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A device and method for treating nitrogen oxides in condensed acid

A technology of nitrogen oxides and spraying devices, applied in chemical instruments and methods, separation methods, and separation of dispersed particles, etc., can solve the problem of exceeding the standard; it may also enter the finished sulfuric acid, the quality of the finished acid is unqualified, and a large amount of brown smoke appears, etc. problems, to achieve the effect of improving the working environment, operating cost economy, and preventing contact

Active Publication Date: 2018-06-19
JINCHUAN GROUP LIMITED
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The nitrogen oxides in the sulfuric acid production system may be discharged into the atmosphere along with the tail gas, causing the nitrogen oxides to exceed the standard during the exhaust gas discharge process; they may also enter the finished sulfuric acid, resulting in a red color of the finished acid and unqualified quality of the finished acid; Concentrated in the acid liquid collected by the fiber demister and converted into the condensed acid of the external heat exchanger, resulting in a large amount of brown smoke during the process of flushing the dry suction mist catcher and discharging the condensed acid from the external heat exchanger, if not Taking corresponding measures in time will not only cause environmental pollution, but also cause certain harm to people.

Method used

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  • A device and method for treating nitrogen oxides in condensed acid
  • A device and method for treating nitrogen oxides in condensed acid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Add condensed acid and water to the mixing tank in a volume ratio of 1:3. The mixing tank is filled with clean water to 3.1 meters. The condensed acid enters the mixing tank after mixing the acid through the acid mixer, and releases a large amount of nitrogen oxides after fully mixing with water ; Add a urea solution with a concentration of 21.5% and water in a volume ratio of 1:2 into the absorption liquid circulation tank to configure a 7.6% dilute solution, and the liquid level is controlled at 3 meters.

[0028] Start the fan, the condensed acid and water will be fully mixed and release a large amount of nitrogen oxides. With the slight negative pressure (-3.4KPa) of the fan, it will escape to the upper part of the spray absorption tower through the liquid barrier; start the absorption pump to absorb The liquid is transported to the tube-tank liquid separator in the spray absorption tower, and the tube-tank liquid separator is started to spray the absorption liquid down...

Embodiment 2

[0030] Add condensed acid and water to the mixing tank at a volume ratio of 1:2.5. The mixing tank is filled with clean water to 3.15 meters. The condensed acid enters the mixing tank after mixing the acid through the acid mixer, and releases a large amount of nitrogen oxides after fully mixing with water ; Add 18.5% urea solution and water in a volume ratio of 1:1 into the absorption liquid circulation tank to form an 8.5% dilute solution, and the liquid level is controlled at 3 meters.

[0031] Start the fan, the condensation acid and water will release a large amount of nitrogen oxides, and the slight negative pressure (-3.6KPa) of the fan will escape upward through the liquid septum to the upper part of the spray absorption tower, and be absorbed by the urea solution; start The absorption pump transports the absorption liquid to the spray device in the spray absorption tower. The absorption liquid is in countercurrent contact with the nitrogen oxide gas, and the nitrogen oxide...

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Abstract

The invention discloses a device and a method for treating nitrogen oxide in condensed acid. The device comprises a spraying absorption tower, wherein the spraying absorption tower comprises a tower body, the top of the tower body is connected with a fan through a smoke exhaust pipe, and a spraying device, a filler layer, a gas-liquid separation device and a liquid mixing tank are sequentially arranged in the tower body from top to bottom; the gas-liquid separation device comprises a plurality of groups of liquid baffle plates and liquid isolation covers for covering the liquid baffle plates of each group; a liquid outlet is formed in the sidewall of the liquid mixing tank, and the upper part of the liquid mixing tank is connected with an acid mixer and a water inlet pipe. The device also comprises an absorption liquid circulation tank and an absorption pump, wherein the gas-liquid separation device, the absorption liquid circulation tank, the absorption pump and the spraying device are sequentially connected. According to the device and the method, escape of waste gas and production of waste are avoided in the whole process, and the absorption efficiency is high.

Description

Technical field [0001] The invention relates to the technical field of sulfuric acid production, in particular to a device and method for treating nitrogen oxides in condensed acid. Background technique [0002] NO x It is an acid gaseous pollutant and one of the main causes of photochemical smog and acid rain. In the kiln of the front-end device of smelting flue gas sulphuric acid production, as the flame temperature increases, molecular oxygen and nitrogen will generate nitrogen oxides. Especially when oxygen-enriched smelting is used, the production of nitrogen oxides will increase; In the electric precipitator and electric mist eliminator of the device, nitrogen oxides are also generated as the discharge process occurs. The nitrogen oxides in the sulfuric acid production system may be discharged into the atmosphere with the exhaust gas, causing excessive nitrogen oxides during the exhaust gas emission process; it may also enter the finished sulfuric acid, causing the color o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/78B01D53/56
CPCB01D53/56B01D53/78B01D2251/2067
Inventor 孙治忠常全忠史万敬李山东谢成程楚宋莹程华花
Owner JINCHUAN GROUP LIMITED
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