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Potassium permanganate mediated oxidation dyeing method

An oxidation dyeing and potassium permanganate technology, applied in the field of potassium permanganate-mediated oxidation dyeing, can solve problems such as human hazards, environmental pollution, operator injury, etc., achieve uniform color, reduce environmental pollution, and improve softness Effect

Active Publication Date: 2016-05-04
BEIJING FANBO CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, due to the strong oxidizing properties of potassium dichromate, an oxide film layer can be formed in the fur surface treatment, which is beneficial to the subsequent dyeing. Therefore, potassium dichromate is usually used as a mordant in the fur dyeing process before soaking. Oxidative dyeing, but potassium dichromate is a toxic chemical reagent, which not only brings physical harm to the operator, but also pollutes the environment. In addition, the residual potassium dichromate on the fur is also potentially harmful to the human body

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] The method for potassium permanganate mediated oxidative dyeing comprises the following steps:

[0050] 1) Material selection: the selected raw leather is natural white, undyed animal skin;

[0051] 2) Pretreatment of raw hides: After the hides are soaked in water, fleshed, degreased, softened and pickled, etc., they are then subjected to aldehyde tanning treatment to make the hides have good oxidation resistance and prepare for later dyeing;

[0052] 3) Unhairing: the pretreated raw hides are unhaired with the first mixed aqueous solution of soda ash, ammonia water and Weiss degreasing agent JA-50, and the unhaired is soaked in the first mixed aqueous solution at a temperature of 40°C for 1 hour; The first mixed aqueous solution used for wool opening is mixed by adding 2.5g of soda ash, 2.5ml of ammonia water, and 0.6ml of Weiss degreasing agent JA-500.6ml per liter of water; dye is added to the first mixed aqueous solution, and the liquid ratio is 18;

[0053] 4) Wat...

Embodiment 2

[0068] The method for potassium permanganate mediated oxidative dyeing comprises the following steps:

[0069] 1) Material selection: the selected raw leather is natural white, undyed animal skin;

[0070] 2) Pretreatment of raw hides: After the hides are soaked in water, fleshed, degreased, softened and pickled, etc., they are then subjected to aldehyde tanning treatment to make the hides have good oxidation resistance and prepare for later dyeing;

[0071] 3) Unhairing: the pretreated raw hides are unhaired with the first mixed aqueous solution of soda ash, ammonia water and Weiss degreasing agent JA-50, and the unhaired is soaked in the first mixed aqueous solution at a temperature of 38°C for 1.5 hours The first mixed aqueous solution used for hair opening is mixed by adding 2g of soda ash, 2ml of ammonia water, and 0.5ml of Weiss degreasing agent JA-500.5ml in every liter of water; dye is added in the first mixed aqueous solution, and the liquid ratio is 20;

[0072] 4) ...

Embodiment 3

[0087] The method for potassium permanganate mediated oxidative dyeing comprises the following steps:

[0088] 1) Material selection: the selected raw leather is natural white, undyed animal skin;

[0089] 2) Pretreatment of raw hides: After the hides are soaked in water, fleshed, degreased, softened and pickled, etc., they are then subjected to aldehyde tanning treatment to make the hides have good oxidation resistance and prepare for later dyeing;

[0090]3) Unhairing: the pretreated raw hides are unhaired with the first mixed aqueous solution of soda ash, ammonia water and Weiss degreasing agent JA-50, and unhaired is soaked in the first mixed aqueous solution at a temperature of 35°C for 2 hours; The first mixed aqueous solution used for wool opening is mixed by adding 1.5g of soda ash, 1.5ml of ammonia water, and 0.4ml of Weiss degreasing agent JA-500.4ml per liter of water; dye is added to the first mixed aqueous solution, and the liquid ratio is 25;

[0091] 4) Water w...

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Abstract

The invention relates to the field of animal fur processing and particularly relates to an oxidation dyeing method utilizing potassium permanganate as a medium. The oxidation dyeing method comprises the following steps: preprocessing raw material fur, and carrying out wool opening by virtue of a first mixing water solution containing sodium carbonate, ammonia water and a degreasing agent; washing; soaking the washed raw material fur for 20-40 minutes by virtue of a water solution containing potassium permanganate and a penetrating agent, adding lactic acid, continuously soaking, and carrying out oxidation dyeing after the soaking; washing the dyed raw material fur for eliminating a flooding phenomenon, carrying out retanning, drying, adding oil, standing, dry washing, and dry shoveling, so as to obtain finished products. According to the oxidation dyeing method, the potassium permanganate is utilized for replacing toxic potassium dichromate to serve as a medium auxiliary during the oxidation dyeing, the thicknesses and pores of obtained oxidation films are uniform, and the colors of the dyed fur are uniform; furthermore, the process is safe and reliable to operate, the environmental pollution is effectively reduced, and the obtained fur is safe and harmless to human bodies.

Description

technical field [0001] The invention relates to the field of animal fur treatment, in particular to a potassium permanganate-mediated oxidative dyeing method. Background technique [0002] Fur has a long history and tradition in China. It has always had a breeding industry, a dyeing factory and a garment manufacturing industry. It is a major exporter and consumer of fur garments. Nowadays, the fur industry is developing rapidly in China, and the production technology has gradually reached international standards. According to incomplete statistics, in 2002, there were more than 600 fur dyeing and dyeing factories, more than 500 fur garment factories, more than 100,000 employees, and furs exported all over the world. But the accompanying pollution also poses a big challenge to China, especially the pollution from the fur dyeing process. In today's rapid economic growth, environmental protection is extremely important to us, and the production and application of clean techno...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P1/673D06P3/30C14C3/04
Inventor 王朝锋郑超斌郑红超郝安生
Owner BEIJING FANBO CHEM
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