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Compound fertilizer synergist modified by oxidized graphene and preparation method of compound fertilizer synergist

A graphene modification, compound fertilizer technology, applied in fertilization devices, fertilizer mixtures, applications, etc., can solve the problems of insignificant synergy effect of phosphate fertilizer and potash fertilizer, difficult to improve the comprehensive utilization rate of compound fertilizer, and unsuitable for long-term application, etc. Easy to mass-produce, strong slow release, and the effect of reducing the loss of fertilizer nutrients

Inactive Publication Date: 2016-05-18
CHENDU NEW KELI CHEM SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In the above-mentioned patents, urease inhibitors and nitrification inhibitors are mostly used as the main components of fertilizer synergists to stabilize nitrogen fertilizer and improve fertilizer efficiency. However, since urease inhibitors and nitrification inhibitors are very easy to pollute water bodies, it is not suitable for long-term application, and the fertilizer effect is prolonged. The period is short, the synergistic effect on phosphorus and potassium fertilizers is not significant, and it is difficult to improve the comprehensive utilization rate of compound fertilizers

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A kind of compound fertilizer synergist is made up of the raw material of following weight part:

[0036] 70 parts of hemp straw, 20 parts of sodium polyglutamate, 0.5 part of ammonium persulfate, 4 parts of sodium carboxymethylcellulose, 5 parts of cyclodextrin, and 0.5 part of graphene oxide.

[0037] A kind of preparation method of compound fertilizer synergist comprises the following steps:

[0038] (1) Put 70 parts by weight of hemp stalks into a high-speed shearing machine for shearing treatment, wash with water to remove dust, dry at 60-80°C, then pulverize with a pulverizer, and pass through a 150-300 mesh sieve;

[0039] (2) Put the agricultural and forestry waste powder screened in step (1) into a closed reactor, irradiate it with plasma for 6 minutes, set the discharge power to 250W, and the vacuum degree to 12-15pa;

[0040] (3) Stir and dissolve 20 parts by weight of sodium polyglutamate and 60-200 parts by weight of water, mix the modified hemp stalk powd...

Embodiment 2

[0043] A kind of compound fertilizer synergist is made up of the raw material of following weight part:

[0044] 40 parts of cotton stalks, 40 parts of wheat straw, 10 parts of butadiene anhydride, 1 part of potassium persulfate, 2 parts of guar gum, 3 parts of gladiolus gum, 10 parts of cyclodextrin, and 0.5 parts of graphene oxide.

[0045] A kind of preparation method of compound fertilizer synergist comprises the following steps:

[0046] (1) Put 40 parts by weight of hemp stalks and 40 parts by weight of wheat straw into a high-speed shearing machine for shearing treatment, wash with water to remove dust, dry at 60-80°C, and then pulverize with a pulverizer, pass through 150-300 mesh screen;

[0047] (2) Put the agricultural and forestry waste powder screened in step (1) into a closed reactor, irradiate it with plasma for 4 minutes, set the discharge power to 300W, and the vacuum degree to 12-15pa;

[0048] (3) Stir and dissolve 10 parts by weight of butadiene anhydride...

Embodiment 3

[0051] A kind of compound fertilizer synergist is made up of the raw material of following weight part:

[0052] 75 parts of reed stalks, 10 parts of polyaspartic acid, 10 parts of konjac glucomannan, 0.5 parts of sodium bisulfite, 3 parts of gum arabic, 6 parts of cyclodextrin, and 0.3 parts of graphene oxide.

[0053] A kind of preparation method of compound fertilizer synergist comprises the following steps:

[0054] (1) 75 parts by weight of reed stalks are put into a high-speed shearing machine for shearing treatment, washed with water to remove dust, dried at 60-80°C, then pulverized with a pulverizer, and passed through a 150-300 mesh sieve;

[0055] (2) Put the reed stalk powder screened in step (1) into a closed reactor, irradiate it with plasma for 4 minutes, set the discharge power to 250W, and the vacuum degree to 12~15pa;

[0056] (3) Add 10-20 parts by weight of polyaspartic acid and 10 parts by weight of konjac glucomannan, stir and dissolve with water at a wei...

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Abstract

The invention belongs to the field of crop fertilizer and particularly relates to compound fertilizer synergist modified by oxidized graphene and a preparation method of the compound fertilizer synergist. The compound fertilizer synergist is prepared from, by weight, 70-80 parts of forestry and agricultural residues, 10-20 parts of a modifying agent, 0.5-1 part of a catalyst, 1-5 parts of stabilizer, 5-10 parts of cyclodextrin and 0.3-0.5 part of the oxidized graphene. The preparation method includes the steps that plasma illumination is utilized to conduct bombardment on the surfaces of forestry and agricultural residues, hydroxide radicals, carbanyl groups, carboxyl and other functional groups containing oxygen are introduced into the surfaces of the forestry and agricultural residues, then polymerization with water-soluble polymer modifier occurs under the action of high-field-intensity ultrasound waves, stable nanometer gel particles of three-dimensional network structures are formed, after modification with the oxidized graphene and cyclodextrin is completed, high adsorption, complexing power and a water-retaining property are achieved, nutrient elements in soil can be subjected to complexing, losing of fertilizer nutrients is reduced, the water retention and fertilizer retention performance of soil is improved, and the utilization rate of compound fertilizer can be remarkably raised. The compound fertilizer synergist has the advantages of being environmentally friendly, free of pollution, capable of raising the utilization rate of fertilizer and improving soil environment and the like.

Description

technical field [0001] The invention belongs to the field of crop fertilizers, in particular to a compound fertilizer synergist modified by graphene oxide and a preparation method thereof. Background technique [0002] my country is a country with a large agricultural development. The small area of ​​arable land and low grain output are the biggest problems facing my country's agricultural development. At present, the important means to increase grain output is the application of chemical fertilizers. my country is the largest producer and user of chemical fertilizers in the world. The annual amount of chemical fertilizer application accounts for 35% of the world's total, but the utilization rate of chemical fertilizers is less than 30%, which is far lower than that of developed countries. In order to improve fertilizer efficiency and fertilizer utilization rate, some new fertilizers are applied, such as compound fertilizers, slow and controlled release fertilizers, biologic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00C05G3/04C05G3/80
CPCC05G3/00C05G3/80
Inventor 陈庆孙丽枝
Owner CHENDU NEW KELI CHEM SCI CO LTD
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