Macroporous crosslinked antibacterial macromolecular resin containing halamine functional group, as well as preparation and application thereof

A polymer resin and cross-linked polymer technology, applied in the fields of application, botanical equipment and methods, biocides, etc., can solve the problems of high production cost, poor surface hydrophilicity, etc., and achieve enhanced surface hydrophilicity and enhanced antibacterial Efficacy, the effect of reducing production costs

Inactive Publication Date: 2015-12-02
SHANGHAI NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although these two Chinese patents have solved the problem that the U.S. patent US561162 produces a large amount of organic waste liquid and cyanide-containing wastewater and the production cost is too high in the process of producing water-insoluble heterocyclic haloamine polymer sterilization and disinfection resin materials, and the preparation of the U.S. patent US768...

Method used

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  • Macroporous crosslinked antibacterial macromolecular resin containing halamine functional group, as well as preparation and application thereof
  • Macroporous crosslinked antibacterial macromolecular resin containing halamine functional group, as well as preparation and application thereof
  • Macroporous crosslinked antibacterial macromolecular resin containing halamine functional group, as well as preparation and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Present embodiment is the preparation (I) of polymethacrylamide-methylenebisacrylamide macroporous cross-linked resin, and its reaction formula is as follows:

[0042]

[0043] Water phase: Take 2.4g of methacrylamide (MAA), 0.8g of methylenebisacrylamide (MBAA), 0.25g of potassium persulfate (PPS), and 2ml of N,N-dimethylformamide (DMF) into Into a 50ml single-necked flask, add 14ml of deionized water and stir to dissolve, then heat at a constant temperature of 40°C for later use.

[0044] Oil phase: Add 36ml of cyclohexane into a 100ml three-necked flask, then add a small amount of emulsifier OP-4, heat at a constant temperature of 40°C under mechanical stirring for later use.

[0045] After the water phase is dissolved, add the water phase to the oil phase drop by drop, keep the temperature for 0.5h after the addition is completed, then set the temperature to 70°C, adjust the speed to 700r / min, and reflux for 3h to obtain the prepared Polymethacrylamide-methylene...

Embodiment 2

[0048] This embodiment is the preparation (II) of polymethacrylamide-methylenebisacrylamide macroporous cross-linked resin

[0049] Water phase: Take 1.0g of methacrylamide (MAA), 1.0g of methylenebisacrylamide (MBAA), 0.15g of potassium persulfate (PPS), and 2ml of N,N-dimethylformamide (DMF) into Into a 50ml single-necked flask, add 14ml of deionized water and stir to dissolve, then heat at a constant temperature of 40°C for later use.

[0050] Oil phase: Add 36ml of cyclohexane into a 100ml three-necked flask, then add a small amount of emulsifier OP-4, heat at a constant temperature of 40°C under mechanical stirring for later use.

[0051] After the water phase is dissolved, add the water phase to the oil phase drop by drop, keep the temperature for 0.5h after the addition is completed, then set the temperature to 70°C, adjust the speed to 700r / min, and reflux for 3h to obtain the prepared Polymethacrylamide-methylenebisacrylamide macroporous cross-linked resin.

[0052]...

Embodiment 3

[0055] This example is the preparation of polyacrylic acid-methylenebisacrylamide macroporous cross-linked resin, and its reaction formula is as follows:

[0056]

[0057] Water phase: Take 1.0g of acrylic acid (AA), 1.0g of methylenebisacrylamide (MBAA), 0.15g of potassium persulfate (PPS), and 2ml of N,N-dimethylformamide (DMF) into a 50ml single-necked flask Add 14ml of deionized water and stir to dissolve, then heat at 40°C for later use.

[0058] Oil phase: Add 36ml of cyclohexane into a 100ml three-necked flask, then add a small amount of emulsifier OP-4, heat at a constant temperature of 40°C under mechanical stirring for later use.

[0059] After the water phase is dissolved, add the water phase to the oil phase drop by drop, keep the temperature for 0.5h after the addition is completed, then set the temperature to 70°C, adjust the speed to 700r / min, and reflux for 3h to obtain the prepared Polyacrylic acid-methylenebisacrylamide macroporous cross-linked resin.

...

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Abstract

The invention relates to a macroporous crosslinked antibacterial macromolecular resin containing a halamine functional group, as well as preparation and application thereof. According to the preparation, acrylic acid, acrylate, acrylamide and the like serving as monomers of polymerization, an amide crosslinking agent serving as a crosslinking agent of polymerization, and benzene, methylbenzene, xylene and the like serving as a pore-foaming agent perform a polymerization reaction under the action of an initiator to generate a macroporous crosslinked copolymer resin containing a halamine functional group; and the macroporous crosslinked antibacterial macromolecular resin containing a halamine functional group is generated by means of a halogenating reaction of the halamine functional group. Compared with the prior art, the antibacterial macromolecular resin has a quick, effective and broad-spectrum antibacterial effect, can be widely applied to sterilization and disinfection treatment of various water bodies and air and control of harmful unpleasant gases, and can be subjected to certain mixing treatment with other materials to prepare various sanitary antibacterial products, such as antibacterial mattress protectors, antibacterial carpets, antibacterial diapers and the like.

Description

technical field [0001] The invention relates to a high-molecular polymer bactericide, in particular to a macroporous cross-linked bactericidal high-molecular resin containing a haloamine functional group, as well as its preparation and application. Background technique [0002] The application of effective antibacterial and disinfection materials and technologies is an important means to block the spread and prevalence of harmful microorganisms. Due to the disadvantages of high toxicity and easy pollution caused by water-soluble fungicides, the development of water-insoluble polymer fungicides, especially water-insoluble resin fungicides has attracted more and more people's interest. US Patent No. 4,349,646 discloses a method for preparing water-insoluble polyquaternium bactericidal resin by reacting chloromethylated polystyrene resin or polychloromethacrylate resin with tertiary amine or di-tertiary diamine. US4826924 discloses a polystyrene resin or polystyrene-divinylben...

Claims

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Application Information

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IPC IPC(8): C08F220/56C08F222/38C08F220/06C08F8/20C08J9/28A01N37/28A01P1/00
Inventor 梁杰田洪儒
Owner SHANGHAI NORMAL UNIVERSITY
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