Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Aqueous electrolyte and super-capacitor

A water-based electrolyte and supercapacitor technology, which is applied in the direction of hybrid capacitor electrolyte, etc., can solve the problems of small operating temperature range of supercapacitor, the inability of the electrolyte to maintain the electrochemical properties, and the decrease of the conductivity of the electrolyte, and achieve good electrochemical performance, Not easy to freeze, the effect of large operating temperature range

Active Publication Date: 2016-01-27
CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI
View PDF6 Cites 12 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the temperature range from the freezing point to the boiling point of water in the aqueous electrolyte is small, which makes the operating temperature range of the supercapacitor small and easy to freeze
At the same time, because the solubility of most electrolytes in water decreases with the decrease of temperature, at low temperature, the electrolyte in the aqueous electrolyte will continue to precipitate, and the concentration of the electrolyte will decrease, resulting in a decrease in the conductivity of the electrolyte, and the electrolyte cannot be kept at room temperature. Good electrochemical properties, which affect the performance of the capacitor, and even make the capacitor unusable

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Aqueous electrolyte and super-capacitor
  • Aqueous electrolyte and super-capacitor
  • Aqueous electrolyte and super-capacitor

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0038] The present invention has no special limitation on the preparation method of the supercapacitor, and preferably includes the following steps: uniformly mixing the electrode material and the conductive adhesive to obtain a mixture, and the conductive adhesive is preferably acetylene black and polytetrafluoroethylene;

[0039] coating the mixture on a metal plate and pressing it into a film to obtain a pole piece;

[0040] The two pole pieces are wound together with the diaphragm to form a core package, and placed in the electrolyte to obtain a supercapacitor, and the diaphragm is located between the two pole pieces.

Embodiment 1

[0044] 0.4mol sodium perchlorate (NaClO 4 ) and 0.05mol glucose (C 6 h 12 o 6 ) was dissolved in deionized water, then the solution was diluted to 100ml, and prepared to contain 4mol / LNaClO 4 , and at the same time contain 0.5mol / LC 6 h 12 o 6 aqueous electrolyte.

Embodiment 2

[0046] 0.5mol sodium perchlorate (NaClO 4 ) and 0.1mol glucose (C 6 h 12 o 6 ) was dissolved in deionized water, then the solution was diluted to 100ml, and prepared to contain 5mol / LNaClO 4 , and also contains 1mol / LC 6 h 12 o 6 aqueous electrolyte.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Concentrationaaaaaaaaaa
Login to View More

Abstract

The invention provides an aqueous electrolyte and a super-capacitor. The aqueous electrolyte comprises glucose, water and an inorganic salt. Compared with the prior art, the glucose is added to the aqueous electrolyte taking the inorganic salt as an electrolyte, a solidifying point of the acquired glucose-water-salt electrolyte is relatively lower than that of a water-salt electrolyte, and the glucose-water-salt electrolyte is difficult to freeze and has good electrochemical performance at a relatively low temperature, so that using restrictions of the aqueous electrolyte at low temperature conditions are broken through. Furthermore, sodium perchlorate is selected preferably to act as the electrolyte, so that the acquired aqueous electrolyte is enabled to have higher electric conductivity, a wider working temperature range and a wider potential window, and the aqueous electrolyte is enabled to still have good performance under the low temperature conditions. In addition, the glucose is taken as an anti-freeze additive, so that the solidifying point of the aqueous electrolyte is reduced. The glucose is an environment-friendly substance, and is wide in source, cheap and easy to get.

Description

technical field [0001] The invention belongs to the technical field of electric double layer capacitors, in particular to an aqueous electrolyte and a supercapacitor. Background technique [0002] With the development of society, people's demand for sustainable and clean energy is becoming more and more urgent. Electrochemical supercapacitors, also called supercapacitors, are energy storage components based on the electrochemical reaction process at the electrode / solution interface. The capacity of electrochemical supercapacitors is 20 to 200 times that of traditional capacitors, which can reach farad level or even thousand farad level. It has both the advantages of high power density of conventional capacitors and high energy density of rechargeable batteries, and is considered to be an efficient and practical new energy source. [0003] Supercapacitors can be divided into two categories according to the energy storage mechanism: capacitors using activated carbon with hig...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): H01G11/64H01G11/62
CPCY02E60/13
Inventor 王宏宇高继超齐力
Owner CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products