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Titanium sol modified flame-retardant optical cable material and preparation method thereof

A titanium sol and modification technology, applied in the field of optical cable materials, can solve the problems affecting the comprehensive performance of polystyrene and the agglomeration of modified particles, so as to improve the thermal decomposition temperature and carbon formation, improve the dispersion, and improve the fire safety Effect

Inactive Publication Date: 2016-09-07
安徽电信器材贸易工业有限责任公司
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  • Abstract
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  • Application Information

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Problems solved by technology

[0006] However, a large amount of addition leads to the agglomeration of modified particles in the matrix resin, which will affect the comprehensive performance of polystyrene

Method used

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Embodiment Construction

[0022] A titanium sol modified flame-retardant optical cable material, which is composed of the following raw materials in parts by weight:

[0023] Talc powder 10, calcium aluminate 1, polytetrafluoroethylene wax 4, potassium perfluorobutane sulfonate 0.4, epoxy soybean oil 2, polyvinyl chloride 100, polystyrene 20 sodium hypophosphite monohydrate 3, paraformaldehyde 2. 35% hydrochloric acid 0.2, chlorinated spirocyclic phosphate 4, aluminum chloride hexahydrate 5, triethylamine 0.1, tetrabutyl titanate 2, polyglycerin fatty acid ester 0.1, magnesium sulfate 1, hydroxyethyl cellulose Su 0.8, calcium lactobionate 2, acetic acid 1.

[0024] A preparation method of the titanium sol modified flame retardant optical cable material, comprising the following steps:

[0025] (1) Take the above-mentioned sodium hypophosphite monohydrate, add it to deionized water 50 times its weight, stir evenly, put it into a constant temperature water bath at 76°C, slowly add the above-mentioned pa...

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Abstract

The invention discloses a titanium sol modified flame-retardant optical cable material, which is prepared from the following raw materials in parts by weight: 10 to 13 parts of talcum powder, 1 to 2 parts of calcium aluminate, 4 to 5 parts of polytetrafluoroethylene wax, 0.4 to 1 part of potassium perfluorobutanesulfonate, 2 to 3 parts of epoxidized soybean oil, 100 to 130 parts of polyvinyl chloride, 20 to 27 parts of polystyrene, 3 to 4 parts of sodium hypophosphite hydrate, 2 to 3 parts of paraformaldehyde, 0.2 to 0.3 part of 35-37-percent hydrochloric acid, 4 to 6 parts of dichloropentate, 5 to 7 parts of aluminum chloride hexahydrate, 0.1 to 0.2 part of triethylamine, 2 to 3 parts of tetrabutyl titanate, 0.1 to 0.4 part of polyglycerol fatty acid ester, 1 to 2 parts of magnesium sulfate, 0.8 to 1 part of hydroxyethyl cellulose, 2 to 3 parts of calcium lactobionate and 1 to 2 parts of acetic acid. The titanium sol modified flame-retardant optical cable material has the advantages that the effects of diluting flame and reducing temperature in a burning region can be achieved; in addition, free radicals generated during polystyrene chain segment cracking can be captured through some phosphorous oxide free radials and the like generated during the cracking; the thermal stability of the material is improved; the heat release value of the material is reduced.

Description

technical field [0001] The invention relates to the technical field of optical cable materials, in particular to a titanium sol modified flame-retardant optical cable material and a preparation method thereof. Background technique [0002] In recent years, nanotechnology has attracted widespread attention in the field of flame retardancy. Studies have shown that nanomaterials only need a small amount of addition (generally less than 5%) to achieve a more obvious flame retardancy effect. Therefore, the preparation of flame-retardant nanocomposites is an important component in the field of flame-retardant technology, and is highly regarded by researchers. Layered inorganic nanomaterials are one of the most effective filler materials in flame-retardant nanocomposites. When layered inorganic nanomaterials are dispersed in the polymer matrix at the nanoscale, they can significantly improve the mechanical properties of nanocomposites. , thermal stability and flame retardant prope...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L25/06C08L27/18C08L91/00C08L59/00C08L1/28C08K13/02C08K3/22C08K5/5317C08K3/34
CPCC08L27/06C08L2201/02C08L2201/08C08L2205/02C08L2205/035
Inventor 王卫东余文辉韩伟
Owner 安徽电信器材贸易工业有限责任公司
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