Dry solid of anion-modified cellulose nanofiber and method for producing same
A technology of anion modification and nanofiber, which is applied in the direction of surface coating liquid device, coating, pretreatment surface, etc., which can solve the problems of storage space storage and transportation cost increase
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Embodiment 1
[0090]
[0091] The above-mentioned carboxylated CNF (carboxyl group amount: 1.6 mmol / g, average fiber diameter: 40 nm, aspect ratio: 150) was used as anion-modified CNF. 40% by mass relative to the anion-modified CNF was added to a 0.7% by mass aqueous suspension of anion-modified CNF (that is, when the solid content of anion-modified CNF was 100 parts by mass, the solid content of carboxymethyl cellulose 40 parts by mass) of carboxymethylcellulose (trade name: F350HC-4, viscosity (1%, 25°C) about 3000mPa·s, carboxymethyl substitution degree about 0.9), in a TK homomixer (12,000rpm) Stirring in medium temperature for 60 minutes to prepare an aqueous dispersion of anion-modified CNF. The pH of this dispersion liquid is about 7-8. Add 0.5% sodium hydroxide aqueous solution to the aqueous dispersion, adjust the pH to 9, and apply it on the surface of the drum of a drum dryer D0405 (manufactured by Katuragi Industrial Co., Ltd.) to form a film with a thickness of about 100 to ...
Embodiment 2
[0107] In manufacture of a dry solid substance, it carried out similarly to Example 1 except having adjusted pH to 8.
Embodiment 3
[0109] In manufacture of a dry solid substance, it carried out similarly to Example 1 except having adjusted pH to 11.
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