Method for producing carbon-containing titanium sponge and device thereof

A technology of sponge titanium and carbon content, which is applied in the field of non-ferrous metal smelting, can solve the problems of addition and uneven addition, and achieve the effects of adding carbon elements, ensuring ingredients, and solving negative effects

Inactive Publication Date: 2015-04-29
朝阳金达钛业股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of the present invention is to provide a method and device for producing carbon-containing titanium sponge, which can solve a series of problems caused by uneven carbon addition in the titanium alloy smelting process by pre-adding carbon before the formation of sponge titanium
The carbide and particle size of the carbon-containing sponge titanium in the titanium alloy are very ideal, which effectively solves the negative impact of adding carbon to the titanium alloy, and also reduces the difficulty of titanium alloy batching and mixing, ensuring the uniform composition and quality of the titanium alloy ingot Stable and solves a series of technical problems of adding carbon elements in the domestic titanium alloy smelting process

Method used

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  • Method for producing carbon-containing titanium sponge and device thereof

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Embodiment 1

[0026] Feed amount based on five tons of reduction furnace: 20 tons of titanium tetrachloride (industrial grade), 32 kg of carbon tetrachloride (analytical pure). The preparation method of carbon-containing titanium sponge is as follows:

[0027] (1) Control the pressure in the titanium tetrachloride storage tank 7 at 0.03-0.06MPa, maintain the positive pressure state in the titanium tetrachloride storage tank, and supplement argon when it is lower than 0.03MPa to maintain the titanium tetrachloride storage tank. Tank pressure within the specified range of 0.03 ~ 0.06Mpa;

[0028] (2) Add the titanium tetrachloride of above-mentioned amount afterwards, and add the carbon tetrachloride of above-mentioned amount in stirring, carbon tetrachloride adds flow rate and is 800~1000ml / min, fully mixes with agitator 6, makes tetrachloride Carbon is fully dissolved in titanium tetrachloride;

[0029] (3) the mixed carbon tetrachloride and titanium tetrachloride mixture is added in the ...

Embodiment 2

[0032] Feed amount based on five tons of reduction furnace: 20 tons of titanium tetrachloride (industrial grade), 64 kg of carbon tetrachloride (analytical pure). The preparation method of carbon-containing titanium sponge is as follows:

[0033] (1) Control the pressure in the titanium tetrachloride storage tank 7 at 0.03-0.06MPa, maintain the positive pressure state in the titanium tetrachloride storage tank, and supplement argon when it is lower than 0.03MPa to maintain the titanium tetrachloride storage tank. Tank pressure within the specified range of 0.03 ~ 0.06Mpa;

[0034] (2) Add the titanium tetrachloride of above-mentioned amount afterwards, and add the carbon tetrachloride of above-mentioned amount in stirring, carbon tetrachloride adds flow rate and is 800~1000ml / min, fully mixes with agitator 6, makes tetrachloride Carbon is fully dissolved in titanium tetrachloride;

[0035] (3) the mixed carbon tetrachloride and titanium tetrachloride mixture is added in the ...

Embodiment 3

[0038]Feed amount based on five tons of reduction furnace: 20 tons of titanium tetrachloride (industrial grade), 128 kg of carbon tetrachloride (analytical pure). The preparation method of carbon-containing titanium sponge is as follows:

[0039] (1) Control the pressure in the titanium tetrachloride storage tank 7 at 0.03-0.06MPa, maintain the positive pressure state in the titanium tetrachloride storage tank, and supplement argon when it is lower than 0.03MPa to maintain the titanium tetrachloride storage tank. Tank pressure within the specified range of 0.03 ~ 0.06Mpa;

[0040] (2) Add the titanium tetrachloride of above-mentioned amount afterwards, and add the carbon tetrachloride of above-mentioned amount in stirring, carbon tetrachloride adds flow rate and is 800~1000ml / min, fully mixes with agitator 6, makes tetrachloride Carbon is fully dissolved in titanium tetrachloride;

[0041] (3) the mixed carbon tetrachloride and titanium tetrachloride mixture is added in the ...

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Abstract

The invention discloses a method for producing carbon-containing titanium sponge and a special device for the method. The method comprises the following steps of pre-adding a carbon-containing compound before titanium sponge is produced from titanium tetrachloride, and then reducing the titanium tetrachloride premixed with the carbon-containing compound to obtain carbon-containing titanium sponge with uniform components, wherein the carbon-containing compound is titanium tetrachloride. According to the method, titanium tetrachloride is directly added before the generation of titanium sponge, and the content of carbon in titanium tetrachloride is controlled so as to achieve the purpose that the content of carbon in titanium tetrachloride is stably controlled; no carbon powder needs to be additionally added during the smelting of a titanium alloy, and thus the segregation of carbon element components and local defects in the titanium alloy caused by the conventional adding method are avoided; sizes of carbides and particles precipitated in the titanium alloy of the carbon-containing titanium sponge are very ideal, the negative impact of a carbon element added in the titanium alloy is effectively solved, meanwhile, the difficulty in preparing and mixing the titanium alloy is reduced, the uniform components and stable quality of titanium alloy ingots are ensured, and a series of technical difficult problems caused by adding the carbon element during the smelting of the titanium alloy at home are solved.

Description

technical field [0001] The invention relates to the technical field of nonferrous metal smelting, in particular to a method and device for producing carbon-containing titanium sponge. Background technique [0002] As an impurity element of sponge titanium, carbon element needs to be strictly controlled in the production process of sponge titanium; the carbon element in sponge titanium mainly comes from magnesium ingot and titanium tetrachloride, which is produced by using qualified titanium tetrachloride and low-carbon magnesium ingot The carbon content of the sponge titanium is usually lower than 0.01%, and the content of carbon element in the sponge titanium is stable, which fully meets the requirements of the titanium alloy for the carbon content of the sponge titanium. [0003] Near-α titanium alloys are typical high-temperature alloys, which have both the creep resistance of α-titanium alloys and high strength. The service temperature of this type of alloy is 500-650°C...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B34/12
Inventor 胥永张金宝张军王继宪
Owner 朝阳金达钛业股份有限公司
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