Water-based anti-dazzle UV coating, hard coated film and preparation method of hard coated film
A hardened film, water-based technology, applied in the direction of polyurea/polyurethane coatings, coatings, etc., can solve the problem that the hardness and wear resistance of the coating film are not as good as those of solvent-based anti-glare UV coatings, and the tightness is not as good as that of solvent-based anti-glare UV coatings. low level problem
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[0058] The present invention also provides a kind of preparation method of cured film, comprises the following steps:
[0059] A) In parts by weight, 30-90 parts of water-based urethane acrylate prepolymer, 10-60 parts of diluted monomer, 5-100 parts of anti-glare particles, 0.05-10 parts of water-based wetting and dispersing agent, 0.05-5 1 part of water-based leveling agent, 1-20 parts of water, 0.5-10 parts of water-based photoinitiator and 1-30 parts of water-based isocyanate curing agent are mixed to obtain a water-based anti-glare UV coating;
[0060] B) coating the water-based anti-glare UV coating obtained in the step A) on the surface of the substrate, and irradiating with ultraviolet light to obtain a semi-finished hardened film;
[0061] C) thermally curing the semi-finished cured film obtained in step B) to obtain a cured film.
[0062] The present invention is preferably prepared according to the dosage of each component in the step A) and according to the prepar...
Embodiment 1
[0073] The raw materials and consumption (parts by weight) used in this embodiment are shown in Table 1.
[0074] Raw material and consumption of table 1 embodiment of the present invention 1
[0075] Waterborne polyurethane acrylate
UCECOAT 7200
40 copies
Aliphatic Polyurethane Dispersions
UCECOAT 7699
20 copies
pentaerythritol triacrylate
EM 235
20 copies
Dipentaerythritol Pentaacrylate
Miramer M500
20 copies
Deionized water
Deionized water
10 copies
2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone
IRGACURE 2959
2 copies
1-Hydroxy-cyclohexyl-phenylmethanone
IRGACURE 184
3 copies
Silica matting powder
HP230 slurry
10 copies
Organically modified 500nm silica
NSI 500P
10 copies
10-15nm silicon dioxide
IPA-ST
20 copies
Alkanolamine with acidic group polymer copolyester
DISPERBYK-180
0.4 parts
Polyether ...
Embodiment 2
[0085] The raw materials and consumption (parts by weight) used in this embodiment are shown in Table 2.
[0086] Raw material and consumption of table 2 embodiment of the present invention 2
[0087] Waterborne Aliphatic Polyurethane Dispersions
UCECOAT 7655
40 copies
Waterborne polyurethane acrylate
UCECOAT 7200
20 copies
dipentaerythritol hexaacrylate
EM 264
15 copies
pentaerythritol triacrylate
EM 235
25 copies
Deionized water
Deionized water
5 copies
2-Hydroxy-2-methyl-1-phenyl-1-propanone
IRGACURE 1173
3 copies
2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone
IRGACURE 2959
2 copies
Silica matting powder
OK 520
10 copies
Organically modified 600nm silica
NSI 650S
8 servings
70~100nm silicon dioxide
IPA-ST-L
15 copies
Pigment affinity group polymer interpolymer
DISPERBYK-184
0.3 parts
Polyether mo...
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