector for accelerating electron filtering
A photodetector and electronic filtering technology, which is applied in the direction of electric solid-state devices, circuits, photovoltaic power generation, etc., can solve the problems of poor exciton blocking ability, low carrier mobility, and short exciton diffusion distance, and achieve the purpose of suppressing excitons. sub-recombination, increase the concentration of excitons, and improve the effect of dissociation ability
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Embodiment 1
[0036] A perovskite photodetector for accelerated electron filtering (structure shown in figure 1As shown), it sets substrate 1 (glass substrate coated with indium tin oxide), anode 2, hole transport layer 3, active layer 4, electron filter layer 5 and composite cathode 6 layer by layer from bottom to top, Its preparation method comprises the following steps:
[0037] 1) Clean the glass substrate (thickness: 90 nanometers) coated with indium tin oxide (ITO) on the surface (15 minutes ultrasonic cleaning with acetone, 15 minutes ultrasonic cleaning with ethanol), and dry the cleaned glass substrate with a nitrogen gun , followed by UV sampling treatment on the ITO surface (processing for 20 minutes);
[0038] 2) Deposition of the hole transport layer on the ITO surface of the glass substrate processed in step 1): the hole transport layer material used is PEDOT:PSS, which is spin-coated on the ITO surface at a rate of 4000 revolutions per second for 30 seconds, and then place ...
Embodiment 2~3
[0046] The structure and preparation method of the perovskite photodetector for accelerated electron filtering described in Examples 2 and 3 are roughly the same as in Example 1, except that the mixing ratios of PC71BM and the exciton blocking material TmPyPB are 40:60 and 60, respectively. : 40, the spectral responsivity of embodiment 1~3 gained perovskite photodetector is with the variation relation of mixing ratio such as Figure 6 shown.
Embodiment 4
[0048] The structure and preparation method of the perovskite photodetector for accelerated electron filtering described in Example 4 are roughly the same as in Example 1, except that the exciton blocking material used is replaced by OXD-7, and the obtained perovskite photodetector The spectral responsivity see Figure 7 , the results show that the use of OXD-7 as an exciton blocking material also exhibits a high spectral responsivity.
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