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Special thickening and efficiency-improving aid for ammonium glyphosate

A technology of glyphosate ammonium salt and synergist, applied in the direction of herbicide and algicide, application, biocide, etc., can solve the problem of strict glyphosate production process, lack of thickening effect, and lower system Viscosity and other problems, to achieve the effect of reducing the surface tension of the solution, reducing the viscosity, and increasing the viscosity

Active Publication Date: 2015-08-05
深圳市长园嘉彩环境材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005]①Currently, most glyphosate additives are synergistic additives without thickening effect
But add alkyl glycoside surfactant in glyphosate ammonium salt synergistic system, can obviously reduce the viscosity of system, disclose a kind of glyphosate ammonium salt synergist as Chinese patent CN102396449B, this auxiliary agent consists of ten Sodium dialkylbenzene sulfonate, cetyltrimethylammonium bromide, alkyl glycoside, lecithin, silicone defoamer AF-9000 and water, the additive has a certain synergistic effect, but not It has a thickening effect, and the cost of raw materials is relatively high
[0006]②The appearance quality (viscosity, transparency, wall-hanging performance and color, etc.) of general ammonium glyphosate thickeners will vary with the pH, The temperature has great changes, the scope of application is relatively narrow, and the requirements for the production process of glyphosate are relatively strict
Glyphosate ammonium salt additives also have a small number of synergistic thickening additives. Chinese patent CN 103210915A discloses an agricultural thickening and synergistic additive, which consists of fatty alcohol polyoxyethylene ether sulfate, alkyl glycoside, Composed of sodium lauroyl sarcosinate, sodium dodecylbenzenesulfonate, ammonium sulfate and water, but the thickening is not obvious, the dosage is 10% of the weight of ammonium glyphosate salt solution, and the viscosity (25°C) is 240mPa· the s

Method used

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  • Special thickening and efficiency-improving aid for ammonium glyphosate
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  • Special thickening and efficiency-improving aid for ammonium glyphosate

Examples

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Effect test

Embodiment 1

[0030] Example 1. Special thickening and synergist for glyphosate ammonium salt of the present invention and its preparation

[0031] Components: Dodecyl dimethyl benzyl ammonium chloride 200g, lauryl amide amine oxide 600g, glycerol 20g, carbon chain length C8 non-ionic surfactant alkyl glycoside 100g, citric acid 10g, the rest The amount is water.

[0032] Preparation method: first mix dodecyl dimethyl benzyl ammonium chloride and propylene glycol, stir well, then add lauryl amide amine oxide and citric acid, stir again, and finally add non-ionic surfactant alkyl Glycoside, add 50 g of water, and stir evenly to obtain 1000 g of the special thickening and synergist for glyphosate ammonium salt of the present invention.

Embodiment 2

[0033] Example 2. The special thickening and synergistic assistant for glyphosate ammonium salt of the present invention and its preparation

[0034] Ingredients: octadecyl dimethyl benzyl ammonium chloride 100g, cocamide amine oxide 500g, ethylene glycol 40g, carbon chain length C10 non-ionic surfactant alkyl glycoside 200g, citric acid 10g, the rest The amount is water.

[0035] Preparation method: firstly mix dodecyl trimethyl ammonium chloride and ethylene glycol, stir thoroughly, then add cocamide amine oxide and citric acid, stir again, and finally add non-ionic surfactant alkyl Glycoside, add 50 g of water, and stir evenly to obtain 1000 g of the special thickening and synergist for glyphosate ammonium salt of the present invention.

Embodiment 3

[0036] Example 3 The special thickening and synergist for glyphosate ammonium salt of the present invention and its preparation

[0037] Ingredients: octadecyl trimethyl ammonium chloride 100g, dodecyl dimethyl amine oxide 500g, ethylene glycol 20g, carbon chain length C10 non-ionic surfactant alkyl glycoside 300g, citric acid 15g , The balance is water.

[0038] Preparation method: first mix tetradecyl trimethyl ammonium chloride and ethylene glycol, stir well, then add dodecyl dimethyl amine oxide and citric acid, stir again, and finally add non-ionic surface The active agent alkyl glycoside is supplemented with 135 g of water and stirred evenly to obtain 1000 g of the special thickening and synergist for glyphosate ammonium salt of the present invention.

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Abstract

The invention discloses a special thickening and efficiency-improving aid for ammonium glyphosate. The aid comprises the following components by weight: 10 to 30% of a quaternary ammonium salt cationic surface active agent, 40 to 70% of amine oxide, 2 to 5% of a short-carbon-chain alcohol solvent, 10 to 30% of a non-ionic surface active agent alkyl glycoside and 0.5 to 2% of a weakly acidic pH regulator, with the balance being water. A preparation method for the aid comprises the following steps: uniformly mixing the quaternary ammonium salt cationic surface active agent with the short-carbon-chain alcohol solvent under full stirring; then adding the alkyl amine and the weakly acidic pH regulator and carrying out uniform mixing under stirring once again; and finally adding the non-ionic surface active agent alkyl glycoside, supplementing the balancing water and carrying out uniform mixing under stirring. The special thickening and efficiency-improving aid provided in the invention has the advantages of a wide application scope, stable performance, good thickening and efficiency-improving effects, etc., and can not only effectively improve the apparent viscosity of an ammonium glyphosate water aqua, but also significantly improve the efficacy of the ammonium glyphosate water aqua.

Description

technical field [0001] The invention belongs to the technical field of agricultural surfactants, and in particular relates to a special thickening and synergistic assistant for glyphosate ammonium salt. Background technique [0002] The chemical name of glyphosate is N-(phosphonomethyl)glycine. It is a non-selective and non-residual herbicide. It is very effective against perennial root weeds and is widely used in rubber, mulberry, tea, orchards and sugarcane fields . Due to the poor solubility of glyphosate acid, glyphosate acid is generally neutralized to prepare glyphosate salt, usually ammonium salt, isopropylamine salt, potassium salt, sodium salt, dimethylamine salt, among which glyphosate ammonium salt The most widely used in the market. The main products of ammonium glyphosate are 30% ammonium glyphosate salt solution and 75% ammonium glyphosate powder. At present, the additives used in 30% glyphosate ammonium salt solution are mainly non-ionic surfactants such as...

Claims

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Application Information

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IPC IPC(8): A01N25/30A01N57/20A01P13/00
Inventor 何江淮邓孝荣李勇张思聪黄庆波武永田谢琦
Owner 深圳市长园嘉彩环境材料有限公司
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