Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Polycarbonate synthesis process

A technology of polycarbonate and synthesis process, applied in the chemical field, can solve problems such as many side reactions, increase process difficulty, affect product color and quality, and achieve the effect of improving efficiency, improving conversion rate and yield

Active Publication Date: 2016-01-06
NINGBO ZHETIE DAPHOON CHEM
View PDF4 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Because the traditional polycarbonate synthesis process is relatively mature, it is still widely used at present, such as the use of isosorbide and carbonic acid diester esterification reaction in the molten state, and then the finished polycarbonate is obtained through prepolymerization reaction and polycondensation reaction. Although the yield of polycarbonate is high in this process, its synthesis reaction takes a long time and consumes a lot of energy.
At the same time, because the melt transesterification process is carried out at high temperature and high viscosity, there are many side reactions, which affect the color and quality of the product, and the side reactions generated make the selection of catalysts particularly important. The impact of stability requires adding a catalyst quenching step, which will increase the difficulty of the process and hinder the application of melt transesterification supply

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Polycarbonate synthesis process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0016] A polycarbonate synthesis process, comprising the following steps: the first step, stirring and mixing the melted isosorbide and the melted diester carbonate in a raw material mixing tank; the second step, mixing the raw material mixing tank The mixed raw materials are added to the transesterification reactor, and the released hydroxyaryl reaction product is continuously removed; in the third step, the reaction product of the transesterification reaction in the transesterification reactor is added to the tank-type precondensation reactor, and The prepolymerization product is generated in it, and the released hydroxyaryl reaction product is continuously removed; the fourth step is to add the prepolycondensation reactant after the prepolymerization reactor to the horizontal disc polycondensation reactor with hydraulic drive, Microwave treatment is performed on the precondensation reactants to polycondensate into polycarbonate melts.

[0017] Microwaves can accelerate the ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

A polycarbonate synthesis process comprises steps as follows: S1, a raw material mixing stage: melt isosorbide and dialkyl carbonate are stirred and uniformly mixed in a raw material mixing tank; S2, an ester exchange reaction stage: a tower reactor located behind the raw material mixing tank is taken as an ester exchange reactor, and released hydroxyl and aryl reaction products can be removed continuously; S3, a pre-polymerization reaction stage: a kettle pre-polycondensation reactor is arranged behind the ester exchange reactor, a pre-polymerization product is generated in the pre-polycondensation reactor, and meanwhile, released hydroxyl and aryl reaction products are removed continuously; S4: a polycondensation reaction stage: a hydraulic driven horizontal disk polycondensation reactor located behind the pre-polymerization reactor performs microwave processing on a pre-polycondensation product, and the pre-polycondensation product is subjected to polycondensation to form polycarbonate melts. The released hydroxyl and aryl reaction products are removed continuously, so that reaction balance is pushed in the positive direction, the pre-polycondensation product is heated through microwaves in the polycondensation stage, and the reaction rate can be effectively increased.

Description

technical field [0001] The invention relates to the chemical field, in particular to a polycarbonate synthesis process. Background technique [0002] Polycarbonate (referred to as PC) is a high molecular polymer containing carbonate groups in the molecular chain. According to the structure of the ester group, it can be divided into aliphatic, aromatic, aliphatic-aromatic and other types. Among them, the low mechanical properties of aliphatic and aliphatic-aromatic polycarbonates limit their application in engineering plastics. At present, only aromatic polycarbonate has been produced industrially. Due to the special structure of polycarbonate, it has become the fastest-growing general-purpose engineering plastic among the five major engineering plastics. [0003] Because the traditional polycarbonate synthesis process is relatively mature, it is still widely used at present, such as the use of isosorbide and carbonic acid diester esterification reaction in the molten state...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08G64/30
Inventor 傅建永徐小武施懿军邱琪浩周志峰王晨晔王振蔡裕杰
Owner NINGBO ZHETIE DAPHOON CHEM
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products