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A kind of nickel-molybdenum-aluminum coating and preparation method thereof

A nickel-molybdenum-aluminum coating technology, which is applied in the field of nickel-molybdenum-aluminum coating and its preparation, can solve the problems of poor oxidation and corrosion resistance and achieve strong oxidation and corrosion resistance

Inactive Publication Date: 2016-09-14
SHANGHAI INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, thermal barrier coatings use nickel coating, nickel molybdenum coating, nickel molybdenum rare earth coating, nickel molybdenum-molybdenum disilicide coating, nickel molybdenum rare earth-molybdenum disilicide coating as the bonding layer, but the above-mentioned bonding layer materials all have oxidation resistance. Corrosion performance is not very strong and other technical problems

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A nickel-molybdenum-aluminum coating is composed of three elements: nickel, molybdenum and aluminum. Calculated by mass percentage, nickel:molybdenum:aluminum is 64.73%:33.27%:2.00%.

[0027] The preparation method of above-mentioned a kind of nickel-molybdenum-aluminum coating specifically comprises the steps:

[0028] (1) Add 10g nickel salt, 10g molybdenum compound, 10g aluminum salt, 5g complexing agent, 10g chloride, 0.01g electroplating accelerator to 958ml water, stir to dissolve, adjust the pH of the solution to 7.5 with sodium carbonate solution, add water Set the volume to 1L to obtain nickel salt-molybdenum compound-aluminum salt-complexing agent-chloride-plating accelerator electroplating solution, namely nickel chloride-molybdenum pentachloride-aluminum trichloride-aminoacetic acid-tartaric acid-sodium chloride - lanthanum nitrate electroplating solution;

[0029] Wherein the nickel salt is nickel chloride;

[0030] The molybdenum compound is molybdenum p...

Embodiment 2

[0040] A nickel-molybdenum-aluminum coating is composed of three elements: nickel, molybdenum and aluminum. Calculated by mass percentage, nickel: molybdenum: aluminum is 50.27%: 41.23%: 8.50%.

[0041] The preparation method of above-mentioned a kind of nickel-molybdenum-aluminum coating specifically comprises the steps:

[0042] (1) Add 400g nickel salt, 800g molybdenum compound, 350g aluminum salt, 100g complexing agent, 300g chloride, 0.05g electroplating accelerator to 990ml water, stir to dissolve, adjust the pH of the solution to 9.5 with sodium carbonate solution, add water Set the volume to 1L to obtain nickel salt-molybdenum compound-aluminum salt-complexing agent-chloride-plating accelerator electroplating solution, namely nickel nitrate-nickel sulfate-ammonium molybdate-aluminum sulfate-citric acid-ammonium chloride-chloride Potassium-neodymium chloride-erbium chloride electroplating solution;

[0043] Wherein the nickel salt is a mixture of nickel nitrate and nic...

Embodiment 3

[0054] A nickel-molybdenum-aluminum coating is composed of three elements: nickel, molybdenum and aluminum. Calculated by mass percentage, nickel: molybdenum: aluminum is 56.44%: 36.36%: 7.20%.

[0055] The preparation method of above-mentioned a kind of nickel-molybdenum-aluminum coating specifically comprises the steps:

[0056] (1) Add 200g nickel salt, 400g molybdenum compound, 175g aluminum salt, 50g complexing agent, 150g chloride, 0.025g electroplating accelerator to 990mL water, stir to dissolve, adjust the pH of the solution to 8.5 with sodium carbonate solution, add water Set the volume to 1L to obtain nickel salt-molybdenum compound-aluminum salt-complexing agent-chloride-plating accelerator plating solution, namely nickel chloride-nickel nitrate-molybdenum pentachloride-ammonium molybdate-aluminum trichloride-sulfuric acid Aluminum-lactic acid-oxalic acid-ammonium chloride-sodium chloride-gadolinium chloride electroplating solution;

[0057] Wherein the nickel sal...

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PUM

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Abstract

The invention discloses a nickel-molybdenum-aluminum coating and a preparation method thereof. The nickel-molybdenum-aluminum coating is composed of three elements: nickel, molybdenum and aluminum. Calculated by mass percentage, nickel: molybdenum: aluminum is 64.73-50.27%: 33.27-41.23% : 2.00~8.50%. The preparation method is to add nickel salt, molybdenum compound, aluminum salt, complexing agent, chloride, and electroplating accelerator to water, stir and dissolve, adjust the pH value of the solution to 7.5-9.5 with sodium carbonate solution, and obtain nickel salt-molybdenum compound- Aluminum salt-complexing agent-chloride-plating accelerator electroplating solution; the plated piece to be plated is used as a cathode, and the anode is nickel, put into nickel salt-molybdenum compound-aluminum salt-complexing agent-chloride-electroplating accelerator Pulse electroplating is carried out in an electrolytic plating solution. After electroplating, the plated parts are rinsed with water and air-dried to obtain a layer of nickel-molybdenum-aluminum coating with strong oxidation and corrosion resistance on the surface of the plated parts.

Description

technical field [0001] The invention relates to a nickel-molybdenum-aluminum coating and a preparation method thereof. Background technique [0002] With the development of aero-engines toward high thrust-to-weight ratios, the design inlet temperature of aero-engines continues to increase, and the use of high-temperature structural materials alone cannot meet the urgent requirements of the rapid development of advanced aero-engines. At present, the practical way to greatly increase the operating temperature of aero-engines is to use thermal barrier coating technology. Most of the thermal barrier coatings that have been applied in practice have a double-layer structure, and the ceramic layer is used as the surface layer of the thermal barrier coating because of its heat insulation, corrosion resistance, erosion and erosion properties. Due to the thermal expansion coefficient mismatch between ceramics and high-temperature structural materials, a metal bonding layer is require...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D3/56
CPCC25D3/562C25D5/18
Inventor 刘小珍张波陈捷
Owner SHANGHAI INST OF TECH
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