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Environment-friendly and biodegradable type plastics

A plastic, environmentally friendly technology, applied in the field of environmentally friendly degradable plastics, can solve the problems of strong water absorption, fast decomposition rate, oxidation resistance, weak impact resistance, etc., and achieve low water absorption, slow decomposition rate, and good impact resistance. Effect

Inactive Publication Date: 2017-01-11
GUANGXI NANNING ZHICUI SCI TECH CONSULTATION CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is to provide an environmentally friendly and degradable plastic to solve the problem of fast decomposition rate, weak oxidation resistance, impact resistance and strong water absorption in the prior art. And other issues

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0034] The preparation method of the environment-friendly degradable plastic comprises the following steps:

[0035] S1: Polylactic acid resin, modified poly-β-hydroxybutyrate PHB, diisononyl phthalate DINP, tung oil-based alkyd resin, linear low-density polyethylene grafted with maleic anhydride, and γ-glycidyl ether Oxypropyltrimethoxysilane was mixed and stirred at a temperature of 105-120°C and a rotation speed of 200-400r / min for 10-15min to obtain mixture I;

[0036] S2: Under nitrogen protection, add alkaline clay, calcium carbonate, kapok fiber, methyl methacrylate-butadiene-styrene copolymer, aluminum potassium sulfate, citrate, Ethylene-vinyl acetate copolymer, ethylene bisoleic acid amide, diphenylmethane diisocyanate, degradation agent, stirring at ultrasonic power of 120-180W, temperature of 90-96°C, rotation speed of 200-300r / min for 2- 2.5h, the mixture II was obtained;

[0037] S3: Add soybean protein powder, oxidized tapioca starch, anti-mold and antibacteri...

Embodiment 1

[0041] An environmentally friendly degradable plastic, in parts by weight, comprising the following raw materials: 120 parts of polylactic acid resin, 80 parts of modified poly-β-hydroxybutyric acid PHB, 8 parts of diisononyl phthalate DINP, tung oil base 20 parts of alkyd resin, 13 parts of soybean protein powder, 10 parts of oxidized tapioca starch, 6 parts of alkaline clay, 5 parts of calcium carbonate, 12 parts of kapok fiber, 1.5 parts of linear low density polyethylene grafted maleic anhydride, γ-shrinkage 1.5 parts of glyceryl ether oxypropyltrimethoxysilane, 2.5 parts of methyl methacrylate-butadiene-styrene copolymer, 1.5 parts of potassium aluminum sulfate, 3.5 parts of citrate, 2.5 parts of ethylene-vinyl acetate copolymer, 2 parts of ethylene bisoleic acid amide, 1.5 parts of diphenylmethane diisocyanate, 2.1 parts of antifungal and antibacterial agent, 1.5 parts of degradation agent, 0.9 part of antioxidant, 0.8 part of stabilizer;

[0042] The alkaline clay is na...

Embodiment 2

[0054] An environmentally friendly degradable plastic, in parts by weight, including the following raw materials: 102 parts of polylactic acid resin, 76 parts of modified poly-β-hydroxybutyric acid PHB, 6 parts of diisononyl phthalate DINP, tung oil base 15 parts of alkyd resin, 10 parts of soybean protein powder, 7 parts of oxidized tapioca starch, 3 parts of alkaline clay, 3 parts of calcium carbonate, 8 parts of kapok fiber, 1 part of linear low density polyethylene grafted maleic anhydride, γ-shrinkage 1 part of glyceryl ether oxypropyltrimethoxysilane, 2 parts of methyl methacrylate-butadiene-styrene copolymer, 1 part of aluminum potassium sulfate, 3 parts of citrate, 2 parts of ethylene-vinyl acetate copolymer, 1 part of ethylene bisoleic acid amide, 1 part of diphenylmethane diisocyanate, 0.8 part of anti-mold and antibacterial agent, 1 part of degradation agent, 0.6 part of antioxidant, 0.5 part of stabilizer;

[0055] The alkaline clay is nanoscale alkaline clay;

[...

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PUM

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Abstract

The invention discloses environment-friendly and biodegradable type plastics. The environment-friendly and biodegradable type plastics comprises polylactic resin, modified polyvinyl-beta-hydroxybutyric acid PH B, diisononyl phthalate (DINP), tung oil based alkyd resin, soybean protein powder, oxidized cassava starch, alkaline clay, calcium carbonate, kapok fiber, linear low-density polyethylene grafted maleic anhydride, gamma-propyl glycidyl ether oxygen based trimethoxy silane, methyl methacrylate-butadiene-styrol copolymer, aluminum potassium sulfate, citrate, ethylene-eva ethylene, ethylene bis oleamide, methylene diphenyl diisocyanate, an antimycotic antibacterial agent, a degradation agent, antioxidant and a stabilizer. The plastics is good in tensile strength and breaking elongation, good in impact resistance, low in water absorption and good in light-transmitting quality, can be completely degraded into carbon dioxide and water after 132-136 days, and harm cannot be caused to the environment.

Description

[0001] 【Technical field】 [0002] The invention belongs to the fields of plastic preparation technology and environmental protection, and in particular relates to an environmentally friendly and degradable plastic. [0003] 【Background technique】 [0004] Plastics are widely used, such as plastic toys, plastic bottles, plastic packaging, plastic bags, etc. We cannot live without plastics. Studies have found that plastic products produced from polylactic acid resin can be completely degraded into carbon dioxide and water in a composting environment. Moreover, polylactic acid resin has good compatibility, transparency, solvent resistance and biaxial stretching properties, etc., and can be processed in a variety of ways. At present, the more common plastic products at home and abroad are disposable cups, knives and forks, plates, Plastic bags, non-woven fabrics, etc., theoretically as long as they are plastic products, can be made of this bioplastic material. [0005] However, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L67/08C08L89/00C08L3/10C08L51/06C08K13/02C08K3/34C08K3/26C08K5/134C08K5/11C08K3/22
CPCC08L67/04C08K2201/011C08L2201/06C08L2201/08C08L2205/025C08L2205/035C08L2205/16C08L67/08C08L89/00C08L3/10C08L51/06C08K13/02C08K3/346C08K2003/265C08K5/1345C08K5/11C08K2003/2241
Inventor 朱俊宇
Owner GUANGXI NANNING ZHICUI SCI TECH CONSULTATION CO LTD
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