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Antireflection glass and preparation method thereof

An anti-reflection glass and glass substrate technology, applied in chemical instruments and methods, glass/slag layered products, layered products, etc., can solve the problem of easy scratches, affecting product appearance and customer acceptance, and destroying anti-reflection coating optics. effects, etc.

Active Publication Date: 2015-04-29
YICHANG NANBO DISPLAY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Using TiO 2 Although the produced AR film is harder in hardness, TiO 2 Dark spots will appear under UV light irradiation. Although the dark spots gradually fade with time, they will reappear after UV irradiation, which will affect the visual effect of the product.
And Nb 2 o 5 It is dissolved in lye, and the surface layer is made of Nb 2 o 5 If the AR products are cleaned with lye and ultrasonically lyeed in the subsequent processing steps, some Nb will appear 2 o 5 The phenomenon of layer dissolution destroys the optical film layer, thereby destroying the optical effect of the anti-reflection film; at the same time, the Nb 2 o 5 and SiO 2 The Vickers hardness is only 560Hv and 640Hv. If these two materials are used for all the film layers, the anti-reflection film generated will be easily scratched during subsequent processing and end customer use, which will affect the appearance of the product and customer acceptance.

Method used

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  • Antireflection glass and preparation method thereof

Examples

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preparation example Construction

[0067] The preparation method of above-mentioned anti-reflection glass, comprises the steps:

[0068] S10 , providing an aluminosilicate glass substrate 10 .

[0069]Preferably, the thickness of the aluminosilicate glass substrate 10 is 0.4-0.7 mm.

[0070] Preferably, the refractive index of the aluminosilicate glass substrate 10 is 1.50˜1.52.

[0071] Preferably, the aluminosilicate glass substrate 10 is cleaned and dried first.

[0072] S20, sequentially depositing the first low refractive index layer 20, the first high refractive index layer 30, the second low refractive index layer 40, the second high refractive index layer 50, The third low-refractive-index layer 60, the third high-refractive-index layer 70, the fourth low-refractive-index layer 80, the fourth high-refractive-index layer 85, the fifth low-refractive-index layer 90, and the fifth high-refractive-index layer 95 are obtained. reflective glass.

[0073] The material of the first low refractive index laye...

Embodiment 1

[0106] The structure of the anti-reflection glass in Example 1 is glass substrate / SiO 2 / Nb 2 o 5 / SiO 2 / Nb 2 o 5 / SiO 2 / Nb 2 o 5 / SiO 2 / Nb 2 o 5 / SiO 2 / Si 3 N 4 Wherein, " / " represents a stacked structure, and the values ​​in brackets represent thicknesses, which are the same in the following embodiments.

[0107]The material of the glass substrate in Example 1 is aluminosilicate glass with a thickness of 0.7 mm.

[0108] The anti-reflection glass in Example 1 is measured by using Nippon Denshoku’s SD-6000 to measure its full-band transmittance and reflectance in the visible light range with a wavelength of 380-780nm. The measured average transmittance is ≥ 94.5%. Reflectance ≤ 1%.

[0109] The hardness of the anti-reflection glass was tested using a pencil hardness tester, and the hardness was 7H.

[0110] A certain amount of the anti-reflection glass was taken and soaked for 2 hours in NaOH solution with a concentration of 10wt% and...

Embodiment 2

[0114] The structure of the anti-reflection glass of embodiment 2 is glass substrate / Nb 2 o 5 / SiO 2 / Nb 2 o 5 / SiO 2 / Nb 2 o 5 / SiO 2 / Nb 2 o 5 / SiO 2 / Si 3 N 4

[0115] The material of the glass substrate in Example 1 is aluminosilicate glass with a thickness of 1.1 mm.

[0116] The anti-reflection glass of Example 2 is measured by using Nippon Denshoku’s SD-6000 to measure its full-band transmittance and reflectance in the visible light range with a wavelength of 380-780nm. The measured average transmittance is ≥ 94.5%. Reflectance ≤ 1%.

[0117] A pencil hardness tester was used to test the hardness of the anti-reflection glass anti-reflection film layer, and the hardness was 7H.

[0118] A certain amount of the anti-reflection glass was taken and soaked for 2 hours in NaOH solution with a concentration of 10wt% and a temperature of 40°C. After testing the spectrum of the sample after immersion, compared with the spectrum before immersio...

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Abstract

The invention discloses a piece of antireflection glass. The antireflection glass is prepared by using aluminosilicate glass as a substrate; the visible light full-wave band average transmittance is higher than or equal to 94.5%, and the film coated surface single-side full-wave band average reflectivity is smaller than or equal to 1%; the antireflection glass is high in hardness, scrape resistance, acid-base resistance and follow-up processability. The antireflection glass comprises the aluminosilicate glass substrate, a first low-refractive index layer, a first high-refractive index layer, a second low-refractive index layer, a second high-refractive index layer, a third low-refractive index layer, a third high-refractive index layer, a fourth low-refractive index layer, a fourth high-refractive index layer, a fifth low-refractive index layer, and a fifth high-refractive index layer, wherein the first low-refractive index layer is made of SiO2; the first high-refractive index layer is made of Nb2O5. The antireflection glass is lower in the film coated surface single-side full-wave band average reflectivity, higher in hardness, and very suitable for acid and alkali treatment in the follow-up manufacturing procedures, so as to be adapted to more working procedures and achieve wider application range. The invention further discloses a preparation method of the antireflection glass.

Description

technical field [0001] The invention relates to an aluminosilicate glass as a substrate, the average transmittance of visible light in the whole band is ≥ 94.5%, the average reflectance of the single side of the coating surface in the whole band is ≤ 1%, high hardness, scratch resistance, acid and alkali resistance, and subsequent processing Strong anti-reflection glass and preparation method thereof. Background technique [0002] With the popularity of smart touch phones and tablets, more and more people develop the habit of using touch electronic products. There is a cover glass on the top of the screen of the touch electronic product, but because the glass has the function of reflecting light, when the outdoor sunlight or indoor strong light is stronger than the transmitted light of the LCD backlight, there will be about 4.2% of the reflected light on each surface of the glass Reflected into the human eye, the eyes cannot see the content displayed on the screen clearly, ...

Claims

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Application Information

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IPC IPC(8): B32B9/04B32B17/00B32B33/00C03C17/34
CPCB32B9/04B32B17/00B32B33/00B32B2307/536B32B2307/584B32B2307/752C03C17/3435
Inventor 方凤军刘玉华何建军杜晓峰边彬
Owner YICHANG NANBO DISPLAY
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