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A kind of preparation method of porous oil-containing lubricating material

A technology of lubricating material and preparation steps, applied in the field of lubricating material preparation, can solve problems such as precipitation easily affected by the environment, uneven pore distribution, failure of lubricating material, etc., and achieve the effect of long-term effective lubrication, good bonding, and avoiding pollution

Active Publication Date: 2018-12-04
周佰芹
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem mainly solved by the present invention is that existing porous oil-containing lubricating materials have uneven pore distribution, low porosity, low self-strength, poor bonding force with the matrix, and the pores are easily affected by the environment and precipitated when the lubricating oil material is adsorbed. The problem leading to the failure of lubricating materials provides a preparation method of porous oil-containing lubricating materials. In this method, the prepared black fungus powder and chitinase solution are stirred and mixed, and the supernatant is obtained after deactivation and centrifugation. After stirring and mixing with absolute ethanol, centrifuge to collect the lower precipitate to obtain black fungus polysaccharide, then heat it with deionized water and trisodium citrate in a water bath, and ultrasonically disperse to make a black fungus polysaccharide dispersion, then mix lubricating oil with black The lubricating mixture prepared by mixing the fungus polysaccharide dispersion is mixed with styrene monomer and acrylate, heated and filtered, and the obtained filter cake is washed and dried to make modified oleoresin particles, which are mixed with talcum powder and azodicarbonamide Mixing and banburying, followed by discharge and cooling, a porous oil-containing lubricating material can be prepared. The preparation process of the present invention is simple, and the prepared lubricating material has a rich porous structure, and the pores are evenly distributed, and the strength is high, and it is compatible with the matrix. High binding force, not affected by the environment, can continuously and stably supply oil to the friction pair, and has a large application space

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0020] First collect the fresh black fungus, wash it and dry it naturally, collect the dried black fungus and grind it, then mix the black fungus powder with the chitinase solution with an enzyme activity of 30U / mL at a mass ratio of 1:100 , heated in a water bath at 40°C for 1h; after the completion of the water bath heating, continue to heat up to 75°C, then incubate and inactivate the enzyme for 1h, then centrifuge at 6800r / min for 10min, collect the supernatant, and use a volume ratio of 1:4 , the supernatant was stirred and mixed with absolute ethanol, treated in an ice-water bath at 0°C for 6h, then centrifuged at 6000r / min for 10min, and the lower layer was collected and freeze-dried to prepare the black fungus polysaccharide; and calculated in parts by weight , respectively weighed 45 parts of deionized water, 10 parts of black fungus polysaccharide prepared above, and 5 parts of trisodium citrate were placed in a Erlenmeyer flask, heated in a water bath at 65°C for 25 ...

example 2

[0023]First collect the fresh black fungus, wash it and dry it naturally, collect the dried black fungus and grind it, then mix the black fungus powder with the chitinase solution with an enzyme activity of 30U / mL at a mass ratio of 1:100 , heated in a water bath at 43°C for 1.5h; after the completion of the water bath heating, continue to heat up to 75-80°C, then heat-preserve and inactivate the enzyme for 1.5h, then centrifuge at 6900r / min for 13min, collect the supernatant, and press the volume Mix the supernatant with absolute ethanol at a ratio of 1:4, treat it in an ice-water bath at 3°C ​​for 7 hours, then centrifuge at 7000r / min for 13 minutes, collect the lower precipitate and freeze-dry to prepare the black fungus polysaccharide; then press In terms of parts by weight, weigh 48 parts of deionized water, 13 parts of black fungus polysaccharide prepared above, and 8 parts of trisodium citrate in a Erlenmeyer flask, heat in a water bath at 68°C for 280 minutes, and then ...

example 3

[0026] First collect the fresh black fungus, wash it and dry it naturally, collect the dried black fungus and grind it, then mix the black fungus powder with the chitinase solution with an enzyme activity of 30U / mL at a mass ratio of 1:100 , heated in a water bath at 45°C for 2h; after the completion of the water bath heating, continue to heat up to 80°C, then heat-preserve and inactivate the enzyme for 2h, then centrifuge at 7000r / min for 15min, collect the supernatant, and use a volume ratio of 1:4 , the supernatant was stirred and mixed with absolute ethanol, treated in an ice-water bath at 5°C for 8 hours, and then centrifuged at 8000r / min for 15 minutes, and the lower layer was collected and freeze-dried to prepare black fungus polysaccharides; and calculated in parts by weight , weighed 50 parts of deionized water, 15 parts of black fungus polysaccharide prepared above, and 10 parts of trisodium citrate were placed in a conical flask, heated in a water bath at 70°C for 30...

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Abstract

The invention discloses a method for preparing a porous oil-containing lubricating material and belongs to the technical field of lubricating material preparation. In the invention, prepared black fungus powder is mixed with chitinase solution through stirring, enzyme deactivation and centrifugal separation treatment are performed to obtain supernatant, the supernatant is mixed with absolute ethyl alcohol, then centrifugal separation and sediment collection are performed to obtain black fungus polysaccharides, then the black fungus polysaccharides, deionized water and trisodium citrate are subjected to heating and ultrasonic dispersion treatment to obtain black fungus polysaccharide dispersion liquid, then lubricating mixture liquid prepared by mixing lubricating oil with the black fungus polysaccharide dispersion liquid is mixed with styrene monomers and acrylate, heating and filtration are performed, a filter cake is collected, washed and dried to obtain modified oil-containing resin particles, the modified oil-containing resin particles are mixed with talcum powder and azodicarbonamide, then kneading is performed, and then discharging and cooling are performed to obtain a porous oil-containing lubricating material. The lubricating material prepared by adopting the method disclosed by the invention has the advantages of high porosity, uniform distribution, high material strength, good binding force with substrates and greater application space.

Description

technical field [0001] The invention discloses a preparation method of a porous oil-containing lubricating material, belonging to the technical field of lubricating material preparation. Background technique [0002] With the continuous development of society, people's requirements for the quality of social products are getting higher and higher, which also puts forward higher standards for the production of industry and daily necessities. As a result, the industrial revolution was set off, and the industrial revolution also led to the technological upgrading of equipment. [0003] When two objects in close contact move relative to each other along their contact surfaces, there will be a kind of resistance, which is friction force, and this phenomenon is friction. Two friction surfaces that are in contact with each other are called friction pairs. Any mechanical movement is realized by the relative motion of various friction pairs, so friction is inevitable. Friction cause...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10M169/04F16N7/12C10M177/00C10N30/06
CPCC10M169/044C10M177/00C10M2201/102C10M2215/182C10N2030/06F16N7/12C10N2010/04
Inventor 金峰高玉刚薛蕾
Owner 周佰芹
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