Liquid crystal aligning agent, liquid crystal alignment film and liquid crystal display element
A liquid crystal display technology, applied in the field of liquid crystal alignment agent, liquid crystal alignment film and liquid crystal display elements, can solve the problems of static electricity, dust generation, and the inability to rub the liquid crystal alignment film evenly
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[0240] [Preparation of polymer composition]
[0241] The polymer composition used in the present invention is preferably prepared in the form of a coating liquid so as to be suitable for forming a liquid crystal aligning film. That is, the polymer composition used in the present invention is preferably prepared in the form of a solution in which a resin component for forming a resin coating is dissolved in an organic solvent. Here, the resin component refers to a resin component containing the above-mentioned photosensitive side chain type polymer capable of expressing liquid crystallinity. In this case, the content of the resin component is preferably 1% by mass to 20% by mass, more preferably 3% by mass to 15% by mass, particularly preferably 3% by mass to 10% by mass.
[0242] In the polymer composition of this embodiment, the above-mentioned resin components may all be the above-mentioned photosensitive side chain polymers capable of exhibiting liquid crystallinity, but t...
Embodiment
[0403] Hereinafter, although an Example is used and this invention is demonstrated, this invention is not limited to this Example.
[0404] The analysis apparatus and analysis conditions used for the synthesis of the specific glycidyl compound of this invention are shown below.
[0405] ( 1 H-NMR measurement)
[0406] Device: Varian NMR System 400NB (400MHz) (manufactured by Varian)
[0407] Determination solvent: CDCl 3 (deuterochloroform), DMSO-d 6 (Deuterated Dimethyl Sulfoxide)
[0408] Reference material: TMS (tetramethylsilane) (δ: 0.0ppm, 1 H), CDCl 3 (δ: 77.0ppm, 13 c)
[0409] Abbreviations used in Examples are as follows.
[0410]
[0411]
[0412] MA1 was synthesized by the synthesis method described in the patent document (WO2011-084546).
[0413] MA2 was synthesized by the synthesis method described in the patent document (Japanese Patent Laid-Open No. 9-118717).
[0414]
[0415] T1: Primid XL-552: (N,N,N',N'-tetrakis-(2-hydroxyethyl)adipamide) ...
Embodiment 1
[0467] 33.33 g of BCS and 0.15 g of T1 were added to 50.0 g of methacrylic polymer solution M1 obtained in polymerization example 1, and it stirred at room temperature for 3 hours, and obtained liquid crystal aligning agent AL1.
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