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Composite wet strength agent and production method thereof

A technology of wet strength agent and mixture, which is applied in the field of composite wet strength agent and its production, which can solve the problems of environmental pollution, harmful substances, and harm to human health, and achieve the effects of improving wet strength, enhancing affinity, and enhancing cohesion

Inactive Publication Date: 2015-08-26
山东同创精细化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The existing wet strength agent is mainly based on PAE wet strength agent. In the preparation process of PAE wet strength agent, organic solvents and formaldehyde polymers are used, which are harmful to human health, and harmful substances will be produced during the preparation process. environmental pollution

Method used

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  • Composite wet strength agent and production method thereof

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Effect test

Embodiment 1

[0021] In the embodiment of the present invention, a composite wet strength agent comprises raw materials according to mass percentage: 5 parts of polyamide epichlorohydrin, 3.5 parts of sodium lauryl sulfate, 7 parts of hydroxyethyl hexadecane cellulose, mono 8 parts of potassium dodecyl phosphate, 7 parts of p-toluenesulfonic acid, 11 parts of polyethylene glycol, 12 parts of urea, 6 parts of diethylenetriamine, 7 parts of cyclohexane, 4 parts of sodium sulfamate, 0.5 part of dicarboxylate half ester, 8 parts of dodecyltrimethylammonium chloride and 21 parts of water.

[0022] The production method of described composite wet strength agent, comprises the following steps:

[0023] (1) Weigh polyamide epichlorohydrin, sodium lauryl sulfate, hydroxyethyl hexadecyl cellulose, potassium monododecyl phosphate, p-toluenesulfonic acid and polyethylene glycol in proportion , mixed, stirred and reacted for 0.8h, and the stirring speed was 110r / min;

[0024] (2) Weigh and mix urea, d...

Embodiment 2

[0028] In the embodiment of the present invention, a composite wet strength agent, raw materials according to mass percentages include: 6 parts of polyamide epichlorohydrin, 4 parts of sodium lauryl sulfate, 6 parts of hydroxyethyl hexadecane cellulose, mono 9 parts of potassium dodecyl phosphate, 6 parts of p-toluenesulfonic acid, 10 parts of polyethylene glycol, 13 parts of urea, 7 parts of a mixture of diethylenetriamine and triethylenetetramine with a mass ratio of 1:1, 8 parts of cyclohexane, 4.5 parts of sodium sulfamate, 1 part of dihydrocarbyl methylpropionic acid, 7.5 parts of dodecyltrimethylammonium chloride and 18 parts of water.

[0029] The production method of described composite wet strength agent, comprises the following steps:

[0030] (1) Weigh polyamide epichlorohydrin, sodium lauryl sulfate, hydroxyethyl hexadecyl cellulose, potassium monododecyl phosphate, p-toluenesulfonic acid and polyethylene glycol in proportion , mixed, stirred and reacted for 1.2h,...

Embodiment 3

[0035] In the embodiment of the present invention, a composite wet strength agent, raw materials according to mass percentages include: 8 parts of polyamide epichlorohydrin, 3.5 parts of sodium lauryl sulfate, 4 parts of hydroxyethyl hexadecane cellulose, mono 10 parts of potassium dodecyl phosphate, 5 parts of p-toluenesulfonic acid, 8 parts of polyethylene glycol, 15 parts of urea, 8 parts of tetraethylenepentamine, 7 parts of cyclohexane, 5 parts of sodium sulfamate, 1.5 parts of dihydrocarbyl methylpropionic acid, 7 parts of dodecyltrimethylammonium chloride and 18 parts of water.

[0036] The production method of described composite wet strength agent, comprises the following steps:

[0037] (1) Weigh polyamide epichlorohydrin, sodium lauryl sulfate, hydroxyethyl hexadecyl cellulose, potassium monododecyl phosphate, p-toluenesulfonic acid and polyethylene glycol in proportion , mixed, stirred and reacted for 1.5h, the stirring speed was 100r / min;

[0038] (2) Weigh and ...

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Abstract

The invention discloses a composite wet strength agent and a production method thereof. The composite wet strength agent is prepared from, in parts by mass, 5-8 parts of polyamide epichlorhydrin, 3-4 parts of lauryl sodium sulfate, 4-7 parts of hydroxyethyl cetane cellulose, 8-10 parts of mono lauryl phosphate potassium, 5-7 parts of p-toluene sulfonic acid, 8-11 parts of polyethylene glycol, 12-15 parts of urea, 6-8 parts of polyethylene polyamine, 7-9 parts of cyclohexane, 4-5 parts of sodium sulfamate, 0.5-1.5 parts of catalyst, 7-8 parts of dodecyl trimethyl ammonium chloride and 13-21 parts of water by mixing, stirring, reacting and pH (potential of hydrogen) adjusting. The prepared composite wet strength agent is in an emulsion form and is better in stability; the retention time is a year; no organic solvent harmful to a human body is added in a preparation process, so that the composite wet strength agent is green and environment-friendly; and when the composite wet strength agent is used for coating paper, the dry and wet tensile strength of the paper is greatly improved.

Description

technical field [0001] The invention relates to a wet strength agent, in particular to a composite wet strength agent and a production method thereof. Background technique [0002] As an additive, wet strength agent is mainly used in the paper industry. Wet strength agents include permanent wet strength agents and temporary wet strength agents. Conventional wet strength agents are used in paper products, and their tensile strength is small, which cannot improve the quality of paper. To improve the effect of wet strength agent, it is necessary to enhance the strength between fibers, form water-insensitive chemical bonds, form complex polymer networks, etc., in order to effectively improve the performance of wet strength agent and improve the tensile strength of paper products. [0003] The existing wet strength agent is mainly based on PAE wet strength agent. In the preparation process of PAE wet strength agent, organic solvents and formaldehyde polymers are used, which...

Claims

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Application Information

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IPC IPC(8): D21H21/20
Inventor 李庆同李庆勇张朝波丁来民
Owner 山东同创精细化工有限公司
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